Browse > Article
http://dx.doi.org/10.14478/ace.2015.1055

Study on Binders for Preparing Antistatic Films of PEDOT/PSS  

Kim, Seok Jun (Department of Polymer Engineering, College of Engineering, Suwon University)
Park, Wan-Su (Department of Polymer Engineering, College of Engineering, Suwon University)
Hwang, Jung Seok (Department of Polymer Engineering, College of Engineering, Suwon University)
Pak, Na Young (EverChemTech Co., Ltd.)
Choi, Young Ju (EverChemTech Co., Ltd.)
Chung, Dae-won (Department of Polymer Engineering, College of Engineering, Suwon University)
Publication Information
Applied Chemistry for Engineering / v.26, no.4, 2015 , pp. 458-462 More about this Journal
Abstract
It is essential to employ a binder to prepare transparent films from conductive polymer such as poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT/PSS). In this paper, poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP), and PSS were selected as a binder, and their effects were investigated. The formation of the film was found to be primarily dependent on the surface tension of coating solution including PEDOT/PSS and a binder. When PSS was used as a binder, the film was not formed. In case of using PVP, it was easily peeled off from the substrate. However, when using the PVA or the mixtures of PVA and PSS or PVA and PVP as a binder, films with good transparency and uniform surface resistances were produced. Based on adhesion and long-term stability tests, we concluded that the mixture of PVA and PSS is the best binder for preparing antistatic films of PEDOT/PSS.
Keywords
poly(3,4-ethylenedioxythiophene); poly(styrene sulfonate); binder; antistatic film; poly(vinyl alcohol);
Citations & Related Records
Times Cited By KSCI : 6  (Citation Analysis)
연도 인용수 순위
1 H. Shirakawa, E. J. Louis, A. G. MacDiarmid, C. K. Chiang, and A. J. Heeger, Synthesis of Electrically Conducting Organic Polymers: Halogen Derivatives of Polyacetylene, (CH)x, J. Chem. Soc., Chem. Commun., 16, 578-580 (1997).
2 J. H. Hong and K. S. Jang, Synthesis and Characterization of Soluble Polypyrrole with High Conductivity, J. Korean Ind. Eng. Chem., 18, 234-238 (2007).
3 Y. H. Lee, Y. W. Ju, H. R. Jung, Y. I. Huh, and W. J. Lee, Preparation of Polypyrrole/Sulfonated-SEBS Conducting Composites Through an Inverted Emulsion Pathway, J. Ind. Eng. Chem., 11, 550-555 (2005).
4 J. M. Lee and K. H. Lim, Electrochemical Synthesis of Conducting Polythiophene in an Ultrasonic Field, J. Ind. Eng. Chem., 6, 157-162 (2000).
5 H. Munstedt, Ageing of Electrically Conducting Organic Materials, Polymer, 29, 296-302 (1988).   DOI   ScienceOn
6 S. G. Park, J. J. Na, J. S. Lee, and R. A. Osteryoung, Characteristics of Film Preparation with Conducting Polyphenylenediamine Powder, J. Ind. Eng. Chem., 2, 181-188 (1996).
7 A. Elschner, S. Kirchmeyer, W. Lovenich, U. Merker, and K. Revter, PEDOT: Principles and Applications of an Intrinsically Conductive Polymer, 199-200, CRC Press, Boca Raton, FL, USA (2010).
8 K. Ando, Z. Kato, N. Uchida, K. Uematsu, and K. Saito, Wetting of aqueous solutions of organic binder (PVA) on sapphire and fused quartz, J. Mater. Sci., 24, 4048-4051 (1989).   DOI
9 S. Mandai and Y. Hirai, Polyvinylalcohol Applied for The Ink Jet Silica Binder-Application of Crosslinkable PVA Gohsefimer Z-, Japan Tappi J., 58, 1555-1562 (2004).   DOI
10 S. Wan, W. Z. Lu, Z. X. Fu, and X. C. Wang, Aqueous tape casting of ZnO varistor ceramics with PVA as binder and their properties, Electron. Compon. Mater, 34, 13-17 (2012).
11 J. Cao, H. L. Lin, L. H. Yho, Y. Shi, and P. J. Xia, Chemical Sensitization of Sodium Benzenesulfinate in Photothermographic Materials Using PVA as Binder, J. Photochem. Photobiol., 23, 247-252 (2005).
12 J. Cao, H. L. Lin, L. H. Yao, X. Zhi, J. P. Li, and P. J. Xia Effects of Grain Size and Content of AgBr on Sensitivity of PTG Materials Using PVA as a Hydrophilic Binder, Photogr. Sci. Photochem., 23, 6-13 (2005).
13 J. Cao, H. L. Lin, L. H. Yao, Y. Shi, J. P. Li, and P. J. Xia, Effects of Conventional Chemical Sensitivity of PTG Materials Using PVA as a Hydrophilic Binder, Photogr. Sci. Photochem., 23, 108-113 (2005).
14 U. Kim and W. M. Carty, The Effect of Solution Chemistry on PVA Binder Migration, Ceram. Eng. Sci. Proc., 24, 183 (2003).
15 W. X. Yuan and Z. J. Li, Effects of PVA organic binder on electric properties of $CaCu_3Ti_4O_{12}$ ceramics, J. Chem. Phy., 73, 599-603 (2012).
16 M. Moshen-Nia and M. Hamid, Viscometric study of aqueous poly(vinyl alcohol) (PVA) solutions as a binder in adhesive formulations, J. Adhesion Sci. Technol., 20, 1273-1280 (2006).   DOI   ScienceOn
17 J. H. Cheng and D. J. Wen, An Aqueous Photocrosslinkable Chitosan-PVA (Polyvinyl Alcohol) Binder for Tapecasting Alumina Substrates, Key. Eng. Mater., 368-372, 656-658 (2008).   DOI
18 L. Suhrenbrock, G. Radtke, and K. Knop, Suspension pellet layering using PVA-PEG graft copolymer as a new binder, Int. J. Pharm., 412, 28-36 (2011).   DOI   ScienceOn
19 H. Miura, K. Morohosh, J. Okada, B. Lin, and M. Kimura, Tensile Strength and Conductive Performance of PVA and PEDOT/PSS Blended Fiber, SEN'I GAKKAISHI, 66, 280-283 (2010).   DOI
20 N. Romyen, S. Thongyai, P. Preserthdam, and G. A. Sotzing, Enhancement of poly(3,4-ethylenedioxy thiophene) / poly(styrene sulfonate) properties by poly(vinyl alcohol) and doping agent as conductive nano-thin film for electronic application, J. Mater. Sci., 24, 2897-2905 (2013).
21 S. C. Biswas, L. Dubreil, and D. Marion, Interfacial Behavior of Wheat Puroindolines: Study of Adsorption at the Air-Water Interface from Surface Tensio Measurement Using Wilhelmy Plate Method, J. Coll. Interf. Sci., 244, 245-253 (2001).   DOI   ScienceOn
22 M. A. Mckee, B. S. Yoo, and R. A. Stall, Uniform growth of InSb on GaAs in a rotating disk reactor by LP-MOVPE, J. Cryst. Growth, 124, 286-291 (1992).   DOI   ScienceOn
23 H. Ji, H. M. Lim, Y. W. Chang, and H. S. Lee, Comparison of the Viscosity of Ceramic Slurries using a Rotational Rheometerand a Vibrational Viscometer, J. Korean Ceram. Soc., 49, 542-548 (2012).   DOI   ScienceOn
24 H. L. Wang, D, W. Mcbranch, V. I. klimov, and R. Helgeson, Controlled unidirectional energy transfer in luminescent self-assembled conjugated polymer superlattices, Chem. Phys. Lett., 315, 173-180 (1999).   DOI   ScienceOn
25 M. H. Ahn, E. S. Cho, and S. J. Kwon, Process Optimization of ITO Film on PC Substrate Deposited by In-line Sputtering Method for a Resistive-type Touch Panel, J. Korean Vacuum. Soc., 6, 440-446 (2009).
26 J. Y. Kim, H. J. Yang, N. Y. Pak, Y. J. Choi, S. M. Lee, and D. W. Chung, Study on the Synthesis of the Binder for Antistatic Coating Applicable under High Voltage, Appl. Chem. Eng., 24, 196-200 (2013).
27 J. Y. Chea, J. K. Yoon, O. G. Kang, B. J. Ryn, and K. W. Koo, The Electrical Characteristics of the Antistatic Wafer Carrier, Trans Korean Inst Electr Eng., 63, 319-324 (2014).   DOI   ScienceOn
28 J. W. Bae, S. H. Cha, and J. N. Park, A new polymeric binder for silicon-carbon nanotube composites in lithium ion battery, Macro. Mol. Res., 1, 826-831 (2013).
29 A. Kaminska, H. Kaczmarek, and J. Kowalonek, The Influence of side groups and polarity of polymers on the kind and effectiveness of their surface modification by air plasma action, Eur. Polym. J., 38, 1915-1919 (2002).   DOI   ScienceOn
30 H. W. Chung and S. R. Kim, Detergency of PET Film Having Various Surface Free Energy: Part 1. Surface Tension of MAA Grafted PET Film, J. Korean Soc. Cloth Text, 12, 217-223 (1988).
31 M. C. M. Zaccaron, R. V. B Oliveira, M. Guiotoku, A. T. N. Pires, and V. Soldi, Blends of hydroxypropyl methylcellulose and poly(1-vinylpyrrolidon -co-vinyl acetate) Miscibility and thermal stability, Polym. Degrad. Stab., 90, 21-27 (2005).   DOI   ScienceOn
32 A. B. Seabra and M. G. de Oliveira, Poly(vinyl alcohol) and poly(vinyl pyrrolidone) blended films for local nitric oxide release, Biomaterials, 25, 3773-3782 (2004).   DOI   ScienceOn
33 R. Jayasekara, I. Harding, I. Bowater, G. B. Y. Christie, and G. T. Lonergan, Preparation, surface modification and characterisation of solution cast starch PVA blended films, Polym. Test., 23, 17-27 (2004).   DOI   ScienceOn
34 M. H. Abou_Taleb, Thermal and Spectroscopic Studies of Poly(N-vinylpyrrolidone)/Poly(vinyl alcohol) Blend Films, J. Appl. Polym. Sci., 14, 1202-1207 (2009).
35 N. Nishioka, S. Hamabe, T. Murakami, and T. Kitagawa, Thermal Decomposition Behavior of Miscible Cellulose/Synthetic Polymer Blends, J. Appl. Polym. Sci., 69, 2133-2137 (1998).   DOI