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Study on the Optimization of Cationic Ring Opening Polymerization of Silicone-Based Epoxy Monomers for Holographic Photopolymers  

Kim, Dae-Heum (Chemical Engineering Department, Kwangwoon University)
Chung, Dae-Won (Department of Polymer Engineering, University of Suwon)
Publication Information
Macromolecular Research / v.17, no.9, 2009 , pp. 651-657 More about this Journal
Abstract
This study examined the optimum compositions of binder, photo-acid generator (PAG) and sensitizer for the cationic ring opening polymerization of 1,3-bis[2-(3-{7-oxabicyclo-[4.1.0]heptyl})]-tetramethyldisiloxane in the presence of polydimethylsiloxane with four epoxide moieties as a co-monomer. When diffractive efficiency (DE) values were compared quantitatively to analyze the effect of the binder on holographic photopolymerization, DE was affected by the viscosity of the binders and miscibility with the monomer mixture. Extremely low DE values were observed when the immiscible dimethyl silicone was used as a binder. Therefore, methylphenyl silicone, which is miscible with the monomer mixture, was used as the binder for further studies. The optimal conditions were a binder viscosity between 250 to 390 cP, and contents of the binder, PAG, and sensitizer were 75-125 wt%, > 6 wt% and 0.05 wt% to the total monomer mixture, respectively.
Keywords
photopolymer; cationic ring opening polymerization; polydimethylsiloxane; epoxide; hydrosilylation;
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1 A. Pu and D. Pasaltis, Appl. Opt., 35, 2389 (1996)   DOI
2 D. H. Close, A. D. Jacobson, I. D. Margerum, R. G. Brault, and F. J. McClung, Appl. Phys. Lett., 14, 159 (1969)   DOI
3 B. M. Monroe, J. Imaging Sci., 35, 25 (1991)
4 N. Kim, E. S. Hwang, and C. W. Shin, J. Opt. Soc. Korea, 10, 1 (2006)   DOI   ScienceOn
5 W. H. Jung, E. J. Ha, I. D. Chung, and J. O. Lee, Macromol. Res., 16, 532 (2008)   DOI
6 J. H. Kim, H. J. Oh, and E. Y. Kim, J. Mater. Chem., 18, 4762 (2008)   DOI   ScienceOn
7 J. V. Crivello and Z. Mao, Chem. Mater., 9, 1554 (1997)   DOI   ScienceOn
8 J. V. Crivello, Radiat. Phys. Chem., 63, 21 (2002)   DOI   ScienceOn
9 E. A. Cetin, R. A. Minns, and D. A. Waldman, USP 6784300 (2004)
10 Y. Kang, Y. H. Seo, D. W. Kim, and C. Lee, Macromol. Res., 12, 431 (2004)   DOI
11 D. Kim, Y. Kim, S. Park, and S. Nam, J. Polym. Soc. Korea, 8, 515 (2004)
12 J. R. Lawrence, F. T. O'neill, and J. T. Sheridan, Appl. Opt., 112, 449 (2001)
13 B. L. Booth, Appl. Opt., 14, 593 (1975)   DOI   PUBMED   ScienceOn
14 M. L. Vadala, M. Rutnakornpituk, M. A. Zalich, T. G. St Pierre, and J. S. Riffle, Polymer, 45, 7449 (2004)   DOI   ScienceOn
15 P. K. Dhal, M. G. Horner, R. T. Ingwall, E. S. Kolb, P. G. Mehta, R. A. Minns, H. G. Schild, and D. A. Waldman, USP 5759721 (1998)
16 W. S. Colburn, J. Imaging Sci. Technol., 41, 443 (1997)
17 P. Forcen, L. Oriol, C. Sanchez, F. J. Rodriguez, R. Alcala, S. Hvilsted, and K. Jankova, Eur. Polym. J., 43, 3292 (2007)   DOI   ScienceOn
18 H. Choi, D. J. Feng, H. N. Yoon, and S. H. Choi, Macromol. Res., 11, 36 (2003)   DOI   ScienceOn
19 S. Blaya, R. Mallavia, L. Carretero, A. Fimia, and R. F. Madrigal, Appl. Phys. Lett., 75, 1628 (1998)
20 J. V. Crivello and J. H. W. Lam, Macromolecules, 10, 1307 (1977)   DOI
21 D. W. Chung and T. G. Kim, J. Ind. Eng. Chem., 13, 979 (2007)
22 J. V. Crivello, Radiat. Phys. Chem., 63, 21 (2002)   DOI   ScienceOn
23 D. G. Kim, J. Y. Lim, S. W. Nam, and D. Chung, J. Opt. Soc. Korea, 11, 183 (2007)   DOI   ScienceOn
24 D. H. Choi, M. J. Cho, H. Yoon, H. N. Yoon, J. H. Kim, and S. H. Paek, Opt. Mater., 27, 85 (2004)   DOI   ScienceOn
25 D. Chung, J. P. Kim, D. H. Kim, and J. Y. Lim, J. Ind. Eng. Chem., 12, 783 (2006)
26 B. Marciniec, J. Gulinski, W. Urbaniak, and Z. W. Kornetka, in Comprehensive handbook on hydrosilylation, B. Marciniec, Ed., Pergamon, Oxford, 1992
27 S. T. Phan, W. C. Lim, J. S. Han, I. N. Jung, and B. R. Yoo, J. Organomet. Chem., 691, 604 (2006)   DOI   ScienceOn
28 S. Sugawara, K. Murase, and T. Kitayama, Appl. Opt., 14, 378 (1975)   DOI   ScienceOn
29 Y. M. Chang, S. C. Yoon, and M. J. Han, Opt. Mater., 30, 662 (2007)   DOI   ScienceOn
30 S. H. Lee, W. S. Jahng, K. H. Park, N. Kim, W. J. Joo, and D. H. Choi, Macromol. Res., 16, 31 (2008)   DOI
31 H. C. Yeong and K. Yusuke, Polym. J., 38, 678 (2006)   DOI   ScienceOn
32 K. Sukegawa, S. Sugawara, and K. Murase, Electron. Commun. Jpn., 58-C, 132 (1975)
33 V. Moreau, Y. Renotte, and Y. Lion, Proc. SPIE, 3951, 108 (1999)
34 J. V. Crivello, J. V. Crivello, Nucl. Instr. Methods, B 151, 8 (1999). 151, 8 (1999)   DOI   ScienceOn
35 J. V. Crivello and M. Jang, J. Photochem. Photobiol. Chem., 159, 173 (2003)   DOI   ScienceOn
36 Y. Ishida, K. Yokomachi, M. Seino, T. Hayakawa, and M. A. Kakimoto, Macromol. Res., 15, 147 (2007)   DOI
37 W. G. Kim, H. K. Ahn, H. W. Lee, S. H. Kim, and J. V. Crivello, Opt. Mater., 21, 343 (2002)
38 K. D. Pradeep, G. H. Michael, T. I. Richard, S. K. Eric, G. M. Parag, A. M. Richard, G. S. Howard, and A. W. David, USP 5759721 (1996)