• 제목/요약/키워드: Polarization curve

검색결과 219건 처리시간 0.023초

^{87}Rb D_2$ 전이선에 대한 원편광 분광 연구 및 레이저 주파수 안정화 (Circular Polarization Spectroscopy in ^{87}Rb D_2$ line and Laser Frequency Stabilization)

  • 문한섭;김승일;김현아;김중복;이호성
    • 한국광학회지
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    • 제6권4호
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    • pp.317-323
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    • 1995
  • 선폭 축소된 반도체 레이저를 이용하여 루비듐 원자의 $D_{2}$ 전이선에 대해 도플러 효과가 제거된 편광분광을 실시하고 광펌핑 편광 분광 이론과 비교하였다. 펌프광이 충분히 약했을 때 실험에서 얻어진 분산모양의 스펙트럼은 단일 주기 광펌핑 이론과 잘 일치하였다. 또한 편광 분광 신호를 직접 오차신호로 사용하여 공진기 길이를 보상한 결과, 주파수 변조를 하지 않고서도 레이저 주파수를 원자의 초미세 전이선에 안정화시킬 수 있었다.

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아연-니켈합금 전기도금층의 부식특성 (Corrsion of Ni-Ze Electrodeposited Alloy)

  • 예길촌;신현준
    • 한국표면공학회지
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    • 제21권2호
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    • pp.39-46
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    • 1988
  • Corrosion behavior of 5-26wt% Ni-Zn electrodeposited alloys was investigated by means of dipping electrochmical polarization measurement and galvanic coupling test. The weight loss and anodic polarization curve of coatings were measured by means of dipping and polarization measurement respectively. The galvanic protection effect of alloy coatings was measured by galvanic coupling test and the surface morpholgy of coatings was observed after corrosion testing. Our findings support thous of previous investigations showing that ${\gamma}$single phase coatings, while galvanic pprotection effect of dual phase coatings improved in comparison with ${\gamma}$single phase coating. The formation of colony in coating of ${\gamma}$and η+${\gamma}$ dual phsae caused the localized corrsion and increased the corrosion rate of the Ni-Zn coating.

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Application of Potential-pH Diagram and Potentiodynamic Polarization of Tungsten

  • Seo, Yong-Jin;Park, Sung-Woo;Lee, Woo-Sun
    • Transactions on Electrical and Electronic Materials
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    • 제7권3호
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    • pp.108-111
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    • 2006
  • The oxidizer-induced corrosion state and microstructure of surface passive metal-oxide layer greatly influenced on the removal rate of tungsten film according to the slurry chemical composition of different mixed oxidizers. In this paper, the actual polishing mechanism and pH-potential equilibrium diagram obtained from potentiodynamic polarization curve were electrochemically compared. An electrochemical corrosion effect implies that slurries with the highest removal rate (RR) have the high dissolution rate.

다양한 코팅 방법에 따른 전조한 강 볼트의 내부식성 (1) (Corrosion Resistance of the Roll Formed Steel Bolts with the Various Types of Coating Methods (1))

  • 사바르;보보무로드;손요헌;김인수
    • 소성∙가공
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    • 제28권2호
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    • pp.71-76
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    • 2019
  • Corrosion resistance is one of the essential properties required in steel bolts. The various types of coatings are used to improve the corrosion resistance of steel bolts. But, roll formed, subsequently Zn alloy electrodeposited and top coated steel bolt easily takes place the white storage stain or white rust under high humidity condition. To investigate the corrosion resistance of roll formed and subsequently the various types of coated steel bolts, their polarization curves were measured by potentio-dynamic tester in this study. Based on the measured polarization curves, the more times of chromate and top coating on roll formed steel bolt, the higher corrosion resistance was shown. The roll formed steel bolt, which was Zn-Ni electro-deposited, two times chromated, one time inorganic top coated, one time organic top coated and annealed, showed the best corrosion resistance.

초박막 폴리머 강유전체 박막의 특성 (Characteristics of Ultra-thin Polymer Ferroelectric Films)

  • 김광호
    • 반도체디스플레이기술학회지
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    • 제19권4호
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    • pp.84-87
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    • 2020
  • The properties of ultra-thin two-dimensional (2D) organic ferroelectric Langmuir-Blodgett (LB) films of the poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] were investigated to find possible applicability in flexible and wearable electronics applications. In the C-V characteristics of the MFM capacitor of 2-monolayer of 5 nm films, a butterfly hysteresis curve due to the ferroelectricity of P(VDF-TrFE) was confirmed. Typical residual polarization value was measured at 2μC/㎠. When the MFM capacitor with ultra-thin ferroelectric film was measured by applying a 10 Hz bipolar pulse, it was shown that 65% of the initial polarization value in 105 cycles deteriorated the polarization. The leakage current density of the 2-monolayer film was maintained at about 5 × 10-8 A/㎠ for the case at a 5MV/cm electric field. The resistivity of the 2-monolayer film in the case at an electric field at 5 MV/cm was more than 2.35 × 1013 Ω·cm.

기체확산층 물성이 고분자전해질 연료전지 성능에 미치는 영향 (Effect of Gas Diffusion Layer Property on PEMFC Performance)

  • 김준섭;김준범
    • 공업화학
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    • 제31권5호
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    • pp.568-574
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    • 2020
  • 기체확산층은 유로에서 전극으로 반응물을 전달하고, 반응으로 생성되는 물을 배출하는 통로이며 열 배출과 전극 지지대 등의 역할을 하는 고분자전해질 연료전지의 핵심 구성요소이다. 본 연구에서는 국내외 기체확산층 상용 제품인 39BC와 JNT30-A3에 대한 연료전지의 성능 평가를 수행하였다. 25 ㎠ 단위 전지를 이용하여 유량, 상대습도 조건에 대한 분극 곡선을 측정하였고, empirical equation을 이용하여 운전 조건에 대한 성능 인자를 도출하였다. 기체확산층의 PTFE 함량이 높을수록 저항이 증가하였고, 미세다공층의 크랙은 물의 이동 통로로서 농도 손실에 영향을 미쳤다. 또한 상대습도가 낮을수록 Ohmic 저항이 증가하였지만, 전류밀도가 증가할수록 이온전도도가 증가하여 Ohmic 저항이 감소하였다. Empirical equation을 이용한 fitting curve을 통하여 기체확산층의 운전 조건에 대한 성능 인자 경향을 해석할 수 있었다.

Hf0.5Zr0.5O2 강유전체 박막의 다양한 분극 스위칭 모델에 의한 동역학 분석 (Switching Dynamics Analysis by Various Models of Hf0.5Zr0.5O2 Ferroelectric Thin Films)

  • 안승언
    • 한국재료학회지
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    • 제30권2호
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    • pp.99-104
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    • 2020
  • Recent discoveries of ferroelectric properties in ultrathin doped hafnium oxide (HfO2) have led to the expectation that HfO2 could overcome the shortcomings of perovskite materials and be applied to electron devices such as Fe-Random access memory (RAM), ferroelectric tunnel junction (FTJ) and negative capacitance field effect transistor (NC-FET) device. As research on hafnium oxide ferroelectrics accelerates, several models to analyze the polarization switching characteristics of hafnium oxide ferroelectrics have been proposed from the domain or energy point of view. However, there is still a lack of in-depth consideration of models that can fully express the polarization switching properties of ferroelectrics. In this paper, a Zr-doped HfO2 thin film based metal-ferroelectric-metal (MFM) capacitor was implemented and the polarization switching dynamics, along with the ferroelectric characteristics, of the device were analyzed. In addition, a study was conducted to propose an applicable model of HfO2-based MFM capacitors by applying various ferroelectric switching characteristics models.

국산동판을 사용한 리드프레임 도금기술에 관한 연구 (Electroplating on the Lead Frames Fabricated from Domestic Copper Plate)

  • 장현구;이대승
    • 한국표면공학회지
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    • 제19권3호
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    • pp.92-108
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    • 1986
  • An electroplating on the lead frame fabricated from domestic copper plate was studied experimentally. In this study, nickel was plated on the thin copper lead frame and silver layer was coated on the nickel film in the cyanide electrolyte. The effect of process variables such as current density, plating time, coating thickness and flow rate of electrolytic solution on the properties of coating was investigated. Some samples on each step were fabricated during electroplating. The results obtained from polarization measurement, observation of SEM photograph, adhesion test of coating and microhardness test are as follows. On silver plating, polarization resistance of potentiostatic cathodic polarization curve is reduced as the flow rate of Ag electrolytic solution increases. And above resistance is also reduced when the minor chemicals of sodium cyanide and sodium carbonate are added in potassium silver cyanide bath. The reduced polarization resistance makes silver deposition on the cathode easy. An increase in the current density and the coating thickness causes the particle size of deposit to coarsen, and consequently the Knoop microhardness of the coating decreases. On selective plating an increase in the flow rate of plating solution lead to do high speed plating with high current density. In this case, the surface morphology of deposit is of fine microstructure with high Knoop hardness. An increasing trend of the adhesion of coating was shown with increasing the current density and flow rate of electrolytic solution.

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전력공급장치를 이용한 선박용 연료전지 시뮬레이터의 구현 (Implementation of Fuel Cell Simulator for Ship Using the Programmable Power Supply)

  • 박도영;오진석
    • Journal of Advanced Marine Engineering and Technology
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    • 제36권8호
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    • pp.1117-1122
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    • 2012
  • 연료전지를 선박에 적용하는 연구를 위해서는 연료전지 특성을 고려한 전력 시스템 설계 및 부하 제어에 대한 연구가 필요하다. 하지만 연료전지를 직접 실험하기 위해서는 여러 보조기기들과 복잡한 제어 기술이 필요하다. 이러한 이유로 연료전지 시뮬레이터가 필요하며, 이를 위한 연구가 활발히 진행중이다. 본 논문에서는 자동차, 소형 선박 등에 적용되고 있는 PEMFC에 관하여 LabVIEW를 기반으로 시뮬레이션 하였다. 또한 이러한 시뮬레이션 데이터를 바탕으로 프로그램이 가능한 전력공급장치를 이용하여 시뮬레이터를 제작하여 연료전지의 특성을 구현하였다. 이를 통해 연료전지의 분극화 곡선과 변수에 따른 I-V특성을 확인할 수 있었다.

쇼트피닝 가공을 통한 스프링강의 부식거동에 관한 연구 (A Study on Corrosive Behavior of Spring Steel by Shot-Peening Process)

  • 안재필;박경동
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.325-330
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    • 2004
  • Recently, the request for the high strength of material is more and more increased in the area of industrial environment and machinery. To accomplish the high strength of materials, carbonizing treatment, nitrifying treatment, shot-peening method are representatively applied, however, shot-peening method is generally used among the surface processes. Shot peening is a cold working process used to impact Compressive residual stressed in the exposed surface layers. Benefits due to shot peening are increase in resistance to fatigue, stress corrosion cracking, fretting, galling, erosion and closing of pores. In this study, the influence of shot peening on the corrosion was investigated on spring steel immersed in 3.5% NaCl. The immersion test as performed on the two kinds of specimens. Corrsion potential, polarization curve, residual stress and etc, were investigated from experiment results. From test result the effect of shot peening on the corrosion was evaluated. The important results of the experimental study on the effects of shot peened on the environment corrosion of spring steels are as follows; In case of corrosion potential, shot peened specimen shows more activated negative direction as compared with parent mental. Surface of specimen, which is treated with the shot peened is placed as more activated state against inner base metal. It can cause t도 anti-corrosion effect on the base metal.

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