• Title/Summary/Keyword: Petroleum oil

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Synthesis of Biodiesel from Vegetable Oil and Their Characteristics in Low Temperature (식물성 오일로부터 바이오디젤의 합성과 저온특성)

  • Lim, Young-Kwan;Kim, DongKil;Yim, Eui Soon
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.208-212
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    • 2009
  • Biodiesel come from animal fat and vegetable oil by methanolysis was known for eco-friendly fuel for the alternative petrodiesel. But, various kinds of biodiesel need to analyze the cold characteristic due to poor fuel properties than petrodiesel in a cold condition. In this paper, 12 types of biodiesel were synthesized in 86~96% yields from 12 kinds of vegetable oil by transesterification. These synthesized biodiesels were analyzed in terms of the cold characteristics like cloud point, pour point, and cold filter plugging point (CFPP). The biodiesel comes from perilla oil which has rich olefin showed the excellent fuel characteristics in a low temperature.

Characterization of Basic Nitrogen-Containing Compounds in the Products of Lube Base Oil Processing by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

  • Li, Xiaohui;Zhu, Jianhua;Wu, Bencheng
    • Bulletin of the Korean Chemical Society
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    • v.35 no.1
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    • pp.165-172
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    • 2014
  • The distribution of basic nitrogen-containing compounds in three vacuum gas oils (VGOs) with different boiling ranges and their dewaxed oils from the lube base oil refining unit of a refinery were characterized by positive-ion electrospray ionization (ESI) Fourier transform-ion cyclotron resonance mass spectrometry (FT-ICR MS). It turned out that the composition of basic nitrogen compounds in the samples varied significantly in DBE and carbon number, and the dominant basic N-containing compounds in these oil samples were N1 class species. $N_1O_1$, $N_1O_2$, and $N_2$ class species with much lower relative abundance were also identified. The composition of basic nitrogen compounds in VGOs and dewaxed VGOs were correlated with increased boiling point and varied in DBE and carbon numbers. The comparison of the analytical results between VGOs and dewaxed VGOs indicated that more basic N-containing compounds in VGO with low carbon number and small molecular weight tend to be removed by solvent refining in lube base oil processing.

Seismic attributes for characterization of a heavy-oil shaly-sand reservoir in the Muglad Basin of South Sudan

  • Deng, William A.;Kim, Taeyoun;Jang, Seonghyung
    • Geosciences Journal
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    • v.22 no.6
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    • pp.1027-1039
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    • 2018
  • Seismic attributes are often used to identify lithology and evaluate reservoir properties. However, interpretation based only on structural attributes and without knowledge of the Vp/Vs ratio can limit the ability to evaluate changes in heavy oil reservoirs. These limitations are often due to less obvious impedance differences. In order to investigate pieces of evidence of a heavy-oil shaly-sand reservoir from seismic data, besides geochemistry, we studied seismic attributes and characterized the reservoir using seismic stack data and well logging data. The study area was the Muglad rift basin in South Sudan. We conducted a seismic complex analysis to evaluate the target reservoir. To delineate the frequency responses of the different lithological units, we applied the spectral decomposition method to the target reservoir. The most unexpected result was continuous bands of strong seismic reflectors in the target reservoir, which extended across the borehole. Spectral decomposition analysis showed that the low-frequency zone of 25 Hz dominant frequency was consistent with instantaneous attributes. This approach can identify lithology, reveal frequency anomalies, and filter the stacked section into low- and high-frequency bands. The heavy-oil reservoir zones exhibited velocity attenuation and the amplitude was strongly frequency dependent.

Lubricity Characterization of Hydrogenated Biodiesel as an Alternative Diesel Fuel (경유 대체연료로서 수첨바이오디젤의 윤활 특성 연구)

  • Kim, Jae-Kon;Jeon, Cheol-Hwan;Yim, Eui-Soon;Chung, Choong-Sub
    • Tribology and Lubricants
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    • v.28 no.6
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    • pp.321-327
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    • 2012
  • Paraffin bio-based hydrotreated biodiesel(HBD) is originated from vegetable oil(the process can also be applied to animal fat) with the the chemical structure $C_nH_{2n+2}$. In the number of process of the oil or fat, the hydrogenation is significantly important to create a bio-based diesel fuel. This study is focused on lubricity characteristics of BTL diesel blends to use alternative diesel fuel in Korea. The BTL diesel are blended the different volume ratios (HBD 5(5 vol.% HBD - 95 vol.% diesel), HBD 10, HBD 20, HBD 30, HBD 40 and HBD 50. HBD with paraffin compounds showed a very high centane number, low sulfur content and free aromatic compound. Especially, the wear scar of HBD showed poor lubricity compared to automotive diesel due to the fuel composition, low sulfur content and free aromatic compound. Also, the lubricity specification of automotive diesel with different six HBD blends is within the limit by the Korean standards. Finally, HBD as an alternative diesel fuel is challengeable in transportation sector of Korea.

A Study on the Ways to Joint Marine Development and Joint Marine Environmental Protection in Northeast Asia (동북아 해역 권원중첩수역 공동개발합의와 공동환경보호합의 도출 방안)

  • Kim, Ki-Sun
    • Strategy21
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    • s.37
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    • pp.193-241
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    • 2015
  • China, Japan and Korea are the world's top 10 energy consumers, and so very interested in the development of seabed hydrocarbon resources in order to meet their energy demands. The East China Sea is the tri-junction area where three countries' entitlements on the maritime boundaries are overlapped. There are abundant oil reserves in the East China Sea, and therefore competitions among countries are growing to get control of them. Although these countries have concluded the bilateral agreements to jointly develop resources in the East China Sea, they do not function as well. Because joint development and management of seabed petroleum resources can lead to stable development system, and to lower possibility of legal and political disputes, the needs for joint development agreement among three countries are urgent. Meanwhile, Northeast Asian seas are semi-closed seas, which are geographically closed and vulnerable to marine pollution. Moreover there are a lot of nuclear power plants in coastal area, and seabed petroleum resources are being developed. So it is likely to occur nuclear and oil spill accidents. Fukushima nuclear disaster and Bohai Bay oil spill accident in 2011 are the cases to exhibit the potential of major marine pollution accidents in this area. It is anticipated that the risks become higher because power plants and offshore oil platforms are extending gradually. Therefore, the ways to seek the joint marine environmental protection agreement focused on regulation of nuclear power plant and offshore oil platform have to be considered. In this paper, we try to find the way to make joint development and joint environmental protection agreement in Northeast Asian seas. We concentrate on the measure to drive joint development of seabed petroleum deposits in East China Sea's overlap area, despite of maritime delimitation and territorial disputes, and we try to drive joint marine environmental protection system to respond to marine pollution and accidents due to offshore oil platform and nuclear power plants. Through these consideration, we seek solutions to deal with lack of energy, disputes of maritime territorial and boundary delimitation, and marine pollution in Northeast Asia.

Stratigraphy and Petroleum Geochemical Characteristics of Jiaolai Basin in Shandong Province of China (중국 교래분지의 층서와 석유지화학적 특성)

  • Cheong, Tae-Jin;Oh, Jae-Ho;Lee, Young-Joo;Kim, Ji-Hoon
    • The Korean Journal of Petroleum Geology
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    • v.12 no.1
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    • pp.1-8
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    • 2006
  • Jiaolai Basin is the Cretaceous continental sedimentary basin developed in Shandong Province of China. It is interpreted as a pull-apart basin which is filled with fluvio-lacustrine sediments and volcanic rocks. The sedimentary strata are divided into three formations: Laiyang Formation, Qingshan Formation and Wangshi Formation in ascending order. Laiyang Formation of the early Cretaceous consists of conglomerate, sandstone and shale, which are grey, black or red in color, respectively. Qingshan Formation of early Cretaceous includes various kinds of volcanic rocks. Late Cretaceous Wangshi Formation consists of red conglomerate, sandstone and shale. Various types of oil shows are observed on many outcrops in the basin such as asphalt filing fissures, oil smelling, rocks wetted with oil. However, commercial oil discovery was not made. Laiyang Formation is the richest in terms of organic matter contents. Some grey or black shales of Laiyang Formation contain more than 1% of organic matter. Kerogens of some layers mainly consist of amorphous organic matter or pollen. Thermal maturity of the organic matter reached main oil generation zone and hydrocarbon genetic potential is fairly good. According to such geochemical data, some layers of Laiyang Formation can act as hydrocarbon source rocks.

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A Study on the Storage Stability and Malodor of Bio-Fuel oil (바이오중유의 저장안정성 및 악취특성 연구)

  • JANG, EUN-JUNG;PARK, CHEON-KYU;LEE, BONG-HEE
    • Journal of Hydrogen and New Energy
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    • v.28 no.6
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    • pp.712-720
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    • 2017
  • As Korean government has activated the renewable portfolio standard (RPS) since 2012, producers have been seeking and using the various renewable resources to meet the RPS quota. One of these efforts, Power Bio-Fuel oil demonstration project is being conducted to check the operability and compatibility with fossil fuel, Fuel oil (B-C) from 2014. The oil is a mixture of vegetable oil and animal fat or fatty acid ester of them and should satisfy some specification to use the power generation. The oil's quality and combustion characteristics are different from conventional oil, Fuel oil (B-C) in current power plant facility. In this study, it was investigated the storage stability and malodor intensity of Bio-Fuel oil.

Friction Reduction Properties of Evaporation Coated Petroleum and Silicone Oil Lubricants (증발 코팅법으로 증착된 광유와 실리콘 오일 윤활제의 마찰 저감 특성)

  • Yoo, Shin Sung;Kim, Dae Eun
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.8
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    • pp.864-869
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    • 2013
  • As the size of mechanical components decreases, capillary forces and surface tension become increasingly significant. A major problem in maintaining high reliability of these small components is that of large frictional forces due to capillary action and surface tension. Unlike the situation with macro-scale systems, liquid lubrication cannot be used to reduce friction of micro-scale components because of the excessive capillary and drag forces. In this work, the feasibility of using evaporation to coat a thin film of organic lubricant on a solid surface was investigated with the aim of reducing friction. Petroleum and silicone oils were used as lubricants to coat a silicon substrate. It was found that friction could be significantly reduced and, furthermore, that the effectiveness of this method was strongly dependent on the coating conditions.

Bubble breakup dynamics and flow behaviors of a surface-functionalized nanocellulose based nanofluid stabilized foam in constricted microfluidic devices

  • Wei, Bing;Wang, Yuanyuan;Wen, Yangbing;Xu, Xingguang;Wood, Colin;Sun, Lin
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.24-32
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    • 2018
  • Nanocellulose was surface-functionalized toward the applications in enhanced oil recovery (EOR) as a green alternative. The focus of this paper is on the effect of this material based nanofluid (NF) on foam lamella stabilization through studying its bubble breakup dynamics and flow behaviors in constricted mircofluidic devices. The NF stabilized foam produced an improved flow resistance across the capillary largely due to the capillary trapped bubbles at the contraction. The "snap-off" caused the NF stabilized foam to produce finer textured bubbles, which can migrate readily forward to the deep porous media, as revealed by the pressure profiles.