• 제목/요약/키워드: Passive resistance

검색결과 330건 처리시간 0.035초

Effects of Corrosion Inhibitor on Corrosion of Al-based Alloys in Ethylene Glycol-Water Coolant Environment

  • Gwang-Soo Choi;Young-Man Kim;Chan-Jin Park
    • Corrosion Science and Technology
    • /
    • 제22권5호
    • /
    • pp.305-313
    • /
    • 2023
  • The objective of this study was to investigate the effectiveness of sodium dodecyl benzene sulfonate (SDBS) as a corrosion inhibitor on the pitting corrosion behavior of aluminum alloys used in electric vehicle battery cooling systems within a mixture of ethylene glycol and water (EG-W) coolant. Potentiodynamic polarization testing revealed unstable passive film formation on the aluminum alloys in the absence of SDBS. However, the addition of SDBS resulted in a robust passive film, enhancing the pitting corrosion resistance across all examined alloys. Pitting corrosion was predominantly observed near intermetallic compounds in the presence of Cl? ions, which was attributed to galvanic interactions. Among tested alloys, A1040 demonstrated superior resistance due to its lower areal fraction of precipitates and donor density. The incorporation of SDBS inhibitors mitigated the overall pitting corrosion process by hindering Cl? ion penetration. These findings suggest that SDBS can significantly improve pitting corrosion resistance in aluminum alloys employed in battery coolant environments.

지지부재로 이형철근을 설치하는 띠형 강보강재의 인발성능 평가 (The Evaluation for Pullout Performance of Steel Strip Reinforcements with Deformed-Bars as Transverse Members)

  • 정성규;김주형;조삼덕;이광우
    • 한국지반신소재학회논문집
    • /
    • 제12권4호
    • /
    • pp.77-86
    • /
    • 2013
  • 본 연구에서는 지지부재가 설치된 띠형 강보강재에 대한 실내인발시험을 수행하였다. 주문진 표준사를 사용하여 상대밀도 80%인 모형지반을 조성하였고, 지지부재의 개수를 0~2개로 구분하여 실내인발시험을 수행하였다. 상재압은 $50kN/m^2{\sim}200kN/m^2$까지 4단계로 구분하여 적용하였고, 1mm/min 속도로 강보강재를 인발하였다. 표면이 매끄러운 띠형 강보강재의 인발저항력은 보강재 표면과 지반 사이에서 마찰저항만 발현되기 때문에 인발 초기에 급격히 증가하다가 지속적으로 감소하는 경향을 나타낸다. 반면, 지지부재를 설치한 강보강재의 인발저항력은 마찰저항뿐만 아니라 수동저항도 함께 발현되므로 계속적으로 증가하는 것으로 나타났다. 보강재의 형태에 관계없이 최대인발저항은 상재압이 증가함에 따라 선형적으로 증가하는 것으로 나타났다. 지지부재를 1개 설치한 경우에 비해 지지부재를 2개 설치했을 때의 최대수동저항은 작게 나타났다. 이는 지지부재의 설치 간격 및 위치에 따라 지지부재에서 발현되는 수동저항의 크기가 다르기 때문에 나타나는 현상으로 판단되며, 지지부재 설치 위치 및 간격에 따른 추가 인발시험을 통해 확인할 필요가 있다.

압력에 따른 평행박막 밸브의 자율 변형을 이용한 수동형 유량 제어기 (A Passive Flow-rate Regulator Using Pressure-dependent Autonomous Deflection of Parallel Membrane Valves)

  • 도일;조영호
    • 대한기계학회논문집A
    • /
    • 제33권6호
    • /
    • pp.573-576
    • /
    • 2009
  • We present a passive flow-rate regulator, capable to compensate inlet pressure variation and to maintain a constant flow-rate for precise liquid control. Deflection of the parallel membrane valves in the passive flowrate regulator adjusts fluidic resistance according to inlet fluid pressure without any external energy. Compared to previous passive flow-rate regulators, the present device achieves precision flow regulation functions at the lower threshold compensation pressure of 20kPa with the simpler structure. In the experimental study, the fabricated device achieves the constant flow-rate of $6.09{\pm}0.32{\mu}l/s$ over the inlet pressure range of $20{\sim}50$ kPa. The present flow-rate regulator having simple structure and lower compensation pressure level demonstrates potentials for use in integrated micropump systems.

Determining Factors for the Protectiveness of the Passive Film of FeCrN Stainless Steel Formed in Sulfuric Acid Solutions

  • Ha, Heon-Young;Lee, Tae-Ho
    • Corrosion Science and Technology
    • /
    • 제12권4호
    • /
    • pp.163-170
    • /
    • 2013
  • In NaCl solutions acidified with $H_2SO_4$, Fe20Cr1.1N alloy showed enhanced pitting corrosion resistance than Fe20Cr alloy. An XPS analysis revealed that the passive film of Fe20Cr1.1N alloy contained higher cationfraction of Cr than that of Fe20Cr alloy, and nitrogen was incorporated into the film. In addition, it was found that the passive film of Fe20Cr1.1N alloy was thinner and had higher oxygen vacancy density than that of Fe20Cr alloy. Based on these observations, it was concluded that the chemical composition was the determining factor for the protectiveness of the passive film of Fe20Cr based alloy in dilute $H_2SO_4$ solution.

피동 주입 시험 장치의 척도 해석 및 설계 방법론 연구 (Study on Scaling Analysis and Design Methodology of Passive Injection Test Facility)

  • 배황;이민규;류성욱;신수재;김영인;이성재;박현식
    • 한국유체기계학회 논문집
    • /
    • 제19권5호
    • /
    • pp.50-60
    • /
    • 2016
  • A design methodology of the modeled test facility to conserve an injection performance of a passive safety injection system is proposed. This safety injection system is composed of a core makeup tank and a safety injection tank. Individual tanks are connected with pressure balance line on the top side and injection line on the bottom side. It is important to conserve the scaled initial injection flow rate and total injection time since this system can be operated by small gravity head without any active pumps. Differential pressure distribution of the injection line induced by the gravity head is determined by the vertical length and elevation of each tank. However, the total injection time is adjustable by the flow resistance coefficient of the injection line. The scaling methodology for the tank and flow resistance coefficient is suggested. A key point of this test facility design is a scaling analysis for the flow resistance coefficient. The scaling analysis proposed on this paper is based on the volume scaling law with the same vertical length to the prototype and can be extended to a model with a reduced vertical length. A set of passive injection test were performed for the tanks with the same volume and the different length. The test results on the initial flow rate and total injection time showed the almost same injection characteristics and they were in good agreement with the design values.

띠형 강보강재에 설치된 수동저항부재의 설치 특성에 따른 상호간섭계수 평가 (Evaluation on Degree of Interference Based on Installation Characteristics of Transverse Members Installed in Steel Strip Reinforcement)

  • 정성규;홍기권;한중근;이광우
    • 한국지반신소재학회논문집
    • /
    • 제13권3호
    • /
    • pp.11-19
    • /
    • 2014
  • 본 연구에서는 띠형 강보강재에 '${\sqcap}$' 형태의 수동저항부재를 설치하는 보강재에 대한 인발시험 결과를 바탕으로 수동저항부재의 간격 및 설치위치에 따른 간섭효과를 분석하였다. 수동저항부재에서 발현되는 최대수동저항력은 수동저항부재의 설치 위치에 따라 차이가 발생하였으며, 전면벽체에 근접하여 설치된 수동저항부재에서 더 큰 수동저항력이 발현되는 것을 확인하였다. 최대인발력을 사용하여 간섭계수(DI)를 평가한 결과, 지지부재 직경과 간격의 비(S/B)가 동일한 경우에는 수동저항부재의 설치 위치에 따른 인발력 차이를 반영하지 못하는 것으로 평가되었다. 그러나 최대수동저항력을 사용하여 간섭계수(F)를 산정할 경우에는 수동저항부재의 설치 간격뿐만 아니라, 수동저항부재의 설치 위치에 따른 최대수동저항력 차이를 반영하는 것으로 분석되었다.

플라즈마 산질화처리된 AISI 420 마르텐사이트 스테인레스 강재의 표면 경도 및 부식 거동 (Surface Hardness and Corrosion Behavior of AISI 420 Martensitic Stainless Steels Treated by Plasma Oxy-Nitriding Processing)

  • 김진한;이광민
    • 한국재료학회지
    • /
    • 제33권7호
    • /
    • pp.309-314
    • /
    • 2023
  • This study aimed to address the limitations of traditional plasma nitriding methods by implementing a short-term plasma oxy-nitriding treatment on the surface of AISI 420 martensitic stainless steel. This treatment involved the sequential formation of nitride and oxide layers, to enhance surface hardness and corrosion resistance, respectively. The process resulted in the formation of a 20 ㎛-thick nitride layer and a 3 ㎛-thick oxide layer on the steel surface. Initially, the hardness increased by 2.2 times after nitriding, followed by a subsequent decrease of approximately 31 % after oxidation. While the nitriding process reduced corrosion resistance, the subsequent oxidation process led to the formation of a passive oxide film, effectively resolving this issue. The pitting corrosion of the oxide passive film started at 82.6 mVssc, providing better corrosion resistance characteristics than the nitride layer. Consequently, the trade-off between surface hardness and corrosion resistance in plasma oxy-nitrided AISI 420 martensitic stainless steel is anticipated to be recognized as an innovative and comprehensive surface treatment process for biomedical components.

초기 스퍼터링조건이 스테인리스강의 이온질화시 지로하층 형성거동에 미치는 영향 (The Effects of Sputtering conditions in Pre Sputtering on the Formation Behavior of Nitride Layer in the Ion Nitriding of Stainless Steel)

  • 최상진
    • 한국공작기계학회:학술대회논문집
    • /
    • 한국공작기계학회 1999년도 추계학술대회 논문집 - 한국공작기계학회
    • /
    • pp.197-203
    • /
    • 1999
  • Stainless steels in general has passive film having strong corrosion resistance on surface. Therefore it must be necessarily removed by etching in mixing solution of sulfuric and chloric acid before Nitriding treatment. But in the ion nitriding, nitride layer was easily formed because passive film was removed without difficult by sputtering effect. The removal extent of these passive films was greatly effected by gas mixing ratios and pressure and holding times of pre sputtering factors in pre sputtering stage. As a results of experiment it has been known that pre sputtering pressure and holding time was not nearly effective on the formation behavior of nitride layer. But when A/H2 gas mixing ratios was 1/2 (vol%) was the most effective of the all pre sputtering conditions. It was resulted from the combination of mechanical reaction byArgon bombardment and chemical reaction by reduction of hydrogen on the passive film.

  • PDF

Nonlinear analyses of structures with added passive devices

  • Tsai, C.S.;Chen, Kuei-Chi
    • Structural Engineering and Mechanics
    • /
    • 제18권4호
    • /
    • pp.517-539
    • /
    • 2004
  • Many types of passive control devices have been recognized as effective tools for improving the seismic resistance of structures. A lot of past research has been carried out to study the response of structures equipped with energy-absorbing devices by assuming that the behavior of the beam-column systems are linearly elastic. However, linear theory may not be adequate for beams and columns during severe earthquakes. This paper presents the results of research on the nonlinear responses of structures with and without added passive devices under earthquakes. A new material model based on the plasticity theory and the two-surface model for beams and columns under six components of forces is proposed to predict the nonlinear behavior of beam-column systems. And a new nonlinear beam element in consideration of shear deformation is developed to analyze the beams and columns of a structure. Numerical results reveal that linear assumption may not be appropriate for beams and columns under seismic loadings, especially for unexpectedly large earthquakes. Also, it may be necessary to adopt nonlinear beam elements in the analysis and design process to assure the safety of structures with or without the control of devices.

응축수 중에서 가스보일러용 STS 304의 부식거동에 관한 연구 (The Study on the Corrosion Behavior of STS 304 for Gas Boiler in the Condensed Water)

  • 윤병두;임우조;정기철
    • 한국가스학회지
    • /
    • 제9권1호
    • /
    • pp.21-25
    • /
    • 2005
  • 가스보일러용 오스테나이트계 스테인리스강재(STS 304)의 부식거동에 관해 연구하기 위하여, 응축수중에서 전기화학적 부식시험을 수행하여. STS 304의 전기화학적 부식거동을 고찰하였다. 다음과 같은 결론을 얻었다. 1)중성환경인 pH=6.5에서 pH가 낮아질수록 STS 304의 분극저항은 감소하고, 부식전위는 비전위화된다. 2)중성 및 산성환경 중에서 STS 304의 부식반응기구는 음극지배로 판단된다. 3) pH가 중성 환경인 pH=6.5에서 강산성 환경인 pH=0.5로 낮아질수록 STS 304의 부동태 전위영역이 감소하고 부동태유지 전류밀도는 증가하고 있다.

  • PDF