• Title/Summary/Keyword: Particle adhesion

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Ga doped ZnO Thin Films for Gas Sensor Application (Ga이 첨가된 ZnO 박막의 가스센서로의 응용 연구)

  • Hwang, Hyun-Suk;Yeo, Dong-Hun;Kim, Jong-Hee;Song, Joon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.499-502
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    • 2008
  • In this work, Ga-doped ZnO (GZO) thin films for gas sensor application were deposited on low temperature co-fired ceramics (LTCC) substrates, by RF magnetron sputtering method. The LTCC substrate is one of promising materials for this application since it has many advantages (e.g., low cost production, high manufacturing yields and easy realizing 3D structure etc.). The LTCC substrates with thickness of $400\;{\mu}m$ were fabricated by laminating 12 green tapes which consist of alumina and glass particle in an organic binder. The structural properties of the fabricated GZO thin film with thickness of 50 nm is analyzed by X-ray diffraction method (XRD) and field emission scanning electron microscope (FESEM). The film shows good adhesion to the substrate. The GZO gas sensors are tested by gas measurement system and show fast response and recovery characteristics to $NO_x$ gas that is 27.2 and 27.9 sec, recpectively.

A Study on the Properties of Ethylene-Vinyl Acetate Emulsion Blended with SBR, Urethane and Epoxy Latex (에폭시, 우레탄 및 SBR계 라텍스를 혼합한 에틸렌-비닐아세테이트 에멀젼의 특성에 관한 연구)

  • Choi, Sang-Goo
    • Elastomers and Composites
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    • v.34 no.5
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    • pp.414-422
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    • 1999
  • SBR, polyurethane and epoxy latex were separately blended with ethylene-vinyl acetate(EVA) emulsion In $0{\sim}50%$. EVA emulsion was not reacted with latexes in liquid phase and mixtures had good stroage stability. The viscosity of cement mixtures was elevated to 20,000cps in $0.5{\sim}2.0$ hours by mixing. The mixtures mixed with pigment represented high viscosity and showed higher viscosity as time goes by. Mixtures had higher hardness with mixing SBR than mixing epoxy or urethane. The hardness was suddenly increased over cement content 30%. showed pencil hardness $H{\sim}2H$ in $50{\sim}60%$. The increase of hardness in high solids was depended upon not only the condensation of latexs but also the coagulation and adhesion of cement particle.

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Development of anti-corrosive coating technique for alloy plated steel sheet using silane based organic-inorganic hybrid materials (Silane계 유무기 하이브리드 적용 합금도금강판 내식성 향상 코팅 기술 개발)

  • Park, Jongwon;Lee, Kyunghwang;Park, Byungkyu;Hong, Shinhyub
    • Corrosion Science and Technology
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    • v.12 no.6
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    • pp.295-303
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    • 2013
  • Silane surface treatments have been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. The silane performance is comparable to, or in some cases better than, that of chromate layers. Based on the tetra-ethylorthosilicate(TEOS) and methlyl trieethoxysilane(MTES), inorganic sol was synthesized and formed hybrid networks with $SiO_2$ nano particle and polypropylene glycol(PPG) on Zn alloyed steel surface. According to SST results, addition of 10nm and 50nm $SiO_2$ nanoparticle in synthesized solution improved anti-corrosion property by its shear stress relaxation effect during curing process. Also, SST results were shown that anti-corrosive property was affected by the amounts of organic compounds.

Study on High-Temperature Oxidation Behaviors of Plasma-Sprayed TiB2-Co Composite Coatings

  • Fadavi, Milad;Baboukani, Amin Rabiei;Edris, Hossein;Salehi, Mahdi
    • Journal of the Korean Ceramic Society
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    • v.55 no.2
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    • pp.178-184
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    • 2018
  • In the present study, $TiB_2-Co$ composite coatings were thermally sprayed onto the surface of a 304 stainless steel substrate using an atmospheric plasma spray (APS). The phase analysis of the powders and plasma-sprayed coatings was performed using X-ray diffractometry analysis. The microstructures of the coatings were studied by a scanning electron microscope (SEM). The average particle size and flowability of the feedstocks were also measured. Both $TiB_2-32Co$ and $TiB_2-45Co$ (wt.%) coatings possessed typical dense lamellar structures and high-quality adhesion to the substrate. The oxidation behaviors of the coatings were studied at $900^{\circ}C$ in an atmospheric environment. In addition, the cross-sectional images of the oxidized coatings were analyzed by SEM. A thin and well-adhered layer was formed on the surface of both $TiB_2-Co$ coatings, confirming satisfactory high-temperature oxidation resistance. The kinetic curves corresponding to the isothermal oxidation of the coatings illustrated a short transient stage from rapid to slow oxidation during the early portion of the oxidation experiment.

Wear Mechanism of Tube Fretting Affected by Support Shapes

  • Kim, Hyung-Kyu;Lee, Young-Ho;Yoon, Kyung-Ho;Kang, Heung-Seok;Song, Kee-Nam;Ha, Jae-Wook
    • KSTLE International Journal
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    • v.3 no.1
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    • pp.68-73
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    • 2002
  • A fretting wear experiment in roam temperature air was performed to evaluate the wear mechanism of fuel rod using a fretting wear tester, which has been developed for experimental study, The main focus was to compare the wear behaviors of fuel rod against support springs with different contact contours (i.e. concave and convex). Wear volume, degree or surface hardening and adhesion tendency of wear particle were examined by the surface roughness tester. The result indicated that with a change of contact condition from contact force of 5 N to 0.1 mm gap, the wear volume of tube increased in the condition of concave spring, but slowly decreased in convex spring. From the results of SEM observation, wear mechanism of each test condition was also dependent on the spring shapes. The wear mechanism of each test condition in room temperature air is discussed.

Applicability evaluation of microbubble for membrane fouling reduction in wastewater reuse membrane process (하수재이용 막여과 공정에서 막오염 저감을 위한 마이크로버블 적용성 평가)

  • Lee, Chang-Ha;Kim, Geon-Youb;Kim, Hyung-Soo;Kim, Ji-Hoon;Lee, Kyung-Il
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.2
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    • pp.169-175
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    • 2017
  • This study applied microbubbles to reduce membrane fouling in wastewater reuse membrane processes, evaluated and compared the transmembrane pressure with or without the application of microbubbles and the cleaning efficiency with the application of aeration and microbubbles. In addition, this study analyzed foulants removed from the membrane surface. Changes in the transmembrane pressure of membranes with the presence or absence of microbubbles were observed. As a result, transmembrane pressure (TMP) increasing rate decreased twofold when applying microbubbles to realize stable operations. This study compared and evaluated cleaning efficiency applying aeration and microbubbles. As a result, the cleaning efficiency was 5% higher on average when applying microbubbles. In turbidity and total organic carbon (TOC), foulants were discharged when applying microbubbles twice as much as applying aeration. It is thought that particulate foulants precipitated on the membrane surface were more likely to desorb because the adhesion between the membrane surface and particle was weakened by microbubbles. Therefore, it is considered possible to effectively control membrane fouling because of the increase in cleaning efficiency when applying microbubbles to wastewater reuse membrane processes.

The Effect of Chitosan Treatment of Fabrics on the Natural Dyeing using Loess (키토산 처리포의 황토염색에 관한 연구)

  • Kwon, Min-Soo;Jeon, Dong-Won;Kim, Jong-Jun
    • Fashion & Textile Research Journal
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    • v.7 no.3
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    • pp.327-332
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    • 2005
  • The purpose of this study is to investigate the effect of chitosan treatment on the dyeing of cotton fabric specimens using loess as colorants. The wet pick up ratio of the chitosan acid solution, as well as the drying condition after the padding of the fabric specimens, was changed in order to study the loess uptake on the fabric. The average particle diameter of the loess was measured. Main components of the loess were $SiO_2$, $Al_2O_3$, and $Fe_2O_3$. By the chitosan treatment, the loess amount on the cotton fabric increased. 80% wet pick up ratio of the chitosan acid solution on the cotton fabric specimen allowed more stable and even adhesion of the loess on the fabric surface, compared to the cases of 100% and 120% wet pick up ratio.

Fabrication of Core-Shell Structure of Ni/Au Layer on PMMA Micro-Ball for Flexible Electronics

  • Hong, Sung-Jei;Jeong, Gyu-Wan;Han, Jeong-In
    • Current Photovoltaic Research
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    • v.4 no.4
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    • pp.140-144
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    • 2016
  • In this paper, core-shell structure of nickel/gold (Ni/Au) conductive layer on poly-methyl-methacrylate (PMMA) micro-ball was fabricated and its conduction property was investigated. Firstly, PMMA micro-ball was synthesized by using dispersion polymerization method. Size of the ball was $2.8{\mu}m$ within ${\pm}7%$ deviation, and appropriate elastic deformation of the PMMA micro-ball ranging from 31 to 39% was achieved under 3 kg pressure. Also, 200 nm thick Ni/Au conductive layer was fabricated on the PMMA micro-ball by uniformly depositing with electroless-plating. Adhesion of the conductive layer was optimized with help of surface pre-treatment, and the layer adhered without peeling-off despite of thermal expansion by collision with accelerated electrons. Composite paste containing core-shell structured particles well cured at low temperature of $130^{\circ}C$ while pressing the test chip onto the substrate to make electrical contact, and electrical resistance of the conductive layer showed stable behavior of about $6.0{\Omega}$. Thus, it was known that core-shell structured particle of the Ni/Au conductive layer on PMMA micro-ball was feasible to flexible electronics.

Thermogravimetric Analysis of Rice Husk Flour for a New Raw Material of Lignocellulosic Fiber-Thermoplastic Polymer Composites

  • Kim, Hyun-Joong;Eom, Young-Guen
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.3
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    • pp.59-67
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    • 2001
  • Rice husk flours were analyzed by chemical composition and thermogravimetric methods in nitrogen atmosphere to discuss its feasibility as a raw material for manufacturing agricultural lignocellulosic fiber-thermoplastic polymer composite. It was revealed in the chemical composition analysis that rice husk flour was composed of moisture, 5.0%; lignin, 21.6%; holocellulose, 60.8%; ash, 12.6%. In the thermogravimetric analysis (TGA), thermal decomposition behavior of rice husk flour from room temperature to $350^{\circ}C$ was similar to that of wood flour, but rice husk flour was more thermally stable from 350 to $800^{\circ}C$ than wood flour because of higher silica content in the rice husk flour and smaller particle size of rice husk flour. The activation energy of thermal decomposition was evaluated using Flynn & Wall expression. As the thermal decomposition proceeded in rice husk flour, the activation energy of thermal decomposition appeared almost constant up to ${\alpha}=0.25$, but thereafter increased. Activation energy of thermal decomposition in wood flour, however, decreased steeply up to ${\alpha}=0.3$, but thereafter remained almost constant. From the results, rice husk flour was thought be a substitute for wood flour in manufacturing agricultural lignocellulosic fiber-thermoplastic polymer composite in the aspect of thermal decomposition.

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A Study on the Metallization Properties of Cu-Sn Alloy Layers Deposited by the Electroplating Method (전해도금법으로 증착한 Cu-Sn 합금막의 배선특성에 관한 연구)

  • Kim, Ju-Yeon;Bae, Gyu-Sik
    • Korean Journal of Materials Research
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    • v.12 no.3
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    • pp.225-230
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    • 2002
  • Sn was selected as an alloying element of Cu. The Cu-Sn thin layers were deposited on the Si substrates by the electroplating method and their properties were studied. By rapidly thermal annealing(RTA) up to 40$0^{\circ}C$ after electroplating, sheet resistance decreased and adhesion strength increased, but that trend was reversed at the 50$0^{\circ}C$ RTA. Cu-Sn particles grew dense and the surface was uniform up to 40$0^{\circ}C$, but at 50$0^{\circ}C$, empty area was introduced and the surface became rough owing to oxidation and particle coarsening and agglomeration. Deposited layer contained significant amount of Si, while pure Cu-Sn layer with the composition ratio of 90:10 was present only on the top surface. However, no significant change in the Cu composition within alloy layers occured by the RTA regardless of its temperature. This indicates that the Cu diffusion into the Si was suppressed by the presence of Sn.