• Electrical & Electronic Materials
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• v.2 no.2
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• pp.109-116
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• 1989

PSN-PT-PZ 삼성분계 압전세라믹의 상도로부터 유전적, 압전적 특성이 가장 양호한 MPB부근의 조성을 선택하여 MnO$_{2}$를 0-2[wt.%]첨가하였으며 일반소성법으로 시편을 제작하였다. 소결온도는 1,200-1,280[.deg.C], 시간은 0.5-3[hr]까지 변화시켰으며 MnO$_{2}$의 첨가가 시편의 유전적, 압전적 특성에 미치는 영향을 고찰하였다. 제작된 시편의 비유전상수는 MnO$_{2}$의 첨가량에 따라 증가하였으며 MnO$_{2}$가 2[wt.%]첨가된 시편 S-15(PSN:PT:PZ, 15:48:37)의 경우 605.41, 큐리온도는 MnO$_{2}$의 첨가량이 증가할수록 선형적으로 감소하였다. 각 시편의 전기기계 결합계수와 유전손실은 MnO$_{2}$의 첨가량이 0.5-1.5[wt.%]범위에서 양호한 특성을 나타내었으며 MnO$_{2}$가 0.5[wt.%] 첨가된 시편 S-5(PSN:PT:PZ, 5:48:47)의 경우 전기기계 결합계수는 0.425로 가장 높은 값을 나타내었다. MnO$_{2}$가 1[wt.%] 첨가된 시편 S-10(PSN:PT:PZ, 10:48:42)에서 공진주파수의 온도의존성이 가장 양호하게 나타났으며 각 시편에 대한 MnO$_{2}$의 첨가량이 증가할수록 결정립 크기는 감소하였다.

• Proceedings of the KIEE Conference
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• 2001.07c
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• pp.1521-1523
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• 2001

In this paper, High quality factor and fine dielectric loss was resulted on specimen added 0.5wt% $MnO_2$ after compared and analyzed dielectric and piezoelectric properties following that added each 0 $\sim$ 0.9wt% of $Fe_2O_3$, $Nb_2O_5$, and $MnO_2$ on dopant at PSN-PT in two material disposition ceramics with research still is not completed to material investigation to increase high power piezoelectric actuator device efficiency. And, a measuring method and the experimental results of the temperature rise under the high vibrational velocity are also described.

• Journal of Sensor Science and Technology
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• v.13 no.2
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• pp.152-156
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• 2004

The dielectric and piezoelectric properties of 0.36Pb($Sc_{1/2}Nb_{1/2}$)$O_{3}$-0.25Pb($Ni_{1/3}Nb_{2/3}$)$O_{3}$-0.39Pb$TiO_{3}$ (hereafter PSNNT) at the morphotropic phase boundary (MPB) composition were investigated with $0{\sim}2.5$ mot% $MnO_{2}$ doping. Bulk density, dielectric loss and tetragonality of crystal structure were all improved with increasing $MnO_{2}$ additive content. With increasing $MnO_{2}$ additive content, the electromechanical coupling factor and quality factor were also increased: Electromechanical coupling $k_{p}$ and quality factor $Q_{m}$ at 2.0 mol% $MnO_{2}$ doping with were showed highest values of 55.6 % and 252, respectively.

• Journal of the Korean Ceramic Society
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• v.37 no.1
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• pp.63-69
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• 2000

Electrically-induced strain(S) and polarization(P) for Pb(Sc1/2Nb1/2)O3-PbTiO3(1-x)PSN-xPT) crystalline solutions were studied. From the compositional dependence of S and P we could observe two maximum values at x=0.10 and x=0.425. It is considered that PSNT10(x=0.10) composition is the structural phase boundary to indicate the variable order-disorder[VOD] region. PSNT(x=0.425) composition is the morphotropic phase boundary[MPB] to indicate the rhombohedral to tetragonal phase transition. Higher S (0.437%) and P (0.3974$\mu$C/$\textrm{cm}^2$) values were attained by the La substitution (5 wt%) at Pb site in the MPB composition of 57.5PSN-42.5PT.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1993.11a
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• pp.10-13
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• 1993

ln this study, x PSN - y PT - z PZ ceramics doped with w MnO$_2$were fabricated by the mixed oxide method at 1250[$^{\circ}C$] for 2[hr] and then the dielectric and pyroelectric properties were investigated. In the 0.05 PSN - 0.4 PT - 0.55 PZ specimen with 0.5[wt.%] MnO$_2$, the pyroelectric coefficient was 6.6${\times}$10$\^$-8/[C/cm$^2$$.$$^{\circ}C$], respectibly.

• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1496-1498
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• 1994

In this study, x PSN - y PT - z PZ ceramics doped with w $MnO_2$ were fabricated by the mixed oxide method at 1250 [$^{\circ}C$] for 2[hr] and then the dielectric and pyroelectric properties were investigated. In the 0.05 PSN - 0.4 PT - 0.55 PZ specimen with 0.5[wt%] $MnO_2$ the Pyroelectrics coefficient was $6.6{\times}10^{-8}[C/cm^2.^{\circ}C]$, respectibly.

• Proceedings of the KIEE Conference
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• 1993.07b
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• pp.1119-1121
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• 1993

The PSN-PT-PZ ceramics doped with the Mn-oxide(0.5wt%) were fabricated by the mixed oxide method at 1250($^{\circ}C$) for 2(hr) and then the dielectric and pyroelectric properties were investigated with the compositions. In the 0.05PSN-0.4PT-0.55PZ specimen with 0.5(wt%) $MnO_2$, the pyroelectric coefficient was $6.6{\times}10^{-8}(C/Cm^2^{\circ}C)$, and the figure of merits for pyroelectric current and voltage were $27{\times}10^{-9},\;45{\times}10^{-12}$(C.Cm/J), respectibly.

• Journal of the Korean Ceramic Society
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• v.36 no.12
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• pp.1287-1295
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• 1999

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.20 no.2
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• pp.124-129
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• 2007

Dielectric and piezoelectric properties of $0.57Pb(Sc_{1/2}Nb_{1/2})O_{3}-0.43PbTiO_{3}$, which is the morphotropic phase boundary composition for the PSN-PT system, were investigated as a function of $Fe_{2}O_{3},\;Nb_{2}O_{5}\;and\;MnO_{2}$ addition 0 wt% to 0.9 wt%. The maximum dielectric constant of ${\varepsilon}_{33}/{\varepsilon}_{o}=2054$ and the minimum dielectric loss of $tan{\delta}=0.37\;%$ at room temperature were obtained at 0.1 wt% of $Fe_{2}O_{3}$ and 0.5 wt% of $MnO_{2}$ addition, respectively. With addition of 0.5 wt% $Nb_{2}O_{5}$ and $0.5\;wt%\;MnO_{2}$, the electromechanical coupling factor $k_{p}$ and mecanical quality factor $Q_{m}$ were significantly increased, respectively. The maximum electromechanical coupling factor $k_{p}=61.5\;%$ was obtained by addition of $Nb_{2}O_{5}$ and high mechanical quality factor $Q_{m}=919$ was obtained by addition of $MnO_{2}$. The $Q_{m}(=919)$ value is 3.3 times larger than that of non-doped 0.57PSN-0.43PT ceramics.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.959-962
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• 2001

In this study, the piezoelectric and dielectric properties and Temperature stability of resonant frequency with MnO$_2$doped 0.36Pb(Sc$_{1}$2/Nb$_{1}$2/)O$_3$- 0.25Pb(Ni$_{1}$3/Nb$_{2}$3/)O$_3$-0.39PbTiO$_3$(hereafter PSNNT) were investigated. The tetagonality of crystal structure was developed with increasing MnO$_2$additive content. With increasing MnO$_2$additive content, the electromechanical coupling factor and quality factor were increased. Electromechanical coupling k$_{p}$ and quality factor Q$_{m}$ at MnO$_2$doped with 2.0mol% were showed highest value of 55.6% and 252. In the case of specimen for MnO$_2$doped with 2mol%, temperature dependance of resonant frequency had a good properties.ies.