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Dielectric and Piezoelectric Properties of 0.57Pb(Sc1/2Nb1/2)O3-0.43PbTiO3 Ceramics with Dopant Additions

도펀트 첨가에 따른 0.57Pb(Sc1/2Nb1/2)O3-0.43PbTiO3 세라믹스의 유전 및 압전특성

  • Published : 2007.02.01

Abstract

Dielectric and piezoelectric properties of $0.57Pb(Sc_{1/2}Nb_{1/2})O_{3}-0.43PbTiO_{3}$, which is the morphotropic phase boundary composition for the PSN-PT system, were investigated as a function of $Fe_{2}O_{3},\;Nb_{2}O_{5}\;and\;MnO_{2}$ addition 0 wt% to 0.9 wt%. The maximum dielectric constant of ${\varepsilon}_{33}/{\varepsilon}_{o}=2054$ and the minimum dielectric loss of $tan{\delta}=0.37\;%$ at room temperature were obtained at 0.1 wt% of $Fe_{2}O_{3}$ and 0.5 wt% of $MnO_{2}$ addition, respectively. With addition of 0.5 wt% $Nb_{2}O_{5}$ and $0.5\;wt%\;MnO_{2}$, the electromechanical coupling factor $k_{p}$ and mecanical quality factor $Q_{m}$ were significantly increased, respectively. The maximum electromechanical coupling factor $k_{p}=61.5\;%$ was obtained by addition of $Nb_{2}O_{5}$ and high mechanical quality factor $Q_{m}=919$ was obtained by addition of $MnO_{2}$. The $Q_{m}(=919)$ value is 3.3 times larger than that of non-doped 0.57PSN-0.43PT ceramics.

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References

  1. 박재환, '$MnO_{2}$ 첨가에 따른 Pb($Mg_{1/3}Nb_{2/3}$)$O_3$계 완화형 강유전체에서의 전기적 물성변화', 전기전자재료학회논문지, 14권, 7호, p. 562, 2001
  2. Y. Yamashita, K. Harada, Y. Hosono, S. Natsume, and N. Ichinose, 'Effect of B-site ions on the electromechanical coupling factors of Pb(B'B'')$O_3$-$PbTiO_3$ piezoelectric material', Jpn. J. AppL Phys., Vol. 37, p. 5288, 1998 https://doi.org/10.1143/JJAP.37.5288
  3. G. A. Smolenskii, V. A. Isupov, and A. I. Agranovskaya, 'New ferroelectric of complex composition of the type $A_{2}(B_{1}B_{2})O_{6}$', Soviet Phys.-Solid State(English Transl.), Vol. 1, No.1, p. 150, 1959
  4. V. J. Tenney, K. W. Hang, and R. E. Novak, 'Ferroelectric and structure properties of the Pb$(Sc_{1/2}Nb_{1/2})_{1-X}Ti_{X}O_{3}$ system', J. Am. Ceram. Soc., Vol. 51, No. 12, p. 671, 1968 https://doi.org/10.1111/j.1151-2916.1968.tb15925.x
  5. Y. Yamashita, 'Piezoelectric properties of niobium-doped Pb$(Sc_{1/2}Nb_{1/2})_{1-X}Ti_{X}O_{3}$ ceramic material near the morphotropic phase boundary', Jpn. J. AppL Phys., Vol. 33, No. 8, p. 4652, 1994 https://doi.org/10.1143/JJAP.33.4652
  6. Y. Yamashita, 'Improved ferroelectric properties of niobium-doped Pb$[(Sc_{1/2}Nb_{1/2})Ti]O_{3}$ ceramic material', Jpn. J. Appl. Phys., Vol. 32, No. 11A, p. 5036, 1993 https://doi.org/10.1143/JJAP.32.5036
  7. M. Adachi, E. Miyabukuro, and A. Kawabata, 'Preparation and properties of Pb$[(Sc_{1/2}Nb_{1/2})_{0.575} Ti_{0425}]O_{3}$ ceramics', Jpn. J. Appl. Phys., Vol.. 33, No. 9B, p. 5420, 1994 https://doi.org/10.1143/JJAP.33.5420
  8. N. A. Prattem, 'Review: The precise measurement of the density of small samples', J. Mat. Sci., Vol.. 16, p. 1737, 1981 https://doi.org/10.1007/BF00540619
  9. V. J. Tennery, K. W. Hang, and R. E. Novak, 'Ferroelectric and structural properties of the Pb$(Sc_{1/2}Nb_{1/2})_{1-X}Ti_{X}O_{3}$ system', J. Am. Ceram. Soc., Vol.. 51, No. 12, p. 671, 1968 https://doi.org/10.1111/j.1151-2916.1968.tb15925.x
  10. 김현재, 조봉희,정형진, 박창엽, 'Pb(Zr,Ti)$O_{3}$-Pb(Mg,Nb)$O_{3}$$MnO_{2}$ 첨가가 전기적 성질에 미치는 영향', 전기전자재료학회논문지, 1권, 2호, p. 152, 1988
  11. M. Kahn, 'Influence of grain growth on dielectric properties of Nb-doped $BaTiO_3$', J. Am. Ceram. Soc., Vol.. 54, No.9, p. 455, 1971 https://doi.org/10.1111/j.1151-2916.1971.tb12384.x
  12. K. Maruyama, Z. Chen, and M. Adachi, 'Phase diagram in la-modified Pb$(Sc_{1/2}Nb_{1/2})O_{3}$- binary ceramics system', Jpn. J. Appl. Phys., Vol.. 36, No. 12A, p. 7272, 1997 https://doi.org/10.1143/JJAP.36.7272
  13. 임은경, 김창일, 이영진, 임종인, 백종후, '액츄에이터 응용을 위한 Pb$(Ni_{1/3}Nb_{2/3})O_{3}$-- 세라믹스의 압전특성에 미치는 $Fe_{2}O_{3}$첨가영향', 전기전자재료학회논문지, 19권, 10호, p. 935, 2006 https://doi.org/10.4313/JKEM.2006.19.10.935
  14. A. Amin, R. E. Newnham, L. E. Cross, S. Nomura, and D. E. Cox, 'Ordering in Pb $(Mg_{1/3}Nb_{2/3})O_{3}$-Pb$(Mg_{1/2}W_{1/2})O_{3}$ solid solution', J. Solid State Chemistry, Vol.. 35, p. 267, 1980 https://doi.org/10.1016/0022-4596(80)90502-2
  15. W. R. Xue, P. W. Lu, and W. Huebner, 'Effect of cakia additions on the electromechanical properties of samarium-modified lead titanate ceramics', Proc. of IEEE, p. 101, 1995