• Bulletin of the Korean Chemical Society
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• v.31 no.1
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• pp.171-173
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• 2010

• Journal of Industrial Technology
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• v.24 no.A
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• pp.215-226
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• 2004

A dynamic reliability model which can take into account the time history of loading sequences may be applied to the analyses of the hydraulic stability of armor units on rubble-mound breakwaters. All the parameters related to the stability of structures have been considered to be constants in the deterministic model until now. Thus, it is impossible to study the effects of some uncertainties of the related random variables on the stability of structures. In this paper, the dynamic reliability model can be developed by POT(Peak Over Threshold) method in order to take into account the time history of loading sequences and to investigate the temporal behaviors of stability of structure with its loading history. Finally, it is confirmed that the results of dynamic reliability model agree with straight- forwardly those of AFDA(Approximate Full Distribution Approach) of the static reliability model for the same input conditions. In addition, the temporal behaviors of probability of failure can be studied by the dynamic reliability model developed to analyze the hydraulic stability of armor units on rubble-mound breakwaters. Therefore, the present results may be useful for the management of repair and maintenance over the whole life cycle of structure.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.656-658
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• 2011

A green and efficient method for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones and -thiones through one-pot three-component reaction of ethyl acetoacetate, an aryl aldehyde, and urea or thiourea in acetonitrile using silica gel-supported polyphosphoric acid (PPA-$SiO_2$) as catalyst is described. Compared to the classical Biginelli reaction conditions, the present methodology offers several advantages such as high yields, relatively short reaction times, mild reaction condition and a recyclable catalyst with a very easy work up.

• Advances in nano research
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• v.5 no.2
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• pp.171-178
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• 2017

Superparamagnetic Zinc ferrite submicropheres are firstly synthesized via a one-pot solvothermal approach at $200-215^{\circ}C$ for 4-8 hours. $ZnCl_2$, $FeCl_3$ and NaAc are used as precursors with ethylene glycol solvent. The X-ray diffraction (XRD) data indicate that $ZnFe_2O_4$ nanoparticles with the grain size around $15{\pm}3nm$ can be successfully synthesized via the one-pot method. The scanning/transmission electronic microscope (SEM/TEM) images further show the samples are submicrospheres self-assembled by nanoparticles with size about 375-500 nm changed with reaction conditions. Room-temperature vibration magnetic strength measurements (VMS) demonstrates the as-obtained $ZnFe_2O_4$ submicrospheres show prefect superparamagnetism, whose coercivity force and remanence are practically nil. The reaction temperature and time influence on the crystallinity, diameter, saturated magnetic intensity and morphology of the particles.

• Journal of Korea Water Resources Association
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• v.45 no.3
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• pp.275-290
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• 2012

In this study, we have developed an optimal time distribution model through extraction of peaks over threshold (POT) series. The median values for annual maximum rainfall dataset, which are obtained from the magnetic recording (MMR) and the automatic weather system(AWS) data at Seoul meteorological observatory, were used as the POT criteria. We also suggested the improved methodology for the time distribution of extreme rainfall compared to Huff method, which is widely used for time distributions of design rainfall. The Huff method did not consider changing in the shape of time distribution for each rainfall durations and rainfall criteria as total amount of rainfall for each rainfall events. This study have suggested an extracting methodology for rainfall events in each quartile based on interquartile range (IQR) matrix and selection for the mode quartile storm to determine the ranking cosidering weighting factors on minutely observation data. Finally, the optimal time distribution model in each rainfall duration was derived considering both data size and characteristics of distribution using kernel density function in extracted dimensionless unit rainfall hyetograph.

• Korean Journal of Medicinal Crop Science
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• v.11 no.2
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• pp.135-142
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• 2003

This study was conducted to clarify on germination rate enhancement effect and to develope the growing seedling method on Sorbus commixta Hedl. The results were follows; The optimum temperature of stratification and germination of mountain ash was $5^{\circ}C$ the seed germination rate in wet stratification with sand at $5^{\circ}C$ for 90 days was 22.6% and the highest germination of 78.9% was observed when seed was soaked in BA 200ppm for 20 minute after stratification for 90 days at $5^{\circ}C$. The highest germination of large chinese hawthorn was 11.1% when seed was soaked BA 50ppm for 20 minute after stratification 90 days at $5^{\circ}C$. Emergence ratio in box raising seedling and pot seedling showed high, 93 and 95%. Root length and dry root weight in pot seedling for 50 days showed higher than that of direct seedling and box raising seedling, Plant height and dry leaf weight in box raising seedling showed higher than that of pot seedling and direct seedling. The growth increment of seedling was high between 40 days and 50 days after seedling. The excellent seedling of mountain ash was produced in pot seedling for 50 days.

• Proceedings of the PSK Conference
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• 2003.04a
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• pp.239.2-240
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• 2003

We have recently described the novel synthetic method for N-protected amines from various ethers using chlorosulfonyl isocyanate(CSI) and found that the mechanism of our CSI reaction is a competitive reaction of SN1 and SNi mechanism according to the stability of carbocation intermediate. Forthermore. we developed the regioselective and diastereoselective one-pot synthetic method for 1,2-amino alcohol, through the reaction of di-and tribenzyl thers with CSI, and invetigated its mechanism. (omitted)

• Proceedings of the PSK Conference
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• 2003.04a
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• pp.242.2-243
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• 2003

We have developed the novel one-pot synthetic method for regioselective N-protected amines, carbamates as a protective group of amines, through the reaction of various ethers with chlorosulfonyl isocyanate (CSJ). This synthetic method provides a simple and convenient alternative for the formation of carbamates, such as -NHMoc, -NHPoc. -NHCbz, -NHPnz, -NHTroc and -NHAloc, by varying the alkyl moiety of ethers. (omitted)

• Journal of Integrative Natural Science
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• v.10 no.3
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• pp.171-174
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• 2017

Non-hydrolyzable fluorinated organosilicon compounds as an eletrolyte for the application of lithium-ion batteries (LIB) are synthesized. New synthetic method for the perfluorinated organosilicon compound containing spacer such as ethyl and propyl group with cyano moiety instead of ethylene glycol to prevent hydrolysis and to promote conductivity are developed in one pot reaction with moderately high yield. Air-sensitive boron trifluoride etherate is no longer required in this reaction. The products are characterized by spectroscopic analysis.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.28 no.3
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• pp.386-389
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• 1983

An experiment was conducted to establish the appropriate tranaplanting method of sesame seedlings. Covering of polyethylene film on nursery bed resulted in more adventitious roots and better growth after transplanting. Nursery soil showed the best results when it was mixed with the equal amounts of soil, sand and compost. The most healthy seedlings were raised by spot seeding of 5${\times}$5 cm distance and 4 cm bed-depth. Compared to direct seeding on June 15, sesame seeded on June 10 followed by transplanting on June 30 flowered 4 days earlier and produced more capsules per plant and 18% more seed yields.