Browse > Article
http://dx.doi.org/10.13160/ricns.2017.10.3.171

New Synthetic Method of Perfluoro-Silanes for the Stable Electrolyte of Lithium Ion Battery Application  

Koh, Kyungkuk (Department of Chemistry, Chosun University)
Sohn, Honglae (Department of Chemistry, Chosun University)
Publication Information
Journal of Integrative Natural Science / v.10, no.3, 2017 , pp. 171-174 More about this Journal
Abstract
Non-hydrolyzable fluorinated organosilicon compounds as an eletrolyte for the application of lithium-ion batteries (LIB) are synthesized. New synthetic method for the perfluorinated organosilicon compound containing spacer such as ethyl and propyl group with cyano moiety instead of ethylene glycol to prevent hydrolysis and to promote conductivity are developed in one pot reaction with moderately high yield. Air-sensitive boron trifluoride etherate is no longer required in this reaction. The products are characterized by spectroscopic analysis.
Keywords
Silane; Perfluoro Compound; Synthesis; Electrolyte; Lithium Ion Battery;
Citations & Related Records
연도 인용수 순위
  • Reference
1 B. Scrosati, " History of lithium batteries", J. Solid State Electrochem., Vol. 15, pp. 1623-1630, 2011.   DOI
2 M. S. Ding and T. R. Jow, "Physicochemical properties of non-aqueous solvents and electrolytes for lithium battery applications", ECS Trans., Vol. 16, pp. 183-214, 2009.
3 N. A. A. Rossi and R. West, "Silicon-containing liquid polymer electrolytes for application in lithium ion batteries", Polym. Int., Vol. 58, pp. 267-272, 2009.
4 K. Amine, Q. Wang, D. R. Vissers, Z. Zhang, N. A. Rossi, and R. West, "Novel silane compounds as electrolyte solvents for Li-ion batteries", Electrochem. Commun., Vol. 8, pp. 429-433, 2006.   DOI
5 K.-Y. Tse, L. Z. Zhang, S. E. Baker, B. M. Nichols, R. West, and R. J. Hamers, "Vertically aligned carbon nanofibers coupled with organosilicon electrolytes: electrical properties of a high-stability nanostructured electrochemical interface", Chem. Mater., Vol. 19, pp. 5734-5741, 2007.   DOI
6 M. G. Voronkov, Yu. L. Frolov, V. M. D'yakov, N. N. Chipanina, L. I. Gubanova, G. A. Gavrilova, L. V. Klyba, and T. N. Aksamentova, "Aroyloxymethyl) trifluorosilanes: A new class of pentacoordinate silicon compounds, J. Organomet. Chem., Vol. 201, pp. 165-177, 1980.   DOI
7 U. H. Berlekamp, A. Mix, B. Neumann, H.-G. Stammler, and P. Jutzi, "2-(Dimethylphosphinomethyl)-and 2-(methylthiomethyl)phenyl silicon compounds: higher coordination with soft donors", J. Organomet. Chem., Vol. 667, pp. 167-175, 2003.   DOI
8 N. Kano, F. Komatsu, M. Yamamura, and T. Kawashima, "Reversible photoswitching of the coordination numbers of silicon in organosilicon compounds bearing a 2-(phenylazo)phenyl group", J. Am. Chem. Soc., Vol. 128, pp. 7097-7109, 2006.   DOI
9 N. Kano, M. Yamamura, and T. Kawashima, "2,2'-Disilylazobenzenes featuring double intramolecular nitrogen...silicon coordination: a photoisomerizable fluorophore", Dalton Trans., Vol. 44, pp. 16256-16265, 2015.   DOI
10 M. G. Voronkov, N. F. Chernov, A. I. Albanov, O. M. Trofimova, Y. I. Bolgova, and E. A. Grebneva, Appl. Organomet. Chem., Vol. 21, pp. 601-603, 2007.   DOI
11 A. E. Pestunovich, E. P. Doronina, A. I. Albanov, and M. G. Voronkov, "Reaction of diphenyl[2-triethoxysilyl)ethyl]phosphine oxide with boron trifluoride etherate", Russ. J. Gen. Chem., Vol. 80, pp. 1603-1607, 2010.