• Title/Summary/Keyword: PA

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Preparation and Property of POSS-Based Organic-Inorganic Hybrid Filler and Polyamide Thermoplastic Elastomer (PA-TPE)/POSS Nanocomposite (POSS 기반 유-무기 하이브리드 충전제와 폴리아미드계 TPE로 이루어진 나노복합체의 제조 및 특성)

  • Han, Jae Hee;Kim, Hyung Joong
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.34-40
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    • 2013
  • Commercially available polyamide thermoplastic elastomer (PA-TPE) was blended with hybrid filler which was prepared by means of the reaction between polyhedral oligomeric silsesquioxane (POSS) containing amine group and toluene diisocyanate (TDI)-caprolactam (CL) to explore the effect of blending the hybrid filler with the TPE. The chemical structure of the filler was identified by using FTIR and $^1H$ NMR. The composites, PA-TPE/POSS-(TDI+CL), which were the blends of TDI+CL modified POSS filler and PA-TPE up to 7 wt%, showed better elastic recovery delivered from lower tension setting compared to the PA-TPE and the PA-TPE/octaphenyl POSS blend. In addition the tensile strength and the initial modulus increased with increasing the hybrid filled content. Consequently it was assumed that the POSS-(TDI+CL) filler was a suitable material for enhancing strength and modulus without loss of elastic properties for the original PA-TPE.

Surface Modification of Latex with Parylene by Chemical Vapor Deposition (화학기상증착법의 Parylene 코팅에 의한 천연 라텍스 표면개질)

  • Song, Jeom-Sik;Choi, Seo-Yoon;Jung, Seong-Hee;Cha, Gook-Chan;Lee, Suk-Min;Mun, Mu-Seong
    • Elastomers and Composites
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    • v.39 no.4
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    • pp.301-308
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    • 2004
  • Three types of parylene (PA-N, PA-C, PA-D) were used for coating the surface on natural latex rubbers in order to improve surface characteristics including mechanical properties and biocompatibility. The parylene coating was the CVD (chemical vapor deposition) method, and the surface properties of the modified latex were measured. Annealing effects on the mechanical properties of the coated latex were also investigated. The adhesion between latex and parylene was good for all the types of parylene used. As annealing temperature was increased, latex modified with PA-N became more hydrophobic, while the latex treated with PA-C and PA-D became more hydrophilic. As the annealing temperature was raised, the tensile strength was increased, and the elongation was decreased. The biocompatibility was noticeably improved on the latex surface modified with the parylenes through CVD method.

Preparation and Characterization of Polyamide4(PA4)-Polyurethane(PU)-PA4 Triblock Copolymers (Polyamide4(PA4)-Polyurethane(PU)-PA4 삼블록 공중합체의 제조 및 특성)

  • Park, Ki Wan;Kim, Dong Hyun;Kim, Hyung Joong
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.9-15
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    • 2014
  • Polyamide4 (PA4)-polyurethane (PU)-PA4 triblock copolymers were synthesized by isocynated (NCO)-terminated PU prepared from 4,4'-diphenyl methane diisocyante (MDI) and polytetramethylene glycol (PTMG) as an initiator and potassium pyrrolidonate (P-py) as a catalyst for anionic ring opening polymerization of 2-pyrrolidone. Subsequently copolymer was controlled to contain different or same molecular weight of PA4 hard block with same or different molecular weight of PU soft block in order to investigate the effects of those differences on various properties of triblock copolymers as a thermoplastic elastomer. As the results shown in typical properties of block copolymeric elastomers, the mechanical strength and melting point ($T_m$) of the copolymers increased with an increase in molecular weight of PA4 block while the elongation at break increased with an increase in that of PU block.

Classification of Shear Strength according to Breccia Content in Fault Core (단층각력 함량에 따른 전단강도의 분류)

  • Yun, Hyun-Seok;Moon, Seong-Woo;Seo, Yong-Seok
    • Economic and Environmental Geology
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    • v.53 no.2
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    • pp.167-181
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    • 2020
  • Analysis of variance (ANOVA) and multiple comparison analysis were performed for shear strengths categorized by breccia content of 5 wt.% (Case-I), 10 wt.%, (Case-II) and 15 wt.% (Case-III) in fault cores. The relationship between breccia contetnt and shear strength was quantitatively classified by calculating the mean and standard deviation of shear strength for each population in each case and then the grouping the breccia contents that had a statistically similar effect on the dispersion of shear strength. As a result, shear strength was clearly classified into group 1 (breccia content of 0-15 wt.%) and group 2 and 3 (breccia coantent of 15-30 wt.% and 30 wt.% or more) in Case-III. Shear strength of the standard line at breccia content of 15 wt.% were determined to be 43.6 kPa, 77.6 kPa, and 118.6 kPa at each normal stress (54 kPa, 108 kPa, and 162 kPa), respectively. In addition, the distribution range of cohesions is 0-43.6 kPa at breccia content of 15 wt.% or less, and 0-70.0 kPa at 15 wt.% or more. Distribution range of friction angles is 0-45.7 ° at breccia content of 15 wt.% or less, and 16.7-57.5 ° at 15 wt.% or more.

Regulation of the plasminogen activator activity and inflammatory environment via transforming growth factor-beta regulation of sperm in porcine uterine epithelial cells

  • Kim, Su-jin;Cheong, Hee-Tae;Park, Choon-keun
    • Journal of Animal Reproduction and Biotechnology
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    • v.35 no.4
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    • pp.297-306
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    • 2020
  • The aims of the present study were to confirm that regulation of the PA and environment via TGF-β regulation of sperm by Percoll-separated in porcine uterine epithelial cells. And, it was performed to identify the cytokines (TGF-β1, 2 and 3, TGF-β receptor1 and 2; interleukin, IL-6, IL-8) and PA-related genes (urokinase-PA, uPA; tissue-PA, tPA; PA inhibitor, PAI; uPA-receptor, uPAR) by spermatozoa. The experiment used porcine uterus epithelial cells (pUECs) and uterine tissue epithelial cells, Boar sperm were separated by discontinuous Percoll density gradient (45/90%), and tissues were co-incubated with spermatozoa, followed by real-time PCR. PA activity was measured of sperm by discontinuous Percoll density gradient (45/90%) for 24 hours. To measure viability and acrosome damage of sperm double stained propidium iodide (PI) and SYBR-14 or FITC-PNA were used. In results, binding ratio of Percoll-separated sperm was found no differences, but sperms isolated from 90% Percoll layer reduced PA activity (p < 0.05). when co-cultured sperm selected Percoll in porcine uterus tissues epithelial cells, 90% layer sperm increased TGF-β R1, contrastively tPA and PAI-1 in comparison with control (p < 0.05). 45% sperm was decreased the expression of uPA (p < 0.05). TGF-β decreased PA activity in the supernatant collected from pUECs (p < 0.05). Especially, The group including uPA, PAI-1 were induce sperm intact, while it was reduced in sperm damage when compared to control (p < 0.05). Also, there was no significant difference group of tPA and tPA+I in the dead sperm and acrosome damage compared to control. The expression of tPA and PAI showed a common response. Percoll-separated spermatozoa in 90% layer reduced tPA and IL-related gene mRNA expression. Thus, Percoll-sparated sperm in 90% layer show that it can suppress inflammation through increased expression of TGF-β and downregulation of PA and IL in epithelial cells compared to 45% layer Percoll.

Comparison Between Travel Demand Forecasting Results by Using OD and PA Travel Patterns for Future Land Developments (장래 개발계획에 의한 추가 통행량 분석시 OD 패턴적용과 PA 패턴적용의 분석방법 비교)

  • Kim, Ikki;Park, Sang Jun
    • Journal of Korean Society of Transportation
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    • v.33 no.2
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    • pp.113-124
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    • 2015
  • The KOTI(Korea Transport Institute) released the new version of KTDB(Korea Transport DataBase) in public. The new KTDB is different from the past KTDB in using the concept of trip generation and trip attraction instead of using the concept of Origin-Destination (OD), which was used in the past KTDB. Thus, the appropriate analysis method for future travel demand became necessary for the new type of KTDB. The method should be based on the concept of PA(Production-Attraction). This study focused on analysis of trip generation and trip distribution related to newly generated trips by future land developments. The study also described clearly the standardized forecasting process and methods with PA travel tables. The study showed that the analysis results with OD-based analysis can be different from the results with PA-based analysis in forecasting travel demand for a simple example case even though they used exactly same orignal travel data. Therefore, this study emphasized that a proper method should be applied with the new PA-based KTDB. It is necessary to prepare and disseminate guidelines of the proper forecasting method and application with PA-based travel data for practician.

Relative Bio-Availability of Different Phosphorus Supplements in Broiler and Layer Chicken Diets

  • Rama Rao, S.V.;Ramasubba Reddy, V.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.7
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    • pp.979-985
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    • 2001
  • Two experiments on commercial broiler chickens (3-37 d) and WL layers (252-364 d) were conducted to study the relative bioavailability of phosphorus (P) from different P supplements in comparison to tricalcium phosphate (TCP), at constant dietary calcium (Ca):P ratio. The P sources tested were dicalcium phosphate (DCP), steam sterilized bone meal (SSBM), commercial mineral mixture (CMM), phosphoric acid (PA) and a combination of CMM + PA. Fluorine (F) content in CMM and SSBM was 13.12 and 0.14 g/kg, respectively. In commercial broiler diets, DCP, SSBM or PA could be used as supplemental P sources without affecting (p<0.05) weight gain, feed intake, tibia ash and, P and Ca contents in tibia ash when compared to TCP. Severity of leg abnormality and deposition of F in bone were higher (p<0.05) in group fed CMM. P retention and serum inorganic P content was significantly reduced (p<0.05) in CMM fed birds compared to those fed TCP, SSBM, PA or CMM+PA. Among other P sources (TCP, SSBM, PA and CMM+PA) the serum inorganic P levels did not vary significantly (p<0.05). The P retention also significantly reduced in CMM fed groups compared to those fed DCP or PA. The P retention significantly increased from 0.183 to 0.216 units by supplementation of PA to CMM diet. In layers, egg production was not affected by replacing TCP with DCP, SSBM, PA or CMM+PA, but significantly (p<0.05) reduced with CMM. Feed (kg)/kg egg mass, egg weight, shell quality (shell weight and shell thickness) and serum Ca levels were not influenced by dietary variation in P source. The poor performance of both broilers and layers fed on CMM based diets could be attributed to the presence of hlgher levels of F (647.8 and 630.1 mg/kg, respectively) and low P utilization. Based on growth, bone mineralization and P retention it is concluded that DCP, SSBM or PA can be used as alternatives to TCP in broiler diets. In WL layer diets, in addition to above P sources, CMM can also be used as supplemental P source by replacing one half of P from CMM with PA without affecting egg production and shell quality.

Strength Properties and Durability of Polymer Concrete Using Mixed Waste Plastics (복합재질 폐플라스틱을 재활용한 폴리머콘크리트의 강도 특성 및 내구성)

  • Joo, Myung-Ki;Lee, Youn-Su;Kim, Moon-Chan;Kim, Youn-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.219-226
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    • 2006
  • The effects of binder content and PA content on the flexural, compressive and impact strengths, water absorption and frezzing and thawing of polymer concrete using mixed waste plastics are examined. As a result the flexural, compressive and impact strengths of the polymer concretes using mixed waste plastics tend to increase with increasing binder content and filler content, regardless of the PA content. The flexural, compressive and impact strengths of the polymer concretes using mixed waste plastics decrease with increasing PA content. The water absorption of the polymer concretes using mixed waste Plastics tend to decreased with increasing binder content, regardless of the PA content. The durability factor of the polymer concretes using mixed waste plastics tend to increased with increasing binder content. However, the durability factor of the polymer concretes using mixed waste plastics tend to decreased with increasing PA content.

PaCO2 at Early Stage is Associated with Adverse Cardiovascular Events in Acute Carbon Monoxide Poisoning (급성 일산화탄소 중독 환자에서 응급실 내원 초기 동맥혈 이산화탄소 분압의 임상적 의미)

  • Yang, Keun Mo;Chun, Byeong Jo;Moon, Jeong Mi;Cho, Young Soo
    • Journal of The Korean Society of Clinical Toxicology
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    • v.17 no.2
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    • pp.86-93
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    • 2019
  • Purpose: The objective was to determine the association between PaCO2 and adverse cardiovascular events (ACVEs) in carbon monoxide (CO)-poisoned patients. Methods: This retrospective study included 194 self-breathing patients after CO poisoning with an indication for hyperbaric oxygen therapy and available arterial blood gas analysis at presentation and 6 hours later. The baseline characteristics and clinical course during hospitalization were collected and compared. The mean PaCO2 during the first 6 hours after presentation was calculated. Results: The incidence rates of moderate (30 mmHg< PaCO2 <35 mmHg) or severe (PaCO2 ≤30 mmHg) hypocapnia at presentation after acute CO poisoning were 40.7% and 26.8%, respectively. The mean PaCO2 during the first 6 hours was 33 (31-36.7) mmHg. The incidence of ACVEs during hospitalization was 50.5%. A significant linear trend in the incidence of ACVEs was observed across the total ranges of PaCO2 variables. In multivariate regression analysis, mean PaCO2 was independently associated with ACVEs (OR 0.798 (95% CI 0.641-0.997)). Conclusion: Mean PaCO2 during the first 6 hours was associated with increased ACVEs. Given the high incidence of ACVEs and PaCO2 derangement and the observed association between PaCO2 and ACVEs, this study suggests that 1) PaCO2 should be monitored at the acute stage to predict and/or prevent ACVEs; and 2) further study is needed to validate this result and investigate early manipulation of PaCO2 as treatment.

Implementation of Public Address System Using Anchor Technology

  • Seungwon Lee;Soonchul Kwon;Seunghyun Lee
    • International journal of advanced smart convergence
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    • v.12 no.3
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    • pp.1-12
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    • 2023
  • A public address (PA) system installed in a building is a system that delivers alerts, announcements, instructions, etc. in an emergency or disaster situation. As for the products used in PA systems, with the development of information and communication technology, PA products with various functions have been introduced to the market. PA systems recently launched in the market may be connected through a single network to enable efficient management and operation, or use voice recognition technology to deliver quick information in case of an emergency. In addition, a system capable of locating a user inside a building using a location-based service and guiding or responding to a safe area in the event of an emergency is being launched on the market. However, the new PA systems currently on the market add some functions to the existing PA system configuration to make system operation more convenient, but they do not change the complex PA system configuration to reduce facility costs, maintenance, and management costs. In this paper, we propose a novel PA system configuration for buildings using audio networks and control hierarchy over peer-to-peer (Anchor) technology based on audio over IP (AoIP), which simplifies the complex PA system configuration and enables convenient operation and management. As a result of the study, through the emergency signal processing algorithm, fire broadcasting was made possible according to the detection of the existence of a fire signal in the Anchor system. In addition, the control device of the PA system was replaced with software to reduce the equipment installation cost, and the PA system configuration was simplified. In the future, it is expected that the PA system using Anchor technology will become the standard for PA facilities.