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http://dx.doi.org/10.7317/pk.2013.37.1.34

Preparation and Property of POSS-Based Organic-Inorganic Hybrid Filler and Polyamide Thermoplastic Elastomer (PA-TPE)/POSS Nanocomposite  

Han, Jae Hee (Department of Advanced Polymer Material Engineering, Major in Polymer Engineering, Kong-ju National University)
Kim, Hyung Joong (Department of Advanced Polymer Material Engineering, Major in Polymer Engineering, Kong-ju National University)
Publication Information
Polymer(Korea) / v.37, no.1, 2013 , pp. 34-40 More about this Journal
Abstract
Commercially available polyamide thermoplastic elastomer (PA-TPE) was blended with hybrid filler which was prepared by means of the reaction between polyhedral oligomeric silsesquioxane (POSS) containing amine group and toluene diisocyanate (TDI)-caprolactam (CL) to explore the effect of blending the hybrid filler with the TPE. The chemical structure of the filler was identified by using FTIR and $^1H$ NMR. The composites, PA-TPE/POSS-(TDI+CL), which were the blends of TDI+CL modified POSS filler and PA-TPE up to 7 wt%, showed better elastic recovery delivered from lower tension setting compared to the PA-TPE and the PA-TPE/octaphenyl POSS blend. In addition the tensile strength and the initial modulus increased with increasing the hybrid filled content. Consequently it was assumed that the POSS-(TDI+CL) filler was a suitable material for enhancing strength and modulus without loss of elastic properties for the original PA-TPE.
Keywords
POSS; hybrid filler; polyamide; thermoplatic elastomer; nanocomposite;
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