• Title/Summary/Keyword: Oxygen resistance

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Siderophore-producing rhizobacteria reduce heavy metal-induced oxidative stress in Panax ginseng Meyer

  • Huo, Yue;Kang, Jong Pyo;Ahn, Jong Chan;Kim, Yeon Ju;Piao, Chun Hong;Yang, Dong Uk;Yang, Deok Chun
    • Journal of Ginseng Research
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    • v.45 no.2
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    • pp.218-227
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    • 2021
  • Background: Panax ginseng is one of the most important medicinal plants and is usually harvested after 5 to 6 years of cultivation in Korea. Heavy metal (HM) exposure is a type of abiotic stress that can induce oxidative stress and decrease the quality of the ginseng crop. Siderophore-producing rhizobacteria (SPR) may be capable of bioremediating HM contamination. Methods: Several isolates from ginseng rhizosphere were evaluated by in vitro screening of their plant growth-promoting traits and HM resistance. Subsequently, in planta (pot tests) and in vitro (medium tests) were designed to investigate the SPR ability to reduce oxidative stress and enhance HM resistance in P. ginseng inoculated with the SPR candidate. Results: In vitro tests revealed that the siderophore-producing Mesorhizobium panacihumi DCY119T had higher HM resistance than the other tested isolates and was selected as the SPR candidate. In the planta experiments, 2-year-old ginseng seedlings exposed to 25 mL (500 mM) Fe solution had lower biomass and higher reactive oxygen species level than control seedlings. In contrast, seedlings treated with 108 CFU/mL DCY119T for 10 minutes had higher biomass and higher levels of antioxidant genes and nonenzymatic antioxidant chemicals than untreated seedlings. When Fe concentration in the medium was increased, DCY119T can produce siderophores and scavenge reactive oxygen species to reduce Fe toxicity in addition to providing indole-3-acetic acid to promote seedling growth, thereby conferring inoculated ginseng with HM resistance. Conclusions: It was confirmed that SPR DCY119T can potentially be used for bioremediation of HM contamination.

Improvement of the Mechanical Property and Corrosion Resistivity of the Ni-/Fe-based Hybrid Coating Layer using High-velocity Oxygen Fuel Spraying by Heat Treatment (열처리를 통한 Ni/Fe계 하이브리드 용사 코팅층의 기계적 특성 및 내식성 향상)

  • Kim, Jungjoon;Lee, Yeonjoo;Kim, Song-Yi;Lee, Jong-Jae;Kim, Jae-hun;Lee, Seok-Jae;Lim, Hyunkyu;Lee, Min-Ha;Kim, Hwi-Jun;Choi, Hyunjoo
    • Journal of Powder Materials
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    • v.29 no.3
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    • pp.240-246
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    • 2022
  • Novel Ni- and Fe-based alloys are developed to impart improved mechanical properties and corrosion resistance. The designed alloys are manufactured as a powder and deposited on a steel substrate using a high-velocity oxygen-fuel process. The coating layer demonstrates good corrosion resistance, and the thus-formed passive film is beneficial because of the Cr contained in the alloy system. Furthermore, during low-temperature heat treatment, factors that deteriorate the properties and which may arise during high-temperature heat treatment, are avoided. For the heattreated coating layers, the hardness increases by up to 32% and the corrosion resistance improves. The influence of the heat treatment is investigated through various methods and is considered to enhance the mechanical properties and corrosion resistance of the coating layer.

Abnormality of P2O5-Na2O-MgO Glasses by Raman and Infrared Spectroscopy (라만과 적외선 분광기를 이용한 P2O5-Na2O-MgO 유리의 이상성에 관한 연구)

  • Lee, Byung-Chul;Kwon, Young-Jun;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.265-271
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    • 2002
  • Density, water resistance, Raman and infrared spectroscopy were used to investigate the change of structural characteristics with the composition of phosphate galss samples made by melting method. The structural abnormality of the density and water resistance were rapidly increased and shown near the 60mol% of $P_2O_5$. This result could be explained by the structural changes owing to the strong shrinkage of glass network by the coordination of DBO(Double-Bonded Oxygen) around $Mg^{2+}$ cations. In addition, it seems that the DBOs coordinating $Mg^{2+}$ cations lose its characteristics of double bonding and resonate with other NBOs(Non-Bonding Oxygen).

Optimization of an Advanced Oxidation with Ozone and Ceramic Membrane Integrated Process for Greywater Reuse (중수 재이용을 위한 오존 고도산화 및 세라믹 분리막 일체형 공정의 최적화 연구)

  • Lee, Jonghun;Rho, Hojung;Park, Kwang Duck;Woo, Yun Chul
    • Journal of Korean Society on Water Environment
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    • v.37 no.6
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    • pp.433-441
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    • 2021
  • The aim of this study was to optimize the ozonation and ceramic membrane integrated process for greywater reclamation. The integrated process is a repeated sequential process of filtration and backwash with the same ceramic membrane. Also, this study used ozone and oxygen gas for the backwashing process to compare backwashing efficiency. The study results revealed that the optimum filtration and backwash time for the process was 10 minutes each when comparing the filtrate flow and membrane recovery rate. The integrated process was operated at three different operating conditions with i) 10 minutes for filtration and 10 minutes for ozonation, ii) 10 minutes for filtration and 10 minute for oxygen aeration, and iii) continuous filtration without any aeration for synthetic greywater. The integrated process with ozone backwashing could produce 0.55 L/min of filtrate with an average of 18.42% permeability recovery, while the oxygen backwashing produced 0.47 L/min and 6.26%, respectively. And without any backwashing, the integrated process could produce 0.29 L/min. This shows that the ozone backwash process is capable of periodically recovering from membrane fouling. The resistance of the fouled membrane was approximately 34.4% for the process with ozone backwashing, whereas the resistance was restored by 10.8% for the process with oxygen backwashing. Despite the periodical ozone backwashing and chemical cleaning, irreversible fouling gradually increased approximately 3 to 4%. Approximately 97.6% and 15% turbidity and TOC were removed by ceramic membrane filtration, respectively. Therefore, the integrated process with ozonation and ceramic membrane filtration is a potential greywater treatment process.

A Study about Decrease of Oxygen Permeability with Adding Glass Flakes and (3-Aminopropyl)triethoxysilane on Polyimide Films (Glass Flake 및 (3-Aminopropyl)triethoxysilane 첨가에 따른 폴리이미드 필름의 산소투과도 감소 연구)

  • Ha-Yoon Nah;Taehee Kim;Haryeong Choi;Ji-Seoung Kim;Won-Jun Lee;Eunkyung Jeon;Joon Hyuk Lee;Hyung-Ho Park
    • Journal of the Microelectronics and Packaging Society
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    • v.31 no.3
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    • pp.80-86
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    • 2024
  • Polyimide has advantages that are different with other polymers, such as high thermal stability, heat resistance, and high chemical resistance. Various application methods for Polyimide have been studied. In this study, research was conducted to manufacture Polyimide films. While implementing Polyimide films with excellent adhesion and pencil hardness through optimized manufacturing conditions, the applicability as a packaging material was considered by adding glass flakes to reduce oxygen permeability. As a result, Polyimide films with glass flakes and (3-Aminopropyl)triethoxysilane have a thickness of about 50 ㎛ were uniformly implemented, and it was confirmed that the adhesion of Polyimide films was 4B, pencil hardness was 5H, and oxygen permeability was below 8.795 × 10-9 cc/s, respectively.

Reduced Titania Films with Ordered Nanopores and Their Application to Visible Light Water Splitting

  • Shahid, Muhammad;Choi, Seo-Yeong;Liu, Jingling;Kwon, Young-Uk
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2271-2275
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    • 2013
  • We report on the photoelectrochemical properties of partially reduced mesoporous titania thin films. The fabrication is achieved by synthesizing mesoporous titania thin films through the self-assembly of a titania precursor and a block copolymer, followed by aging and calcination, and heat-treatment under a $H_2$ (1 torr) environment. Depending on the temperature used for the reaction with $H_2$, the degree of the reduction (generation of oxygen vacancies) of the titania is controlled. The oxygen vacancies induce visible light absorption, and decrease of resistance while the mesoporosity is practically unaltered. The photoelectrochemical activity data on these films, by measuring their photocurrent-potential behavior in 1 M NaOH electrolyte under AM 1.5G 100 mW $cm^{-2}$ illumination, show that the three effects of the oxygen vacancies contribute to the enhancement of the photoelectrochemical properties of the mesoporous titania thin films. The results show that these oxygen deficient $TiO_2$ mesoporous thin films hold great promise for a solar hydrogen generation. Suggestions for the materials design for improved photoelectrochemical properties are made.

Anti-corrosion Properties of SiOxCy(-H) thin Films Synthesized and Oxidized by Atmospheric Pressure Dielectric Barrier Discharge (대기압 유전체배리어방전으로 합성 및 산화 처리된 SiOxCy(-H) 박막의 부식방지 특성)

  • Kim, Gi-Taek;Kim, Yoon Kee
    • Journal of Surface Science and Engineering
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    • v.53 no.5
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    • pp.201-206
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    • 2020
  • A SiOxCy(-H) thin film was synthesized by atmospheric pressure dielectric barrier discharge(APDBD), and a SiO2-like layer was formed on the surface of the film by oxidation treatment using oxygen plasma. Hexamethylcyclotrisiloxane was used as a precursor for the SiOxCy(-H) synthesis, and He gas was used for stabilizing APDBD. Oxygen permeability was evaluated by forming an oxidized SiOxCy(-H) thin film on a PET film. When the single-layer oxidized SiOxCy(-H) film was coated on the PET, the oxygen gas permeability decreased by 46% compared with bare PET. In case of three-layer oxidized SiOxCy(-H) film, the oxygen gas permeability decreased by 73%. The oxygen permeability was affected by the thickness of the SiO2-like layer formed by oxidation treatment rather than the thickness of the SiOxCy(-H) film. The excellent corrosion resistance was demonstrated by coating an oxidized SiOxCy(-H) thin film on the silver-coated aluminum PCB for light emitting diode (LED).

Mode of Resistance and/or Tolerance Action of Paraquat (Paraquat 저항성(抵抗性) 및 내성(耐性) 발현(發現) 기구(機構))

  • Ma, Sang-Yong;Chun, Jae-Chul
    • Korean Journal of Environmental Agriculture
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    • v.13 no.3
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    • pp.373-385
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    • 1994
  • Resistance to paraquat (1,1'-dimethyl-4,4'-bipyridilium ion) has developed in 12 species of 8 genera to which paraquat has been applied 6 to 10 times per year for 5 or more years. In recent years, tolerance to paraquat has been found in Rehmannia glutinosa (Gaertn.) Liboch. ex Fisch. & Mey. which has never been applied with any herbicides involving paraquat. In this review, we differentiate the terms, resistance and tolerance, on the basis of the paraquat-exposure history. Five hypotheses have been evaluated in several species as potential mechanisms of paraquat resistance and/or tolerance. In a species, the mode of action may be due to 1) reduced quantities of paraquat absorbed through the leaf surface, 2) detoxification of paraquat caused by the enhanced paraquat-metabolic activity, 3) rapid sequestration reducing level of paraquat at the site of action in chloroplast, 4) alteration of site of action in photosystem I resulting in interruption of electron transport to paraquat, and 5) rapid enzymatic detoxification of superoxide and other toxic forms of oxygen.

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Fabrication and Characterization of Ni-Cr Alloy Thin Films for Application to Precision Thin Film Resistors

  • Lee, Boong-Joo;Shin, Paik-Kyun
    • Journal of Electrical Engineering and Technology
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    • v.2 no.4
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    • pp.525-531
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    • 2007
  • Ni(75 wt.%)-Cr(20 wt.%)-Al(3 wt.%)-Mn(4 wt.%)-Si(1 wt.%) alloy thin films were prepared using the DC magnetron sputtering process by varying the sputtering conditions such as power, pressure, substrate temperature, and post-deposition annealing temperature in order to fabricate a precision thin film resistor. For all the thin film resistors, sheet resistance, temperature coefficient of resistance (TCR), and crystallinity were analyzed and the effects of sputtering conditions on their properties were also investigated. The oxygen content and TCR of Ni-Cr-Al-Mn-Si resistors were decreased by increasing the sputtering pressure. Their sheet resistance, TCR, and crystallinity were enhanced by elevating the substrate temperature. In addition, the annealing of the resistor thin films in air at a temperature higher than $300^{\circ}C$ lead to a remarkable rise in their sheet resistance and TCR. This may be attributed to the improved formation of NiO layer on the surface of the resistor thin film at an elevated temperature.

Oxidation Resistance and Preferred Orientation of TiAIN Thin Films (TiAIN 박막의 우선방위와 내산화성)

  • Park, Yong-Gwon;Park, Yong-Gwon;Wey, Myeong-Yong
    • Korean Journal of Materials Research
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    • v.12 no.8
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    • pp.676-681
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    • 2002
  • Microstructure, mechanical properties, and oxidation resistance of TiAIN thin films deposited on quenched and tempered STD61 tool steel by arc ion plating were studied using XRD, XPS and micro-balance. The TiAIN film was grown with the (200) orientation. The grain size of TiAIN thin film decreased with increasing Al contents, while chemical binding energy increased with Al contents. When hard coating films were oxidized at $850^{\circ}C$ in air, oxidation resistance of both TiN and TiCN films became relatively lower since the surface of films formed non-protective film such as $TiO_2$. However, oxidation resistance of TiAIN film was excellent because its surface formed protective layer such as $_A12$$O_3$ and $_Al2$$Ti_{7}$$O_{15}$, which suppressed oxygen intrusion.