• Title/Summary/Keyword: Oxygen permeability

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The Effect of Wettability and Protein Adsorption of Contact Lens by Alginic Acid (알긴산에 의한 콘택트렌즈의 습윤성과 단백질 흡착 효과)

  • Ko, Na Young;Lee, Kyung Mun;Lee, Hyun Mee
    • Journal of the Korean Chemical Society
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    • v.61 no.6
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    • pp.352-358
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    • 2017
  • The addition of alginic acid, a natural polysaccharide, to improve the wettability and the reduction of protein adsorption of hydrogel contact lenses. Hydrogel contact lenses were manufactured with various monomers such as 2-methacryloyloxyethyl phosphorylcholine (MPC) and NVP (N-Vinyl-2-pyrrolidone). Alginic acid was added by by the initial mixing method and the interpenetrating polymer networks(IPN) method. Properties of contact lens such as contact angle, oxygen permeability, and protein adsorption amount were evaluated. The oxygen permeability and wettability of the IPN-treated alginate samples were higher than those of the samples that were not treated with IPN. The physical properties were improved as the concentration of IPN-treated alginic acid increased. Protein adsorption decreased by the addition of alginic acid and further decreased with IPN. In particular, contact lenses containing MPC and NVP significantly decreased protein adsorption. Therefore, the effect of alginate on the functional improvement of contact lens was confirmed.

Facilitated Oxygen Transport through a Polyethersulfone Membrane Containing Cobalt Tetraphenylporphyrin-Benzylimidazole (Cobalt Tetraphenylporphyrin-benzylimidazole을 포함한 산소 촉진수송막)

  • Lee, Seung Hwan;Park, Se Hyung;Park, Jung Hoon
    • Membrane Journal
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    • v.28 no.6
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    • pp.424-431
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    • 2018
  • The gas separation performance of a mixed membrane structure based on a mixture of polyethersulfone (PES) and cobalt tetraphenylporphyrin-benzylimidazole (CoTpp-BIm) as an oxygen carrier was investigated. The CoTpp-BIm mixed PES membrane had an asymmetric structure with a mixture of finger structure and sponge-like structure, and the upper surface was dense. The gas separation performance test was carried out using $94%\;N_2$ gas and $6%\;O_2$ mixed gas. Oxygen and nitrogen permeability coefficients were measured at ${\Delta}P$ ranging from 15 to 228 cmHg and the permeate side of the PES membrane was maintained at vacuum level. The oxygen permeability coefficient of CoTpp-BIm mixed PES membranes increased as supplied pressure was decreased. When the supply pressure was 15 cmHg, the gas permeability ($P_{O_2}$) was 6676 Barrer, the $O_2/N_2$ selectivity (${\alpha}$) was 6.1, and the promoting factor (F) was 2.39. Based on these results, it was confirmed that the addition of CoTpp-BIm to the PES film improved the oxygen separation characteristics.

Change of Corneal Shape with Soft Contact Lens Type (소프트콘택트렌즈의 유형에 따른 각막형태의 변화)

  • Woo, Chul-Min;Lee, Hyun Mee
    • Journal of Korean Ophthalmic Optics Society
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    • v.19 no.1
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    • pp.111-120
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    • 2014
  • Purpose: This study was to investigate changes in the thickness of cornea, curvature of cornea, and aberration depending on the water contents, materials, and refractive power of contact lens. Methods: The differences in the corneal thickness between pre- and post-wearing the lenses were compared using 5 kinds of lenses. The changes in the corneal thickness, the curvatures of the anterior and posterior cornea, and high order aberration (HOA) before and after wearing the lenses were investigated at the center of the cornea, and the different distance and the direction away from the center of the cornea. For the equipments of measurement, ORB ScanII (Bausch & Lomb Inc, ver 3.14) was used to measure the corneal topography and thickness, and Zywave (Bausch & Lomb Inc, ver 5.20) was used to analyze the high order aberration. Results: Five (S1, S2, S3, T1, T2) of the lens was used for this study, excluding the lens T2 lens has four lenses and the thickness of the corneal shape, but the impact is minimal. In the case of the hydrogel soft contact lenses (T2 lens) with low oxygen permeability, the corneal thickness showed distinct increasing patterns. The high order aberration and coma aberration were most changed in the silicon hydrogel toric lens, while the depth of anterior was most changed in the hydrogel toric lens. Conclusion: Among the 5 kinds of contact lenses with different water contents, materials, and refractive power used for this study, the corneal shape change was small for the lenses with an oxygen permeability (Dk) of more than 28, and the largest for the lenses with a very low oxygen permeability.

Effect of Conductive Additives in La0.8Sr0.2MnO3 Perovskite Electrodes for Oxygen Reduction and Evolution in Alkaline Solution (알칼리용액에서 La0.8Sr0.2MnO3 페롭스카이트 촉매의 산소환원 및 발생반응에서 도전재의 영향)

  • SHIM, JOONGPYO;LOPEZ, KAREEN J.;YANG, JIN-HYUN;SUN, HO-JUNG;PARK, GYUNGSE;EOM, SEUNGWOOK;LEE, HONG-KI
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.3
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    • pp.276-282
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    • 2016
  • The effects of conductive additives in a $La_{0.8}Sr_{0.2}MnO_3$ perovskite bifunctional electrode for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) were investigated in an alkaline solution. Highly porous carbon black (CB) and Ni powder were added to the bifunctional electrodes as conductive additives. The surface morphologies of electrodes containing CB and Ni were observed by scanning electron microscopy (SEM). The current densities for both ORR and OER were changed by the addition of CB. The conductive additive changed physical properties of bifunctional electrodes such as the sheet conductance, gas permeability and contact angle. It was observed that the air permeability of electrode was most effective to enhance the currents for ORR and OER.

Effect of Sintering Conditions on the Electromagnetic Properties of Mn-Zn Ferrites (소결조건이 Mn-Zn Ferrites의 전자기적 물성에 미치는 효과)

  • 최윤호;신명승;한승기;한영호
    • Journal of the Korean Ceramic Society
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    • v.34 no.6
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    • pp.561-568
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    • 1997
  • The effects of sintering temperature and oxygen partial pressure on the electromagnetic properties of Mn-Zn ferrites were investigated. The grain increased with increasing temperature. The power loss at 100 kHz was decreased, while the power loss at 500 kHz was increased as the grain size increased with sintering temperature. Sintering with low oxygen partial pressure at 115$0^{\circ}C$ resulted in high density and initial permeability, and decreased the power loss at 100 kHz and 500 kHz. The oxygen partial pressure lower than 10-2 atm. during heating, significantly suppressed the hysteresis loss. However, the oxygen activity did not affect the grain size of sintered cores.

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Influence of Physical Property of Soft Film and Packaging Method on the Storage Stability of Individually Packaged Fresh Ginseng (연포장재 필름의 물성 및 포장방법이 개별포장한 수삼의 저장성에 미치는 영향)

  • 손현주;김은희;노길봉;정광식;김정한
    • Journal of Ginseng Research
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    • v.25 no.1
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    • pp.45-52
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    • 2001
  • The storage stability of fresh ginseng packaged individually in a soft film bag was more enhanced as the soft film with lower oxygen permeability was used, while the optimum water vapor permeability for enhancing the storage stability of fresh ginseng was estimated 3.5 g/m$^2$$.$day$.$90% RH when using the soft film with low oxygen permeability of 3.6∼5.4 cc/m$^2$$.$day$.$atm. The storage stability of the individually packaged fresh ginseng was also enhanced when the soft film bag was filled with carbon dioxide-oxygen-nitrogen (25:5:70) miked gas but the vacuum packaging exhibited little effect for the enhancement of storage stability of the fresh ginseng.

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Effects of Reactive Gas Addition on the Mechanical Property and Water Permeability of IZO Films Deposited by DC Sputtering for Application to Flexible OLED (DC 마그네트론 스퍼터로 증착한 flexible OLED용 IZO 박막의 기계적 특성과 투습특성에 미치는 반응성 가스 첨가의 효과)

  • Cheon, Ko-Eun;Lee, Dong-Yeop;Cho, Young-Rae;Song, Pung-Keun
    • Journal of the Korean institute of surface engineering
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    • v.40 no.6
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    • pp.245-249
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    • 2007
  • Amorphous IZO films were deposited on PET substrate by DC magnetron sputtering without substrate heating. In order to investigate effect of reactive gas addition on film properties, 0.2-0.4% of $H_2$ or $O_2$ gas was introduced during the deposition. Deposited IZO films were evaluated with mechanical property, electrical property, and water permeability. In the case of $H_2$ gas addition, mechanical property showed clear degradation compared to $O_2$ gas. In the case of $O_2$ gas, water permeability of the IZO film was increased compared to $H_2$ gas which could be attributed to the low adhesion of the film caused by bombardment of high energy negative oxygen ion. As a result, it is confirmed that water permeability of the film could be strongly affected by adhesion of the film.

Synthesis and Characterization of Alumina Composite Membrane by Al Evaporation and Thermal Oxidation (알루미늄의 진공증발과 열산화에 의한 알루미나 복합분리막의 제조 및 특성분석)

  • 이동호;최두진;현상훈
    • Journal of the Korean Ceramic Society
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    • v.32 no.3
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    • pp.349-358
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    • 1995
  • The ceramic composite membrane was synthesized by thermal oxidation after evaporation of Al on the support prepared by slip casting process. Oxidation was performed at $700^{\circ}C$ and 80$0^{\circ}C$ under dry oxygen atmosphere. It was considered as optimum oxidation condition that the membrane showed a knudsen behaviro. A further oxidation resulted in an increase of gas permeability because top layer became densified. Then, a multi-layered composite membrane was synthesized through a sol-gel method, evaporation and thermal oxidation of Al coating processes. While the membrane was thermally stable up to 80$0^{\circ}C$, gas permeability was rapidly decreased even at a slight amount of deposition of Al.

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