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http://dx.doi.org/10.14579/MEMBRANE_JOURNAL.2018.28.6.424

Facilitated Oxygen Transport through a Polyethersulfone Membrane Containing Cobalt Tetraphenylporphyrin-Benzylimidazole  

Lee, Seung Hwan (Department of Chemical and Biochemical Engineering, Dongguk University)
Park, Se Hyung (Department of Chemical and Biochemical Engineering, Dongguk University)
Park, Jung Hoon (Department of Chemical and Biochemical Engineering, Dongguk University)
Publication Information
Membrane Journal / v.28, no.6, 2018 , pp. 424-431 More about this Journal
Abstract
The gas separation performance of a mixed membrane structure based on a mixture of polyethersulfone (PES) and cobalt tetraphenylporphyrin-benzylimidazole (CoTpp-BIm) as an oxygen carrier was investigated. The CoTpp-BIm mixed PES membrane had an asymmetric structure with a mixture of finger structure and sponge-like structure, and the upper surface was dense. The gas separation performance test was carried out using $94%\;N_2$ gas and $6%\;O_2$ mixed gas. Oxygen and nitrogen permeability coefficients were measured at ${\Delta}P$ ranging from 15 to 228 cmHg and the permeate side of the PES membrane was maintained at vacuum level. The oxygen permeability coefficient of CoTpp-BIm mixed PES membranes increased as supplied pressure was decreased. When the supply pressure was 15 cmHg, the gas permeability ($P_{O_2}$) was 6676 Barrer, the $O_2/N_2$ selectivity (${\alpha}$) was 6.1, and the promoting factor (F) was 2.39. Based on these results, it was confirmed that the addition of CoTpp-BIm to the PES film improved the oxygen separation characteristics.
Keywords
Facilitated transport; Cobalt tetraphenyl porphyrin; Gas separation; Oxygen membrane;
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Times Cited By KSCI : 1  (Citation Analysis)
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