• 제목/요약/키워드: Oxygen contents

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발사대 및 시험장 건물 내의 산소농도 관리 (Oxygen contents monitoring in the building for launch and test facilities)

  • 김지훈;유병일;조상연;강선일;오승협
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 제33회 추계학술대회논문집
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    • pp.246-249
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    • 2009
  • 산소를 추진제로 사용하는 발사체를 발사하기 위한 발사대 및 그것을 시험하기 위한 설비를 보유하고 있는 건물은 언제나 누출된 산소로 인한 화재 및 폭발의 위험성을 지니고 있다. 또한 질소, 헬륨 등과 같은 각종 고압가스류를 사용하고 있기 때문에 밀폐된 공간에서의 가스 누출로 인한 질식사의 위험에도 노출되어 있다. 따라서 이러한 공간 내의 공기 중 산소 농도를 관리하여 발생할 수 있는 사고를 미연에 예방할 수 있어야 한다. 본 논문에서는 산소 농도 관리의 방법과 시스템 구성 및 적용 결과를 정리하였다.

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열처리한 ZnO 박막 내의 산소 농도 변화에 따른 구조적, 광학적 특성 연구 (Effect of Oxygen Contents in Thermal Annealed ZnO films on Structural and Optical Properties)

  • 이주영;김홍승;정은수;장낙원
    • 한국전기전자재료학회논문지
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    • 제18권7호
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    • pp.600-604
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    • 2005
  • We studied that structural and optical properties of ZnO films depend on oxygen contents. ZnO films were deposited on Si (111) substrates at room temperature by rf sputtering system and the thickness of films was 100 nm. The ZnO films were annealed in thermal furnace for 2 h at 800 and $900^{\circ}C$ in $H_2O,\;N_2$, and air ambient gases to control oxygen contents. We used AES, PL, XRD, AFM. As our result, crystal quality and luminescence improved until O/Zn is 1. However, when O/Zn ratio Is larger than 1, the structural and optical properties were getting worse.

매체순환식 가스연소기용 산소공여입자들의 연료별 연소특성 (Reduction Characteristics of Oxygen Carrier Particles for Chemical-looping Combustor with Different Fuels)

  • 류호정;김경수;박영성;박문희
    • 한국수소및신에너지학회논문집
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    • 제20권1호
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    • pp.45-54
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    • 2009
  • Reduction reactivity and carbon deposition characteristics of three oxygen carrier particles(OCN01, OCN02, OCN03) have been investigated by using hydrogen, methane, syngas, and natural gas as fuels. For all particles, the maximum conversion, the oxygen transfer capacity, and the degree of carbon deposition increased as the reactive carbon contents increased. The reduction rate and the oxygen transfer rate increased as the moles of required oxygen per input gas increased. The change of maximum conversion, reduction rate, oxygen transfer capacity, oxygen transfer rate and degree of carbon deposition for different fuels can be explained consistently by using parameters such as the reactive carbon contents and the moles of require oxygen per input gas.

RF magnetron sputtering법으로 제조한 Al doped ZnO 박막의 산소함량과 압력변화에 따른 전기적 특성 변화 (Electrical properties of the Al doped ZnO thin films fabricated by RF magnetron sputtering system with working pressure and oxygen contents)

  • 김종욱;김홍배
    • 반도체디스플레이기술학회지
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    • 제9권4호
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    • pp.77-81
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    • 2010
  • The AZO thin films were deposited on the corning 1737 glass plate by the RF magnetron sputtering and effects of working pressure and oxygen contents on the electrical properties were investigated. XRD spectra showed a preferred orientation along the c-axis and a minimum FWHM for the 70mTorr. From the surface analysis (AFM), the number of crystal grain of AZO thin film increased as working pressure increased. The film deposited with 70mTorr of working pressure showed n-type semiconductor characteristic having suitable resistivity $-1.59{\times}10^{-2}{\Omega}cm$, carrier concentration $-10.1{\times}10^{19}cm^{-3}$, and mobility $-4.35cm^2V^{-1}s^{-1}$ while other films by 7 mTorr, 20 mTorr of working pressure closed to metallic films. The films including the oxygen represent stoichiometric composition similar to the oxide. The transmittance of the film was over 85% in the visible light range regardless of the changes in working pressure and oxygen contents.

ZrB2 분말의 입도 및 산화도가 치밀화에 미치는 영향 (Effects of particle size and oxygen contents on ZrB2 powder for densification)

  • 정세혁;최성철
    • 한국결정성장학회지
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    • 제22권5호
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    • pp.247-253
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    • 2012
  • 본 연구에서는 zirconium diboride($ZrB_2$)의 소결성 향상을 위해 두 가지 전처리 공정을 사용하였다. 물리적 전처리 공정으로 SPEX mill을 사용하여 as-received $ZrB_2$ powder의 입도를 $2.61{\mu}m$에서 $0.35{\mu}m$까지 감소시킬 수 있었다. 화학적 전처리 공정으로 희석된 불산 용액을 사용하여 $ZrB_2$ powder의 산화도를 4.20 wt%에서 2.22 wt%까지 감소시킬 수 있었다. 소결된 $ZrB_2$의 상대 밀도는 입도와 산화도가 감소함에 따라 증가하였다. $ZrB_2$의 치밀화에는 산화도 보다 입도의 영향이 더 크다는 것을 확인하였다. 두 가지 전처리 공정을 통해 소결 조제의 사용 없이 치밀한 $ZrB_2$ 소결체를 제조하였다. 물리적 화학적 전처리 공정을 사용함으로써 $ZrB_2$의 소결성을 향상시킬 수 있었다.

MTBE 함량 변화가 MPI 및 GDi 차량의 배출가스 및 연비에 미치는 영향에 대한 실험적 연구 (An experimental Study of the Effect of MTBE contents on Exhaust Emissions and Fuel Economy of MPI and GDi Vehicles)

  • 송호영;이민호;김기호;임태윤;김홍집
    • 에너지공학
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    • 제25권4호
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    • pp.159-169
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    • 2016
  • 본 연구에서는 함산소기재 중 MTBE를 휘발유에 첨가하여 산소함량(0, 1.0, 2.3 및 2.7 wt %)의 변화에 따라 MPI 및 GDi 차량에서 배출되는 유해한 배출가스와 연비를 분석하였다. 국내 및 미국의 연비시험방법인 FTP-75 mode와 HWFET mode를 적용하였다. CO, NMHC, NOx 배출량은 산소함량의 변화에 따라 미미한 차이는 있었지만 상관관계는 없었다. FTP-75 mode에서 CO2 배출량은 산소함량의 변화에 따라 증감의 경향성은 없었다. 하지만 차량이 예열된 상태이고 고속 운전영역이 포함된 FTP-75 mode의 phase-3와 HWFET mode에서는 산소를 함유한 연료의 CO2 배출량이 적었다. 입자개수 배출량은 산소함량과 음의 상관관계를 보였으며 산소함량 2.3 wt %에서 가장 적었다. 카본발란스법에 의해 계산된 연비는 산소를 함유한 연료가 높았으며 2.3 wt %에서 가장 높았다.

Co1-xMgxO세라믹스의 MgO함량에 따른 전기적 성질 및 산소가스 감지특성 (Effect of MgO Contents on Electrical Properties and Oxygen Sensing Characteristics in Co1-xMgxO Ceramics)

  • 최현국;이덕동;조상희
    • 한국세라믹학회지
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    • 제26권1호
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    • pp.7-12
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    • 1989
  • The effects of composition ratios and sintering conditions in Co1-xMgxO ceramics on the sintering characteristics, electrical properties and oxygen sensing characteristics were investigated. In the same sintering conditions, porosity decreased with increase of MgO contents. The relationshiop of temperature and resistance in Co1-xMgxO ceramics showed NTC(negative temperature coefficient) characteristics at the temperature range from $700^{\circ}C$ to 1,10$0^{\circ}C$. In the case of pure CoO, however, the PTC(positive temperature coefficient) characteristics were shown over about 90$0^{\circ}C$. The electrical conductivity of Co1-xMgxO ceramics decreased proportionally with decrease of oxygen partial pressure at the range from 1 to 10-4(atm). Particularly, Co0.5Mg0.5O ceramics showed the highest sensitivity to oxygen gas.

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P형 열전분말의 수소환원처리가 상온열전특성에 미치는 영향 (Effect of Hydrogen Reduction Treatment on Room-Temperature Thermoelectric Performance of p-type Thermoelectric Powders)

  • 김경태;장경미;하국현
    • 한국분말재료학회지
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    • 제17권2호
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    • pp.136-141
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    • 2010
  • Bismuth-telluride based $(Bi_{0.2}Sb_{0.8})_2Te_3$ thermoelectric powders were fabricated by two-step planetary milling process which produces bimodal size distribution ranging $400\;nm\;{\sim}\;2\;{\mu}m$. The powders were reduced in hydrogen atmosphere to minimize oxygen contents which cause degradation of thermoelectric performance by decreasing electrical conductivity. Oxygen contents were decreased from 0.48% to 0.25% by the reduction process. In this study, both the as-synthesized and the reduced powders were consolidated by the spark plasma sintering process at $350^{\circ}C$ for 10 min at the heating rate of $100^{\circ}C/min$ and then their thermoelectric properties were investigated. The sintered samples using the reduced p-type thermoelectric powders show 15% lower specific electrical resistivity ($0.8\;m{\Omega}{\cdot}cm$) than those of the as-synthesized powders while Seebeck coefficient and thermal conductivity do not change a lot. The results confirmed that ZT value of thermoelectric performance at room temperature was improved by 15% due to high electric conductivity caused by the controlled oxygen contents present at bismuth telluride materials.

THE EFFECT OF HYDROGEN AND OXYGEN CONTENTS ON HYDRIDE REORIENTATIONS OF ZIRCONIUM ALLOY CLADDING TUBES

  • CHA, HYUN-JIN;JANG, KI-NAM;AN, JI-HYEONG;KIM, KYU-TAE
    • Nuclear Engineering and Technology
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    • 제47권6호
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    • pp.746-755
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    • 2015
  • To investigate the effect of hydrogen and oxygen contents on hydride reorientations during cool-down processes, zirconium-niobium cladding tube specimens were hydrogen-charged before some specimens were oxidized, resulting in 250 ppm and 500 ppm hydrogen-charged specimens containing no oxide and an oxide thickness of $0.38{\mu}m$ at each surface. The nonoxidized and oxidized hydrogen-charged specimens were heated up to $400^{\circ}C$ and then cooled down to room temperature at cooling rates of $0.3^{\circ}C/min$ and $8.0^{\circ}C/min$ under a tensile hoop stress of 150 MPa. The lower hydrogen contents and the slower cooling rate generated a larger fraction of radial hydrides, a longer radial hydride length, and a lower ultimate tensile strength and plastic elongation. In addition, the oxidized specimens generated a smaller fraction of radial hydrides and a lower ultimate tensile strength and plastic elongation than the nonoxidized specimens. This may be due to: a solubility difference between room temperature and $400^{\circ}C$; an oxygen-induced increase in hydrogen solubility and radial hydride nucleation energy; high temperature residence time during the cool-down; or undissolved circumferential hydrides at $400^{\circ}C$.

동합금의 탈산에 관한 열역학적 해석 (The Thermodynamic Analysis of Deoxidation in Cu Alloy)

  • 김신우
    • 한국주조공학회지
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    • 제25권1호
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    • pp.36-39
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    • 2005
  • The thermodynamic analysis of deoxidation in molten coppyr by Fe has been made. Equilibrium oxygen solubility saturated with FeO in Cu-Fe-O system has been derived without and with consideration of the solute interaction between Fe and O. The derived relationship of oxygen contents with Fe has been compared with the experimental results done by Kulkarni and the minimum oxygen solubility could be predicted by a simple first order interaction method, Wagner model.