• Title/Summary/Keyword: Oxygen addition

Search Result 2,053, Processing Time 0.034 seconds

A Study on the Optical Emission Spectroscopy of the RF Inductive Plasma Process (RF 유도형 플라즈마 프로세스에 대한 분광학적 연구)

  • Jang, Mun-Gug;Han, Sang-Bo;Park, Sang-Hyun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
    • /
    • v.25 no.11
    • /
    • pp.103-112
    • /
    • 2011
  • This paper is tried to analysis the optical emission spectroscopy related to the position of inductive load coil and flow rates of methane and oxygen in the RF inductive plasma process. According to the position of load coil, peak of $H_{\alpha}$, $H_{\beta}$, and CH were appeared strongly at the middle position of the coil and it decreased both direction. The electron temperature was approximately 0.9[eV] at that position. Emission intensities of $H_{\alpha}$, $H_{\beta}$, and CH increased linearly by increasing input power. In addition, intensities of $H_{\alpha}$ and $H_{\beta}$ increased by increasing the flow rate of oxygen. It might be ascribed that the oxygen species were bonded with $C_nH_m$ by suppressing the combination with hydrogen atoms. Consequently, the optimal position of the inductive coil is decided to the intermediate position between 4th and 5th turns, the wanted carbon thin-film is possible to deposit by controlling flow rates of methane and oxygen.

Effects of Erythrosine on the Cholesterol Oxidative Stability in an Aqueous Model System (수용성 모형계에서 콜레스테롤의 산화 안정성에 대한 Erythrosine의 영향)

  • Chung, Man-Gon;Kim, Jong-Seung;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
    • /
    • v.28 no.1
    • /
    • pp.197-202
    • /
    • 1996
  • The effects of erythrosine on the oxidative stability of cholesterol in an aqueous model system were studied by depleted headspace oxygen and cholesterol oxidation products (COP). As the oncentration of erythrosine was increased, headspace oxygen depletion, 7-COP and total COP increased during storage at $25^{\circ}C$ for 50 hours under the fluorescent light. As the intensity of fluorescent light was increased, amounts of headspace oxygen depleted and COP formed in an aqueous cholesterol dispersion containing erythrosine also increased. Addition of ${\alpha}-,\;{\delta}-$, mixed-tocopherol and ${\beta}-carotene$ resulted in the enhanced oxidative stability of an aqueous cholesterol dispersion containing erythrosine during the fluorescent light storage.

  • PDF

Differences in Body Weight, Dietary Efficiency, Brain Obesity Control Factor (AMPK), Reactive Oxygen Species (MDA), and Antioxidant Enzymes (SOD) in Young Mice According to the Intensity of Aerobic Exercise for 8 Weeks (8주간의 유산소 운동강도에 따른 어린 생쥐의 체중, 식이효율, 뇌의 비만조절 인자(AMPK), 활성산소(MDA), 항산화효소(SOD)의 차이)

  • Jeon, Mi Yang
    • Journal of Korean Biological Nursing Science
    • /
    • v.23 no.3
    • /
    • pp.247-255
    • /
    • 2021
  • Purpose: The goal of this study was to see how different aerobic exercise intensities affected AMP-activated protein kinase (AMPK), reactive oxygen, and antioxidant enzymes in young mice during an 8-week period. Methods: Forty male C57BL/6 mice, aged seven weeks, were randomly assigned to one of four groups: control (n=10), low-intensity exercise (n=10), moderate-intensity exercise (n=10), and high-intensity exercise (n=10). For eight weeks, aerobic activity was performed once a day for 35-40 minutes, five days a week. The data were analyzed using descriptive statistics, analysis of variance (ANOVA), chi-squared tests, and the Tukey test in the SPSS/WIN 25.0 program. Results: Weight (p=.001) was substantially different between the moderate-intensity exercise group and the control group in AMPK (p<.001). In addition, there were no significant differences between the moderate-intensity exercise group and the control group in reactive oxygen malondialdehyde (MDA) levels (p=.136) and antioxidant enzyme superoxide dismutase (SOD) levels (p=.521). Conclusion: These findings suggest that moderate-intensity aerobic exercise increased AMPK activation and helped young mice shed weight.

Effect of Oxygen Plasma Treatment on the Surface and Tensile Properties of Stainless Steel Fibers (산소 플라즈마 처리가 스테인레스 스틸 섬유의 표면 및 인장특성에 미치는 영향)

  • Kwon, MiYeon;Lim, Dae Young;Lee, Seung Goo
    • Textile Coloration and Finishing
    • /
    • v.34 no.2
    • /
    • pp.102-108
    • /
    • 2022
  • The physicochemical properties of stainless steel fibers which were modified by oxygen plasma treatment were analyzed through microscopy and XPS analysis. The wettability of the surface of the stainless steel fiber was observed by measuring water contact angle to find out the effect of the plasma treatment time on the surface characteristics of the stainless steel fiber. In addition, in order to understand the effect of oxygen plasma treatment on the deterioration of the stainless steel fiber properties, the physical properties due to plasma treatment was investigated by measuring the weight reduction, tensile strength, elongation, tensile modulus of the stainless steel fibers according to the treatment time. As a result, the stainless steel fiber surface was etched by the oxygen plasma and the surface became more wettable by the introduction of hydrophilic functional groups. However the physical properties of the stainless steel fiber were not significantly deteriorated even if the surface of the stainless steel fiber made hydrophilic.

Effect of Oxygen Content on Aging Properties of Ti-39Nb-6Zr alloy (Ti-39Nb-6Zr 합금의 산소함량에 따른 시효특성 변화)

  • Han, Chan Byeol;Lee, Dong-Geun
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.35 no.2
    • /
    • pp.88-95
    • /
    • 2022
  • Titanium alloy for bio-medical applications have been developed to reduce the toxicity of alloying elements and avoid the stress-shielding effect which is caused by relatively high elastic modulus compared to bone. Ti-39Nb-6Zr (TNZ40) alloy of elastic modulus exhibits around 40 GPa in the case of beta single phase. However, the strength of this alloy is lower than the other types of titanium alloys. Many research found that adding oxygen to beta-titanium alloys is beneficial for improving the strength through solid solution strengthening. In this study, TNZ40 ingots with addition of O were prepared by an arc remelting process (Ti-39Nb-6Zr-0.16O (wt.%), Ti-39Nb-6Zr-0.26O (wt.%)). Thermo-mechanical processing (i.e., heat treatment, cold swaging and aging heat treatment) has been performed under various conditions. Therefore, the aim of this study is to investigate the effect of oxygen content and ω phase formation on microstructure and mechanical properties.

Effect of Scrap Impurities on Microstructure and Mechanical Properties of Zr Alloys (스크랩 불순물이 Zr 합금의 미세조직 및 기계적 특성에 미치는 영향)

  • Jeong, Gu Beom;Kim, In Won;Song, Jae Sook;Shin, Pyung Woo;Hong, Sun Ig
    • Journal of Korea Foundry Society
    • /
    • v.36 no.3
    • /
    • pp.81-87
    • /
    • 2016
  • In this study, the effect of scrap ratio on the mechanical properties of Zr alloys was studied. Oxygen content in the ingot cake increased rapidly with increasing fraction of scrap, which can be attributed to the surface oxide of scrap including small pieces of turning, chips, etc. Iron content did not increase much with the increasing addition of scrap, suggesting scrap materials was well reserved in the iron-free container. As-cast structure of Zr alloy with the scrap:sponge ratio displayed plate/or needle ${\alpha}$ phase and no appreciable change of the cast structure was observed with change of scrap fraction. The strength increases with increasing fraction of scrap, which can be attributed to the increase of oxygen content. The ductility decreased slightly with increase of scrap fraction. Dislocation-oxygen interaction is known to increase the strength at the expense of ductility. Ingot cake with intentionally added $Fe_2O_3$ exhibited the drastic decrease of the formability, even exhibited the brittle fracture behavior during rolling. The oxidation resistance, however, increased with the increase of scrap fraction because of high oxygen content, which may prevent more penetration and diffusion of oxygen into matrix.

Study on Possibility of Diesel Reforming with Hydrogen Peroxide in Low-Oxygen Environments (산소희박환경에서 과산화수소를 이용한 디젤개질 가능성 탐구)

  • Han, Gwangwoo;Bae, Minseok;Bae, Joongmyeon
    • Korean Chemical Engineering Research
    • /
    • v.53 no.5
    • /
    • pp.584-589
    • /
    • 2015
  • For effective power generation with fuel cells in low-oxygen environments such as submarines and unmanned underwater vehicles, a hydrogen source which has a high hydrogen storage density is required. Diesel fuel is easy to storage and supply due to its liquid phase and it has a high density per unit volume and unit mass of hydrogen that required for driving the fuel cells. In this paper, diesel fuel was selected as a hydrogen source for driving the fuel cell in oxygen lean environments. In addition, the aqueous hydrogen peroxide solution was suggested as an alternative oxidant for hydrogen production through the diesel reforming reaction because of its high oxygen density and liquid phase which makes it easy to storage. In order to determine the characteristics of hydrogen peroxide as an oxidant of diesel reforming, comparative experiments were conducted and it was found that hydrogen peroxide solution has the same characteristics when reformed with oxidants of both steam and oxygen. Moreover, the commercial diesel reforming performances were analyzed according to the reaction temperature and concentration of aqueous hydrogen peroxide solution. Then, through the 49 hours accelerated degradation tests, the possibility of hydrogen production via diesel and aqueous hydrogen peroxide solution was confirmed.

Effect of oxygen deficiency on electronic properties and local structure of amorphous tantalum oxide thin films

  • Denny, Yus Rama;Firmansyah, Teguh;Park, Chanae;Kang, Hee Jae;Yang, Dong-Seok;Heo, Sung;Chung, Jae Gwan;Lee, Jae Cheol
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2015.08a
    • /
    • pp.122.1-122.1
    • /
    • 2015
  • The dependence of electronic properties and local structure of tantalum oxide thin film on oxygen deficiency have been investigated by means of X-ray photoelectron spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and X-ray absorption spectroscopy (XAS). The XPS results showed that the oxygen flow rate change results in the appearance of features in the Ta 4f at the binding energies of 23.2 eV, 24.4 eV, 25.8, and 27.3 eV whose peaks are attributed to Ta1+, Ta2+, Ta3+, Ta4+, and Ta5+, respectively. The presence of nonstoichiometric state from tantalum oxide (TaOx) thin films could be generated by the oxygen vacancies. The REELS spectra suggested the decrease of band gap for tantalum oxide thin films with increasing oxygen deficiency. In addition, XAS spectra manifested both the increase of coordination number of the first Ta-O shell and a considerable reduction of the Ta-O bond distance with the decrease of oxygen deficiency.

  • PDF

Effect of Needle-Like NiO Protecting Layer on NiCrAl Alloy Foam by Controlled Oxygen Concentration (산소 농도 제어를 통한 NiCrAl 합금 폼 표면의 침상 NiO 보호층 효과)

  • Lee, Young-Geun;Shin, Dong-Yo;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
    • /
    • v.28 no.6
    • /
    • pp.324-329
    • /
    • 2018
  • Needle-like NiO protecting layers on NiCrAl alloy foam, used as support for hydrogen production, are introduced through electroplated Ni and subsequent microwave annealing. To improve the stability of the NiCrAl alloy foam, oxygen concentration of microwave annealing to form a needle-like NiO layer with good chemical stability and corrosion resistance is controlled in a range of 20 and 50 %. As the oxygen concentration increases to 50 %, needle-like NiO forms a dense coating layer on the NiCrAl alloy foam; this layer formation can be attributed to accelerated growth of the (200) plane. In addition, the increased oxygen concentration causes increased NiO/Ni ratio of the resultant coating layer on NiCrAl alloy foam due to improved rate of the oxidation reaction. As a result, the introduction of dense needle-like NiO layers formed at 50 % oxygen concentration improves the chemical stability of the NiCrAl alloy foam by protecting the direct electrochemical reaction between the electrolyte and the foam. Thus, needle-like NiO can be proposed as a superb protecting layer to improve the chemical stability of NiCrAl alloy form.

The Effect of the Oxygen Flow Rate on the Electronic Properties and the Local Structure of Amorphous Tantalum Oxide Thin Films

  • Denny, Yus Rama;Lee, Sunyoung;Lee, Kangil;Kang, Hee Jae;Yang, Dong-Seok;Heo, Sung;Chung, Jae Gwan;Lee, Jae Cheol
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.398-398
    • /
    • 2013
  • The electronic properties and the local structure of tantalum oxide thin film with variation of oxygen flow rate ranging from 9.5 to 16 sccm (standard cubic centimeters per minute) have been investigated by X-ray photoelectron spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and X-ray absorption spectroscopy (XAS). The XPS results show that the Ta4f spectrum for all films consist of the strong spin-orbit doublet $Ta4f_{7/2}$ and $Ta4f_{5/2}$ with splitting of 1.9 eV. The oxygen flow rate of the film results in the appearance of new features in the Ta4f at binding energies of 23.2 eV, 24.4 eV, 25.8, and 27.3 eV, these peaks attribute to $Ta^{1+}$, $Ta^{2+}$, $Ta^{4+}$/$Ta^{2+}$, and $Ta^{5+}$, respectively. Thus, the presence of non-stoichiometric state from tantalum oxide ($TaO_x$) thin films could be generated by the oxygen vacancies. The REELS spectra suggest the decrease of band gap for tantalum oxide thin films with increasing the oxygen flow rate. The absorption coefficient ${\mu}$ and its fine structure were extracted from the fluorescence mode of extended X-ray absorption fine structure (EXAFS) spectra. In addition, bond distances (r), coordination numbers (N) and Debye-Waller factors (${\sigma}^2$) each film were determined by a detailed of EXAFS data analysis. EXAFS spectrapresent both the increase of coordination number of the first Ta-O shell and a considerable reduction of the Ta-O bond distance with the increase of oxygen flow rate.

  • PDF