• Title/Summary/Keyword: Over discharge

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Effect of Auxetic Structure of PVdF on Tin Anode Stability for Na-ion Batteries (소듐 이온전지용 주석 음극의 안정화를 위한 PVdF 옥세틱 구조의 영향)

  • Park, Jinsoo
    • Journal of Powder Materials
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    • v.25 no.6
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    • pp.507-513
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    • 2018
  • This study investigates the viability of using a Na-ion battery with a tin(Sn) anode to mitigate the vulnerability caused by volume changes during discharge and charge cycling. In general, the volume changes of carbon material do not cause any instability during intercalation into its layer structure. Sn has a high theoretical capacity of $847mAh\;g^{-1}$. However, it expands dramatically in the discharge process by alloying Na-Sn, placing the electrode under massive internal stress, and particularly straining the binder over the elastic limit. The repeating strain results in loss of active material and its electric contact, as well as capacity decrease. This paper expands the scope of fabrication of Na-ion batteries with Sn by fabricating the binder as an auxetic structure with a unique feature: a negative Poisson ratio (NPR), which increases the resistance to internal stress in the Na-Sn alloying/de-alloying processes. Electrochemical tests and micrograph images of auxetic and common binders are used to compare dimensional and structural differences. Results show that the capacity of an auxetic-structured Sn electrode is much larger than that of a Sn electrode with a common-structured binder. Furthermore, using an auxetic structured Sn electrode, stability in discharge and charge cycling is obtained.

Electrochemical Performance of High-Voltage LiMn0.8Fe0.2PO4 Cathode with Polyacrylonitrile (PAN)-Based Gel Polymer Electrolyte

  • Kwon, O. Hyeon;Kim, Jae-Kwang
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.547-552
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    • 2019
  • Electrochemical properties of $LiMn_{0.8}Fe_{0.2}PO_4$ cathode were investigated with gel polymer electrolyte (GPE). To access fast and efficient transport of ions and electrons during the charge/discharge process, a pure and well-crystallized $LiMn_{0.8}Fe_{0.2}PO_4$ cathode material was directly synthesized via spray-pyrolysis method. For high operation voltage, polyacrylonitrile (PAN)-based gel polymer electrolyte was then prepared by electrospinning process. The gel polymer electrolyte showed high ionic conductivity of $2.9{\times}10^{-3}S\;cm^{-1}$ at $25^{\circ}C$ and good electrochemical stability. $Li/GEP/LiMn_{0.8}Fe_{0.2}PO_4$ cell delivered a discharge capacity of $159mAh\;g^{-1}$ at 0.1 C rate that was close to the theoretical value ($170mAh\;g^{-1}$). The cell allows stable cycle performance (99.3% capacity retention) with discharge capacity of $133.5mAh\;g^{-1}$ for over 300 cycles at 1 C rate and exhibits high rate-capability. PAN-based gel polymer is a suitable electrolyte for application in $LiMn_{0.8}Fe_{0.2}PO_4/Li$ batteries with perspective in high energy density and safety.

Partial Discharge Monitoring Technology based on Distributed Acoustic Sensing (분포형 광음향센싱 기반 부분방전 모니터링 기술 연구)

  • Huioon, Kim;Joo-young, Lee;Hyoyoung, Jung;Young Ho, Kim;Myoung Jin, Kim
    • Journal of Sensor Science and Technology
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    • v.31 no.6
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    • pp.441-447
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    • 2022
  • This study describes a novel method for detecting and measuring partial discharge (PD) on an electrical facility such as an insulated power cable or switchgear using fiber optic sensing technology, and a distributed acoustic sensing (DAS) system. This method has distinct advantages over traditional PD sensing techniques based on an electrical method, including immunity to electromagnetic interference (EMI), long range detection, simultaneous detection for multiple points, and exact location. In this study, we present a DAS system for PD detection with performance evaluation and experimental results in a simulated environment. The results show that the system can be applied to PD detection.

Infiltration characteristic of modified slurry and support efficiency of filter cake in silty sand strata

  • Sai Zhang;Jianwen Ding;Ning Jiao;Shuai Sun;Jinyu Liu
    • Geomechanics and Engineering
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    • v.34 no.2
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    • pp.125-138
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    • 2023
  • To improve the understanding of infiltration characteristic of modified slurry and the support efficiency of filter cake in silty sand strata, the slurry infiltration (SI) and filter cake formation (FCF) were investigated in a laboratory apparatus. The water discharge and the excess pore pressure at different depths of silty sand strata were measured during SI. The relationship between permeability coefficient/thickness ratio of filter cake (kc/ΔL) and effective slurry pressure conversion rate of filter cake (η) were analyzed. Moreover, the SI and FCF process as well as the modification mechanism of CMC (carboxymethyl cellulose) were clarified. The experimental results indicate the formation of only external filter cake in the silty sand strata. The slurry particles obtain thicker water membrane after being modified by CMC, which blocks partial water path in filter cake and decreases the water discharge significantly. The silty sand excavated from tunnel face also contributes to the water discharge reduction. The kc of the external filter cake ranges from 3.83×10-8 cm/s to 7.44×10-8 cm/s. The η of the external filter cake is over 96%, which decreases with increasing kc/ΔL. A silty sand content within 10% is suggested during construction to ensure the uniformity of the filter cake.

Prediction of 2-Dimensional Unsteady Thermal Discharge into a Reservoir (온수의 표면방출에 의한 2차원 비정상 난류 열확산 의 예측)

  • 박상우;정명균
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.7 no.4
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    • pp.451-460
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    • 1983
  • Computational four-equation turbulence model is developed and is applied to predict twodimensional unsteady thermal surface discharge into a reservoir. Turbulent stresses and heat fluxes in the momentum and energy equations are determined from transport equations for the turbulent kinetic energy (R), isotropic rate of kinetic energy dissipation (.epsilon.), mean square temperature variance (theta. over bar $^{2}$), and rate of destruction of the temperature variance (.epsilon. $_{\theta}$). Computational results by four-equation model are favorably compared with those obtained by an extended two-equation model. Added advantage of the four-equation model is that it yields quantitative information about the ratio between the velocity time scale and the thermal time scale and more detailed information about turbulent structure. Predicted time scale ratio is within experimental observations by others. Although the mean velocity and temperature fields are similarly predicted by both models, it is found that the four-equation model is preferably candidate for prediction of highly buoyant turbulent flows.

The Study of Cable Fault Case and the Fault Management System of Electrical Facilities for private use (자외선 영상 이미지 비교를 통한 22.9kV 특고압 설비의 상태진단 연구)

  • Kim, Young-Seok;Shong, Kil-Mok
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2009.10a
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    • pp.211-213
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    • 2009
  • This paper was studied about the ultra-violet rays(UV) image area and discharge quantity of 22.9kV class polymer insulator using UV camera. The UV image area was begun to observe to 60kV that is about 40% of breakdown voltage of polymer insulator and the area was increased by applied voltage. Also, the discharge quantity was increased at 60kV sharply. If the intensity of breakdown passes over about 40% we can know that need the check on the electrical facility.

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Diagonoses of Power Transformer Using Acoustic Emission Techniques (음향기술을 이용한 전력용 변압기 예방진단)

  • Hwang, S.J.;Kwak, H.R.;Jeon, H.J.;Kim, J.C.;Park, J.W.;Choi, S.A.
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.938-941
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    • 1992
  • This paper presents an acoustic emission(AE) technique using ultrasonic sensors to diagonize power transformers. Conventional methods detect and measure the electrical signal of the partial discharge(PD) of transformers in operation. The proposed techniques measures the acoustic signal generated by the partial discharge, and counts the number of the waveforms above a threshold to diagonize transformers. Experiments showed that the proposed method improved diagonosis capability over the conventional PD method.

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A Study on the AC Arc Model of High Pressure Mercury Discharge (고압 수은방전의 교류 아아크 모델에 관한 연구)

  • Chee, Chol-Kon;Kim, Hoon;Lee, Sang-Woo
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.36 no.9
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    • pp.655-659
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    • 1987
  • This study presents a model of the electrical characteristics of the high-pressure mercury vapour arc discharge. Energy balance equation per unit volume of the arc tube is converted into the one per unit length by assuming the parabolic radial temperature distribution and integrating over the cross-section of the tube. Using this energy balance equation, together with the circuit equation and Ohm's law, the arc voltage and current variation for 1 cycle is numerically calculated and a good result is obtained. A simple method to calculate the axis temperature of the arc tube and the radiation output is also presented.

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A Study on the Aging Characteristics of Power Capacitors using Electrical Methods (전기적 방법을 이용한 전력용 콘덴서 열화특성 연구)

  • 김은식;김영욱;김종서;윤철섭;박대희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.199-202
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    • 1998
  • Power capacitors are highly reliable equipment due to their completely enclosed configuration. Aging diagnosis system using partial discharge(PD) and acoustic emission(AE) is being highlighted as a research area for degradation of power capacitors. Their dielectric strength can be however reduced due to some stresses such as over-voltage or thermal degradation of the insulation material during their long period of operation. In this paper, it has been developed to express the AE of the EVENT(average amplitude) and HIT(pulse count) according to the source location. And real time measurement of PD signals for aging diagnosis of power capacitors.

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Study on Anomalous Electron Diffusion in the Hall Effect Thruster

  • Kwon, Kybeom;Walker, Mitchell L.R.;Mavris, Dimitri N.
    • International Journal of Aeronautical and Space Sciences
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    • v.15 no.3
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    • pp.320-334
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    • 2014
  • Over the last two decades, numerous experimental and numerical efforts have examined physical phenomena in plasma discharge devices. The physical mechanisms that govern the anomalous electron diffusion from the cathode to the anode in the Hall Effect Thruster (HET) are not fully understood. This work used 1-D numerical method to improve our understanding and gain insight into the effect of the anomalous electron diffusion in the HET. To this end, numerical solutions are compared with various experimental HET performance measurements and the effects of anomalous electron diffusion are analyzed. The relationships between the anomalous electron diffusion and important parameters of the HET are also studied quantitatively. The work identifies the cathode mass flow rate fraction, radial magnetic field distribution, and discharge voltage as significant factors that affect anomalous electron diffusion. Additionally, the study demonstrates a computational process to determine the radial magnetic field distribution required to achieve specific thruster performance goals.