• Title/Summary/Keyword: Organic complex

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Fabrication of Complex-shaped mullite Ceamics by Gelcasting (Gelcasting을 이용한 Mullite 세라믹스의 제조)

  • 최연규
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.773-781
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    • 1999
  • A new technique to fabricate complex-shaped mullite has been developed through gelcasting without organic binder. The suspension of a commercial mullite powder and boehmite-SiO2 sol as binder was elecrtrosterically stabilized. Ammonium polymetharylyate was employed as a dispersant for the electrosteric stabilization. Complex-shaped bodies were made through casting and gelation at room temperature. The green bodies were dried at a temperature of 30$^{\circ}C$ and relative humidity of 98% without crack development. The dried bodies were then pressureless-sintered at 1650$^{\circ}C$ for 2 h to get a relative density of 98% The Vickers hardness and 4-point flexural strength of sintered parts were 11.0 GPa and 150MPa respectively which are similar to those of commercially available sintered mullite.

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Chemical Properties of Soils in the Vicinity of Yoch의on Industrial Complex (여천공단 주변지역 토양의 화학적 성질)

  • 문형태;표재훈;김준호
    • The Korean Journal of Ecology
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    • v.21 no.1
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    • pp.1-6
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    • 1998
  • Effects of air pollutants on the chemical properties of soil in Yoch'on inductrial complex were investigated. Soil pH showed severe acidity with average value of 4.3$\pm$0.13. Soil pH decreaed along the increase in altitute of Mt. Jeseok. Soil organic matter and total N was 19.2$\pm$3.6% and 4.7$\pm$0.25mg/g, respectively, which were higher than those of unpolluted area, Kongju. Available P was 41.2$\pm$3.7 $\mu$g/g, which was 4 times greater than that of unpolluted area, Kongju. Average content of total-S was 283.5$\pm$14.1 $\mu$g/g, which was 10 times greater than that of unpolluted area. Content of available Al was o.43$\pm$0.03 mg/g, which was 2 times greater than that of unpolluted area. Available Al increased as the soil pH decrease. Contents of exchangeable K, Ca and Mg were significantly lower than those in unpolluted area, because of severe leaching in acid soil.

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Coating Properties of Organic Conducting Materials (유기 전도성 화합물질의 코팅특성)

  • 심재훈;서광석;윤호규;구자윤;박영인;김종은
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.681-684
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    • 1999
  • N-methyl phenazinium 7, 7, 8, 8-tetra-cyanoquinonedimethane (TCNQ) complex salt was synthesized and bar-coated on PET film using various binders. Optical microscope and SEM reveals that TCNQ complex salt crystals were grown on the surface of binders and the shape was different with binders. The surface resistivity was 1$^{5}$ $\Omega$/$\square$ when binders has compatibility with TCNQ complex salt.

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NMR Studies on the Isomerization of Vanadium(V)-Propylenediaminetetraacetate Complex in Solution

  • Han, Sang-Gyu;Park, Sam-Soo;Lee, Man-Ho;Park, Heai-Ku
    • Bulletin of the Korean Chemical Society
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    • v.25 no.1
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    • pp.106-108
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    • 2004
  • In this paper we have determined the thermodynamic parameters for the isomerization between the ${\alpha}$-cis and the ${\beta}$-cis isomers in vanadium(V)-propylenediaminetetraacetate complex in water by $^{51}V$ NMR spectroscopy. In addition, the effects of organic solvents (methanol, formamide and dimethylsulfoxide) and inorganic salts (NaCl, $NaClO_4\;and\;NH_4Cl$) on the isomerization in solution have been investigated.

Exploring a zero food waste system for sustainable residential buildings in urban areas

  • Oh, Jeongik;Lee, Hyunjeong
    • Environmental Engineering Research
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    • v.23 no.1
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    • pp.46-53
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    • 2018
  • This study explores the environmentally innovative and low-impact technology, a zero food waste system (ZFWS) that utilizes food waste and converts it into composts or biofuels and curtails carbon emissions. The ZFWS not just achieves food waste reductions but recycles food waste into fertilizer. Based on a fermentation-extinction technique using bio wood chips, the ZFWS was employed in a field experiment of the system installed in a large-scale apartment complex, and the performance of the system was examined. The on-site ZFWS consisted of three primary parts: 1) a food waste slot into which food waste was injected; 2) a fermentation-extinction reactor where food waste was mixed with bio wood chips made up of complex enzyme and aseptic wood chips; and 3) deodorization equipment in which an ultraviolet and ozone photolysis method was employed. The field experiment showed that food waste injected into the ZFWS was reduced by 94%. Overall microbial activity of the food waste in the fermentation-extinction reactor was measured using adenosine tri-phosphate (ATP), and the degradation rate of organic compounds, referred to as volatile solids, increased with ATP concentration. The by-products generated from ZFWS comply with the national standard for organic fertilizer.

Recovery of nitrogen by struvite precipitation from swine wastewater for cultivating Chinese cabbage

  • Ryu, Hong-Duck;Lee, Han-Seul;Lee, Sang-Ill
    • Journal of Environmental Science International
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    • v.24 no.10
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    • pp.1253-1264
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    • 2015
  • This study assessed the fertilizing value of struvite deposit recovered from swine wastewater in cultivating Chinese cabbage. Struvite deposit was compared with commercial fertilizers: complex, organic and compost to evaluate the fertilizing effect of struvite deposit. Laboratory pot test obviously presented that the struvite deposit more facilitated the growth of Chinese cabbage than organic and compost fertilizers even though complex fertilizer was the most effective in growing Chinese cabbage. It was revealed that the growth rate of Chinese cabbage was simultaneously controlled by phosphorus (P) and potassium (K). Also, the nutrients such as nitrogen (N), P, K, calcium (Ca) and magnesium (Mg) were abundantly observed in the vegetable tissue of struvite pot. Specifically, P was the most abundant component in the vegetable tissue of struvite pot. Meanwhile, the utilization of struvite as a fertilizer led to the lower accumulation of chromium ($Cr^{6+}$) than other pots, except for compost fertilizer pots, and no detection of cadmium (Cd), arsenic (As) and nickel (Ni) in the Chinese cabbage. The experimental results proved that the optimum struvite dosage for the cultivation of Chinese cabbage was 2.0 g struvite/kg soil. On the basis of these findings, it was concluded that the struvite deposits recovered from swine wastewater were effective as a multi-nutrient fertilizer for Chinese cabbage cultivation.

COMPARISON OF RED TIDE DETECTION BY A NEW RED TIDE INDEX METHOD AND STANDARD BIO-OPTICAL ALGORITHM APPLIED TO SEA WIFS IMAGERY IN OPTICALLY COMPLEX CASE-II WATERS

  • Shanmugam Palanisamy;Ahn Yu-Hwan
    • Proceedings of the KSRS Conference
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    • 2005.10a
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    • pp.445-449
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    • 2005
  • Various methods to detect the phytoplankton/red tide blooms in the oceanic waters have been developed and tested on satellite ocean color imagery since the last two and half decades, but accurate detection of blooms with these methods remains challenging in optically complex turbid waters, mainly because of the eventual interference of absorbing and scattering properties of dissolved organic and particulate inorganic matters with these methods. The present study introduces a new method called Red tide Index (Rl), providing indices which behave as a good measure of detecting red tide algal blooms in high scattering and absorbing waters of the Korean South Sea and Yellow Sea. The effectiveness of this method in identifying and locating red tides is compared with the standard Ocean Chlorophyll 4 (OC4) bio-optical algorithm applied to SeaWiFS ocean imagery, acquired during two bloom episodes on 27 March 2002 and 28 September 2003. The result revealed that OC4 bio-optical algorithm falsely identifies red tide blooms in areas abundance in colored dissolved organic and particulate inorganic matter constituents associated with coastal areas, estuaries and river mouths, whereas red tide index provides improved capability of detecting, predicting and monitoring of these blooms in both clear and turbid waters.

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Isolation of Antifungal Active Compounds from the Leaves of Lindera erythrocarpa (비목나무(Lindera erythrocarpa) 잎으로부터 항진균성 활성물질의 분리)

  • Kwon, Sun-Youl;Kim, Jin-Ho;Baek, Nam-Ln;Choi, Gyung-Ja;Cho, Kwang-Yun;Lee, Byung-Moo;Choi, Yong-Hwa
    • Applied Biological Chemistry
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    • v.46 no.2
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    • pp.150-153
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    • 2003
  • Methanol extract obtained from Lindera erythocarpa leaves was successively fractionated with n-hexane, ethylacetate, n-butanol, and $H_2O$. From ethylacetate fraction, an active fraction was isolated through repeated silica gel column chromatography and recrystallization, and was identified as a stereoisomer complex of methyllucidone by MS and MMR analyses. The complex showed 85% antifungal activity at 50 {\mu}g/ml$ against the disease wheat leaf rust.

Automated On-Line Digestion System for the Determination of Total Phosphorus (총 인 분석을 위한 자동 전처리 시스템)

  • 정형근;조영일;김범식;박주형
    • Journal of Environmental Science International
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    • v.10 no.1
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    • pp.13-19
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    • 2001
  • An on-line digestion system based on the flow injection analysis technique was presented for the determination of total phosphorus. The system converts condensed and organic phosphoruses into orthophosphate that can be analyzed spectrophotometically. The reaction between orthophosphate and ammonium molybdate in a strong acid medium forms the yellow complex of phosphomolybdate which is next reduced to a molybdic blue complex by stannous chloride. The quantitation of orthophosphate is based on the absorbance of the molybdic blue. To determine total phosphorus, the digestion system was installed between the sample injector and the reaction coil with the added lines of digestion solution(potassium persulfate+sulfuric acid) and the $H_2O$ carrier. The system has shown that the digestion efficiencies were greater than 95% for the typical condensed and organic phosphoruses. When tripolyphosphate standards were used, the calibration data showed that the linear dynamic range extended to a concentration of 1.5ppm with the detection limit of 25ppb total phosphorus. The typical relative standard deviation was less than 2%. The proposed system was successfully applied to lake water, wastewater, and streamwater. The analytical variables such as digestion efficiency, analysis time, and reproducibility were evaluated and compared with the manual digestion method.

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Cytocompatible Coating of Individual Mammalian Cells with Tannic Acid-Zn Complex (타닌산-아연 복합체를 이용한 단일수준에서의 동물세포 코팅)

  • Lee, Juno
    • KSBB Journal
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    • v.32 no.2
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    • pp.160-167
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    • 2017
  • Coating of individual cells with organic or inorganic materials has drawn a great deal of attention, because it provides the cells with physicochemical durability, which would contribute to the development of bioreactors, biosensor, and lab-on-a-chip, as well as to the fundamental studies in single cell-based biology. Although many strategies have been developed for coating of microbial cells, limited methods are available to coat mammalian cells because most mammalian cells do not have a robust membrane or exoskeleton. Instead, they are enclosed in a lipid bilayer, which is fluidic and vulnerable to changes in its environments. It is more difficult to treat mammalian cells in vitro than microbial cells because the surfaces of mammalian cells are not protected or reinforced by a tough coat. In this work, we report a cytocompatible and degradable nanocoat for mammalian cells. Three types of mammalian cells (HeLa cells, NIH 3T3 fibroblasts, and Jurkat T cells) were individually coated within metal-polyphenol. To maintain the viability of the mammalian cells, we performed the whole processes under strictly physiological culture conditions, and carefully selected nontoxic materials.