[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5012/bkcs.2004.25.1.106

NMR Studies on the Isomerization of Vanadium(V)-Propylenediaminetetraacetate Complex in Solution

Han, Sang-Gyu (Department of Industrial Chemistry, Kyungpook National University)
Park, Sam-Soo (Department of Industrial Chemistry, Kyungpook National University)
Lee, Man-Ho (Department of Industrial Chemistry, Kyungpook National University)
Park, Heai-Ku (Department of Chemical System Engineering, Keimyung University)

Publication Information

Bulletin of the Korean Chemical Society / v.25, no.1, 2004 , pp. 106-108 More about this Journal

Abstract

In this paper we have determined the thermodynamic parameters for the isomerization between the ${\alpha}$ -cis and the ${\beta}$ -cis isomers in vanadium(V)-propylenediaminetetraacetate complex in water by $^{51}V$ NMR spectroscopy. In addition, the effects of organic solvents (methanol, formamide and dimethylsulfoxide) and inorganic salts (NaCl, $NaClO_4\;and\;NH_4Cl$ ) on the isomerization in solution have been investigated.

Keywords

Isomerization; $^{51}V$ NMR; Vanadium(V) complex; Propylenediaminetetraacetate;

Citations & Related Records

Times Cited By KSCI : 1 (Citation Analysis)
Times Cited By Web Of Science : 3 (Related Records In Web of Science)
Times Cited By SCOPUS : 2

1	Scheidt, W. R.; Tsai, C. C.; Hoard, J. L. J. Am. Chem. Soc. 1971,93, 3867. DOI
2	Robson, R. L.; Eady, R. R.; Richardson, T. H.; Miller, R. W.;Hawkins, M.; Postgate, J. R. Nature 1986, 322, 388. DOI
3	Reder, D. Angew. Chem. Intl. Ed. Engl. 1991, 30, 148. DOI
4	Przyborowski, L; Schwarzenbach, G.; Zimmerman, T. Helv.Chim. Acta 1965, 48, 1556. DOI
5	Lee, M.-H.; Heo, N. H.; Oh, Y. K. Bull. Korean Chem. Soc. 2002,23, 1661. DOI ScienceOn
6	Gutmann, V. Coord. Chem. Rev. 1976, 18, 225. DOI ScienceOn
7	Mcneill, J. H.; Yuen, V. G.; Hoveyda, H. R.; Orvig, C. J. Med.Chem. 1992, 35, 1489. DOI
8	Amos, L. W.; Sawyer, D. T. Inorg. Chem. 1972, 11, 2692. DOI
9	Crans, D. C.; Shin, P. K. J. Am. Chem. Soc. 1994, 116, 1305. DOI ScienceOn
10	Smith, M. J.; Kim, D.; Horenstein, B.; Nakanishi, K.; Kustin, K.Acc. Chem. Res. 1991, 24, 117. DOI
11	Viller, H. Phytochemistry 1984, 23, 1387. DOI ScienceOn
12	Saito, K.; Sasaki, Y. Pure Appl. Chem. 1988, 60, 1123. DOI
13	Yamada, S.; Nagase, J.; Funabashi, S.; Tanaka, M. J. Inorg. Nucl.Chem. 1976, 38, 617. DOI ScienceOn
14	Shechter, J.; Karlish, S. J. D. Nature 1980, 284, 556. DOI ScienceOn
15	Scheidt, W. R.; Countryman, R.; Hoard, J. L. J. Am. Chem. Soc.1971, 93, 3878. DOI
16	Crans, D. C.; Keramidas, A. D.; Mahroof-Tahir, M.; Anderson, O.P.; Miller, M. M. Inorg. Chem. 1996, 35, 3599. DOI ScienceOn
17	Kustin, K.; Toppen, D. L. J. Am. Chem. Soc. 1973, 95, 3564. DOI