• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.827-837
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• 2022

If the hydrogen industry is activated, the introduction of C-type and pressurized liquefied hydrogen (LH2) tank suitable for small and medium-sized transp- ortation and storage will be given priority in the future. Therefore in this paper, the behavior for the LH2 property changes and boil-off gas (BOG) treatment of the C-type cargo tank through voyage of the LH2 carrier and pressurized tank of the LH2 receiving terminal were analyzed through computational simulations by making assumptions about the carrier operation and unloading conditions.

• 청정기술
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• 제18권2호
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• pp.191-199
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• 2012

다시마 유래 이취 및 휘발성 유기 성분을 효과적으로 저감 또는 제거하기 위하여, 초임계 이산화탄소의 연속적인 처리 공정이 실험적으로 적용되었다. 다시마 시료는 동결 건조 후 $710{\mu}m$의 크기로 균질화하여 사용하였으며, 초임계 이산화탄소 처리에 의한 효과를 평가하기 위하여 다양한 압력(10~25 MPa) 및 온도(35~$55^{\circ}C$) 조건에서 실험을 수행하였다. 한편, 실험에 사용된 이산화탄소의 유입 유속은 26.81 g/min으로 일정하게 고정하였다. 초임계 이산화탄소 처리 전과 후, 다시마 유래 이취 및 휘발성 유기 성분은 기체 크로마토그래피-질량분석기에 의하여 동정되었으며, 다시마 원료에서 알코올, 알데하이드, 에스터 및 산, 케톤, 할로젠 화합물 그리고 탄화수소계를 주 성분으로 하는 총 47종의 이취 및 휘발성 유기 성분이 동정되었다. 초임계 이산화탄소 처리 후 모든 실험 조건에서 이취 및 휘발성 유기 성분이 저감 또는 제거되었고, 그 중 25 MPa, $55^{\circ}C$의 실험 조건에서 87.48%로 가장 높은 제거율을 보여주었다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.494-497
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• 2006

For commercialization of polymer electrolytemembrane fuel cell (PEMFC), durability of membrane electrode assemblies (MEAs) has to be improved. Especially, long-term stability of MEA is one of the most important issues for frequent shut-down and start-up processes of PEMFC. The degradation of MEA could be attributed to chemical attack of hydrogen peroxide radicals that are formed at high cell voltages without any special treatment to remove residual hydrogen from anode gas channel after shut-down of the fuel cell. In this study, we investigated the long-term stability of MEA under different on/off operation conditions. Residential hydrogen gas was removed from the anode flow channel by purging air or nitrogen. Also, a dummy resistance was applied to the fuel cell to exhaust residential hydrogen at the anode. In these cases, MEA showed much more stable durability. Electrochemical characteristics of the fuel cell were measured byrepeating the on/off cycles with the hydrogen removal processes. Also, degradation of MEA components was examined by SEM, TEM and XRD analyses.

• 대한전자공학회논문지SD
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• 제44권11호
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• pp.15-19
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• 2007

OTFTs (Organic Thin Film Transistors)의 구동에 있어, 게이트 절연막 표면과 채널의 계면상태가 소자의 전기적 특성에 큰 영향을 미치게 된다. OTS(Octadecyltrichlorosilane)등과 같은 습식 SAM(Self Assembly Monolayer)를 이용하거나, $O_2$ Plasma와 같은 건식 표면 처리등 여러 표면 처리법에 대한 연구가 진행되고 있다. 본 논문에서는 pentacene을 진공 증착하기 전에 게이트 절연막을 $O_2$ plasma와 Ar ion beam을 이용하여 건식법으로 전처리 한 후 표면 특성을 atomic force microscope (AFM) and X-ray photoelectron spectroscopy (XPS)를 사용하여 비교 분석하였고, 각 조건으로 OTFT를 제작하여 전기적 특성을 확인하였다. Ar ion beam으로 표면처리 했을 때, $O_2$ plasma처리했을 때 보다 향상된 on/off ratio 전기적 특성을 얻을 수 있었다. 표면 세정을 위하여 $O_2$ plasma 처리시 $SiO_2$ 표면의 OH-기와 반응하여 oxide trap density가 높아지게 되고 이로 인하여 off current가 증가하는 문제가 발생한다. 불활성 가스인 Ar ion beam 처리를 할 경우 게이트 절연막의 세정 효과는 유지하면서, $O_2$ Plasma 처리했을 때 증가하게 되는 계면 trap을 억제할 수 있게 되어, mobility 특성은 동등 수준으로 유지하면서 off current를 현저하게 줄일 수 있게 되어, 결과적으로 높은 on/off ratio를 구현할 수 있다는 것을 확인하였다.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
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• pp.745-748
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• 2000

Anaerobic digester coupled with hollow fiber membrane unit. Treatment of starch waste with anaerobic digester-membrane system was studied. $0.17\;m^2$ area of hollow fiber membrane unit of known pore size was immersed into laboratory-scale anaerobic digestion system. The gas production was about $0.74\;m^3/kg$ COD treated. The COD removal efficient was about 80-95% depending on the hydraulic retention time. Crossflow ultrafiltration as Post treatment to anaerobic filter. The study conducted with different membrane pore size indicated that membrane with 1,000,000 molecular weight cut-off size gave a higher COD removal efficiency in the range of 83-87% while giving a study flux of $120-130\;L/m^2\;{\cdot}\;h$. A study was conducted to see the long term clogging effect of membrane also.

• 한국식품저장유통학회지
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• 제19권1호
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• pp.7-11
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• 2012

온주밀감의 산함량 감소를 목적으로 열처리를 실시할 때 습도와 가스조성의 환경조건이 과실 품질에 미치는 영향을 알아보고자 필름을 이용한 실험을 실시하였다. 필름은 18 ${\mu}m$ HDPE 천공필름, 30 ${\mu}m$ LDPE, 100 ${\mu}m$ LDPE 필름을 이용하였고, $30^{\circ}C$에서 55시간 열처리를 실시하였다. 열처리 후 산함량은 모든 처리구에서 처리 전보다 유의하게 감소하였고, 가용성고형물 함량은 변화가 없어 결과적으로 당산비가 증가하여 품질 향상의 효과가 있었다. 그러나 열처리 중 습도가 낮았던 필름 무처리구는 비슷한 가스조성의 HDPE 천공필름 보다 에탄올 및 아세트알데하이드 함량과 이취정도가 높은 경향이었고, 필름 처리구들 중에서도 필름 내부의 $CO_2$ 농도가 높고 $O_2$가 낮을수록 두 휘발성분 함량도 급격히 증가하고 이취발생이 심하여 신선도가 떨어지는 것이 관찰되었다. 결론적으로, 온주밀감의 산함량 감소를 위한 열처리 시 습도는 90%이상, 온도 처리실의 가스조성은 정상 대기를 유지하는 것이 이취관련 성분의 발생을 줄여 신선도를 유지할 수 있을 것으로 생각된다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.9-18
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• 2001

1. EAF Dust in Japan - Generation and Characteristics. The quantity of dust generated from EAF shops in Japan was estimated to be 520,000 tons/year in 1999. Extremely fine dust (or fume) is formed in the EAF by metal vaporization. Its characteristics such as chemical compositions, phases, particle size, leaching of heavy metal are mentioned. 2. EAF Dust Treatment Methods in Japan. In 1999, 61% of EAF dust was treated by regional zinc recovery processing routes, 25% went to landfill disposal, 4% was reused as cement material, and 10% was treated by on-site processing routes. The problems of EAF dust treatment methods in Japan are: (1) very high treatment cost, and (2) heavy environmental load (leaching of heavy metal, emission of dioxins, depletion of disposal sites, etc). It has been much hoped for that new dust management technology would be developed. 3. New technology of EAF dust treatment in Japan. In Japan, some new technologies of EAF dust treatment have been developed, and some others are in the developing stages. Following five processes are mentioned:. (1) Smelting reduction process by Kawasaki Steel, (2) DSM process by Daido Steel, (3) VHR process by Aichi Steel, (4) On-site dust direct recycling technology, and (5) Process technology of direct separation and recovery of iron and zinc metals contained in high temperature EAF off gas by the Japan Research and Development Center fur Metals.

• 한국대기환경학회지
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• 제33권2호
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• pp.87-96
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• 2017

In this study, 4 gases containing typical chlorinated volatile organic compounds (VOCs) were treated by ultraviolet (UV) irradiation. The typical chlorinated VOCs are dichloromethane (DCM), trichloromethane (TCM), carbon tetrachloride (CTC) and trichloroethylene (TCE). The removal efficiency (RE) and the products of chlorinated VOCs by UV irradiation are investigated. At this time, 2 types of background gas (air and nitrogen) were used to figure out the RE by photooxidation and photolysis. The specification of UV-lamp used in this study was low-pressure mercury lamp emitting wavelength of 185~254 nm. The experimental conditions were set as initial VOC concentration of $180{\pm}10ppm$, empty bed retention time (EBRT) of 53 s, temperature of $23{\pm}2^{\circ}C$ and relative humidity of $65{\pm}5%$. In the photolysis condition with nitrogen ($N_2$) as background gas, the averaged RE of the 4 types of chlorinated VOCs was about 24% higher than that with photooxidation; and the REs of VOCs except CTC were confirmed as >99%. The composition of off-gases after UV photooxidation in air was investigated and several intermediates from DCM, TCM and TCE were detected by GC/MS. Among them, phosgene which is a toxics was detected as an intermediate of TCM. In addition, the concentration of carbon dioxide ($CO_2$) in the off-gases was measured to calculate the mineralization rate (MR). With the photooxidation, TCE showed the highest RE (>99%) while MR was the lowest (17%); and the MR of DCM was the highest (86%). In addition, particulate matters (PM) in the off-gases was also detected and high concentrated $PM_{10}$ ($21,580{\mu}g{\cdot}m^{-3}$) and $PM_{2.5}$ ($6,346{\mu}g{\cdot}m^{-3}$) were detected in TCE off-gas. More than 99% of the chlorinated VOCs could be removed using UV254-185 nm lamp, while it is necessary to conduct further studies on the production and treatment of secondary pollutants.

• 한국주조공학회지
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• 제15권5호
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• pp.477-482
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• 1995

A computer simulation model of various smelting process for melting waste sand was developed by using energy and material balance concept. This model can predict the coal, flux and oxygen consumption and the volume and temperature of off-gas. The major critical variables for smelting process can be explained by using the analysis of energy and material balance. The major conclusions were as follows; 1. The most important variables for smelting process were high post-combustion ratio, high heat transfer efficiency and refractory protection technology. 2. For saving energy in this smelting process, selection of raw materials i.e coal, flux are very important, espacially using of low volatile coal is very profitable. 3. The treatment cost of waste sand is high and environmental restriction is severe, in this reason we must be concerned in the treatment of waste sand by smelting process.

• KSBB Journal
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• 제6권2호
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• pp.135-141
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• 1991

This study thus looks into two treatment processess : i) Anaerobic digester coupled with hollow fibre membrane unit. Treatment of starch waste with anaerobic digester-membrane system was studied. $0.17\m^2$ area of hollow fibre membrane unit of known pore size was immersed into laboratory-scale anaerobic digestion system. The pore size of membrane was varied from 0.03 to $\0.15mu$m. The hydraulic retention time of anaerobic digester was varied from 1.5 to 10 days. The effect of hydraulic retention time on treatment efficiency was significant while effect of membrane size was not significant. The gas production was about 0.74㎥/kg COD treated. The COD removal efficient was about 80-95% depending on the hydraulic retention time. ii ) Crossflow ultrafiltration as post treatment to anaerobic filter. The effluent from anaerobic filter, which had a total COD in the range of 4,500-5,200 mg/L was treated by crossflow ultrafiltration units. The study conducted with different membrane pore size indicated that membrace with 1,000,000 molecular weight cut-off size gave a higher COD removal efficiency in the range of 83-87% while giving a study flux of $120-130 L/\m^2$.h. A study was conducted to see the long term clogging effect of membrane also.