• Title/Summary/Keyword: O/F Ratio

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Identification of Tetrachloroethylene Sorption Behaviors in Natural Sorbents Via Sorption Models

  • Al Masud, Md Abdullah;Choi, Jiyeon;Shin, Won Sik
    • Journal of Soil and Groundwater Environment
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    • v.27 no.6
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    • pp.47-57
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    • 2022
  • A number of different methods have been used for modeling the sorption of volatile organic chlorinated compounds such as tetrachloroethylene/perchloroethylene (PCE). In this study, PCE was adsorbed in several natural sorbents, i.e., Pahokee peat, vermicompost, BionSoil®, and natural soil, in the batch experiments. Several sorption models such as linear, Freundlich, solubility-normalized Freundlich model, and Polanyi-Manes model (PMM) were used to analyze sorption isotherms. The relationship between sorption model parameters, organic carbon content (foc), and elemental C/N ratio was studied. The organic carbon normalized partition coefficient values (log Koc = 1.50-3.13) in four different sorbents were less than the logarithm of the octanol-water partition coefficient (log Kow = 3.40) of PCE due to high organic carbon contents. The log Koc decreased linearly with log foc and log C/N ratio, but increased linearly with log O/C, log H/C, and log (N+O)/C ratio. Both log KF,oc or log KF,oc decreased linearly with log foc (R2 = 0.88-0.92) and log C/N ratio (R2 = 0.57-0.76), but increased linearly with log (N+O)/C (R2 = 0.93-0.95). The log qmax,oc decreased linearly as log foc and log C/N increased, whereas it increased with log O/C, log H/C and log (N+O)/C ratios. The log qmax,oc increased linearly with (N+O)/C indicating a strong dependence of qmax,oc on the polarity index. The results showed that PCE sorption behaviors were strongly correlated with the physicochemical properties of soil organic matter (SOM).

Recovery of An, Ag, and Ni from PCB Wastes by CaF2-containing Slag (형우(螢右) 함유(含有) 슬래그 노이(盧理)를 통한 PCB 스크랩으로부터 Au, Ag, Ni의 회수(回收)에 관한 연구(班究))

  • Park, Joo-Hyun
    • Resources Recycling
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    • v.20 no.4
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    • pp.58-64
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    • 2011
  • Recovery of novel metals such as Au, Ag and Ni from wastes PCB was investigated by slag treatments. The CaO-$Al_2O_3$(-$SiO_2$) and CaO-$SiO_2$-$CaF_2$ slags were employed in the present study. The PCB/Cu ratio is recommended to be lower than unity. The use of CaO-$SiO_2$-$CaF_2$ slag provided the more higher yield of Au, Ag and Ni than the CaO-$Al_2O_3$(-$SiO_2$) slag did, which was mainly due to the lower melting point and the viscosity of $CaF_2$-containing slag. The terminal descending velocity of metal droplets in the slag phase increased with decreasing slag viscosity.

Effect of Dietary Fat on Hepatic Mitochondrial {TEX}$F_{1}${/TEX}{TEX}$F_{0}${/TEX}ATPase Characteristics in NIDDM-prone Rat

  • Kim, Sook-Bae B.;Kim, Chang-Im
    • Preventive Nutrition and Food Science
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    • v.5 no.4
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    • pp.230-233
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    • 2000
  • The present work was designed to determine whether change in fluidity of the mitochondrial membrane affects mitochondrial {TEX}$F_{1}${/TEX}{TEX}$F_{0}${/TEX}ATPase characteristics in NIDDM-prone BHE/Cdb rat. Isolated mitochondria fom BHE/Cdb rat fed a 6% coconut oil or corn oil were functionally tested by an analysis of its respiration and the coupling of this process to ATP synthesis in presence of oligomycin, a specific inhibitor of oxidative phosphorylation (OXPHOS), that binds to the {TEX}$F_{1}${/TEX}{TEX}$F_{0}${/TEX}ATPase. Mitochondria from rats fed coconut oil were more responsive to the inhibitory action of oligomycin with respect to state 3 respiration, respiratory control (RC) ratio and ADP:P (P/O) ratio than were mitochondria from rats fed corn oil. In state 3 respiration, mitochondria from rats fed coconut oil consumed less oxygen than did mitochondria from rats fed corn oil. RC ratio was lower in the mitochondria from rats fed coconut oil than was mitochondria from rats fed corn oil. In P/O ratio, the mitochondria from rats fed coconut oil had a lower P/O ratio than did mitochondria from rats fed corn oil. The data showed that the chang influidity of the mitochondrial membrane by dietary fat affected mitochondrial {TEX}$F_{1}${/TEX}{TEX}$F_{0}${/TEX}ATPase characteristics. The present study on diet differences in {TEX}$F_{1}${/TEX}{TEX}$F_{0}${/TEX}ATPase characteristics provides considerable insight into the role diets play in the control of mitochondrial function, expecially OXPHOS in NIDDM with mitochondrial defects.

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A study on the combustion performance with Hydrogen Peroxide / Kerosene (과산화수소/ 케로신을 추진제로 한 200N급 엔진의 연소 성능에 관한 연구)

  • Kim, Young-Mun;Hwang, Oh-Sik;Lee, Yang-Suk;Ko, Young-Sung;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.61-64
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    • 2009
  • A study on the variation of combustion performance by oxidizer/fuel ratio was conducted. Shower head type injector was used. Injector propelled by liquid kerosene and liquid hydrogen peroxide. The designed operation condition for thrust and combustion pressure were 200N and 10bar. It is found that optimum oxidizer/fuel ratio.

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Fuel Rich Gas O/F Ratio Characteristics of HDPE and Paraffin Fuel in Low Range of the Oxidizer Mass Flux (저 산화제유속 구간에서의 HDPE 및 Paraffin 연료의 연료농후가스 O/F비 특성)

  • Han, Seongjoo;Ryu, Sunghoon;Kim, Jinkon;Kang, Teagon;Moon, Heejang;Kim, Junhyung;Ko, Seung Won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.6
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    • pp.54-60
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    • 2016
  • Multi-port HDPE and Paraffin firing tests are conducted for hybrid gas generator application of a ducted rocket in the low oxidizer mass flux range. A fuel rich gas of O/F ratio from 0.3 to 0.8, a typical O/F operating range of a ducted rocket gas generator, have been achieved with paraffin fuel implying that the hybrid system can be a potential candidate. It was also found that an almost constant O/F ratio regime exists under $35kg/m^2s$ of the oxidizer mass flux, opening a possibility for the paraffin fuel toward the VFDR gas generator application.

Combustion Characteristics of Multi-port Hybrid Rocket (Multi-port 하이브리드 로켓의 연소 특성)

  • Kim, Soo-Jong;Min, Moon-Ki;Cho, Sung-Bong;Moon, Hee-Jang;Sung, Hong-Gye;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.256-259
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    • 2007
  • In this paper, the combustion characteristics of hybrid rocket were studied with various port number of the cylindrical multi-port grain. For the regression rate case, as the port number increases, the both port regression rate and end-surface regression rate tend to increase. For the performance parameter case, as the port number increases, the O/F ratio tends to decreases and the specific impulse tends to increase.

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충돌형 가스발생기 탈설계점 연소시험

  • Kim, Seung-Han;Han, Yeung-Min;Seo, Seong-Hyeon;Moon, Il-Yoon;Lee, Kwang-Jin;Kim, Jong-Kyu;Seol, Woo-Seok
    • Aerospace Engineering and Technology
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    • v.3 no.2
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    • pp.81-90
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    • 2004
  • This paper describes the results of combustion performance test of fuel-rich gas generator(GG) using LOx and kerosene as propellant at off-design conditions. The chamber pressure is thought to be a function of O/F ratio and total propellant mass flow rate. The test shows that the spatial temperature deviation at the exit of gas generator remains within 7.5K and that the average gas temperature at the exit is a function of propellant O/F ratio. The results of firing test of gas generator at off-design conditions, especially the relation between gas temperature and O/F ratio, can provide useful data for the design of future gas generator and for the development of low-O/F ratio reaction analysis code.

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Phantom Study of the Mutual Influences Between 18F-FDG and 99mTcO4- on the Same Day (18F-FDG와 99mTcO4-를 이용한 당일 검사 시 상호 영향에 대한 Phantom 연구)

  • Ham, Jun Cheol;Park, Min Soo;Bahn, Young Kag;Lim, Han Sang;Kim, Jae Sam
    • The Korean Journal of Nuclear Medicine Technology
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    • v.18 no.2
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    • pp.68-72
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    • 2014
  • Purpose The nuclear medicine examination, there is a difficulty to carry out the inspection of both on the day of residual isotope due to the half-life. In this study, by studying the mutual influence and $^{18}F$-FDG of $^{99m}TcO_4{^-}$, I would like to explain the matters to be considered in the case of performing the same day. Materials and Methods With the NEMA-1994 Phantom, and experiments were performed 3 times. Create a 1: 4 Background ratio HOT and the $^{99m}TcO_4{^-}$ The first experiment: After underwent SPECT in INFINIA (GE Healthcare, MI, USA), and were injected with $^{18}F$-FDG 37 MBq in the Background area, 13 once for 60 minutes under the same conditions was time Scan. Create a 1: 4 Background ratio HOT and the $^{18}F$-FDG second is: The Scan in PET/CT Discovery 600 (GE Healthcare, MI, USA), and 148 MBq after injection $^{99m}TcO_4{^-}$ the Background area, once for 60 minutes, 6 under the same conditions was time Scan. Create a 1: 4 Background ratio HOT and the $^{18}F$-FDG experiments las, increments of 296 MBq and 148 MBq the 1 Bed Scan after $^{99m}TcO_4{^-}$, was 1 Bed Scan under the same conditions. Non BKG area and HOT, I was measured comparing the Total Counts and SNR or CNR. Results Showed a significant difference in the ratio CNR of enforcement during SPECT $^{18}F$-FDG is, (p>0.05). The $^{99m}TcO_4{^-}$ was no significant difference between the SNR ratio of PET / CT at the time of the effective date (p<0.05). I got the results $^{99m}TcO_4{^-}$ that reduce the Total Counts of PET / CT scan. Conclusion If you make a PET / CT scan, may affect the test using the $^{99m}TcO_4{^-}$ up to 12 hours, when it is performed before the $^{99m}TcO_4{^-}$, does not affect the SNR and SUV, PET / CT scan I reduced the detection efficiency. The inspection of day, we'd like to recommend a way to complement the detection efficiency to increase the inspection time of PET / CT in move forward the inspection using the $^{99m}TcO_4{^-}$.

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$SiO_2$ Etching in $C_4F_{8}$ Plasma by E-ICP ($C_4F_{8}O_2$ 공정기체와 E-ICP를 이용한 산화막 식각)

  • 송호영;조수범;이종근;오범환;박세근
    • Proceedings of the IEEK Conference
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    • 2001.06b
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    • pp.197-200
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    • 2001
  • Novel Enhanced Inductively Coupled Plasma is applied to etch $SiO_2$. Effect of $O_2$ or Ar addition to $C_{4}F_{8}$ gas is monitored by Optical Emission Spectroscopy and Quadrupole Mass Spectrometer. It is fund that Ar or $O_2$ dilution to $C_{4}F_{8}$ increases F emission intensity and decreases $CF_2$ intensity. However, the ac frequency to the Helmholtz coil decreases the F intensity and thus increases $CF_2$/F ratio. By adjusting the ac frequency, the optimum etch rate and PR to $SiO_2$ selectivity can be obtained in E-lCP.

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Study on Combustion Characteristic of GOx/PE Hybrid Rocket According to Port Diameter (GOx/PE 하이브리드 로켓의 포트 직경에 따른 연소특성 연구)

  • Choi, Jae-Sung;Huh, Hwan-Il
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.692-693
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    • 2010
  • In this study, we analyze the combustion characteristic of GOx/PE hybrid rocket, by changing port diameter of the propellant. To study combustion characteristics of hybrid rocket, GOx is used for oxidizer and PolyEthylene is used for solid propellant. Regression rate and O/F ratio of the rocket is measured and presented.

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