Browse > Article
http://dx.doi.org/10.7857/JSGE.2022.27.6.047

Identification of Tetrachloroethylene Sorption Behaviors in Natural Sorbents Via Sorption Models  

Al Masud, Md Abdullah (School of Architecture, Civil, Environmental and Energy Engineering, Kyungpook National University)
Choi, Jiyeon (School of Architecture, Civil, Environmental and Energy Engineering, Kyungpook National University)
Shin, Won Sik (School of Architecture, Civil, Environmental and Energy Engineering, Kyungpook National University)
Publication Information
Journal of Soil and Groundwater Environment / v.27, no.6, 2022 , pp. 47-57 More about this Journal
Abstract
A number of different methods have been used for modeling the sorption of volatile organic chlorinated compounds such as tetrachloroethylene/perchloroethylene (PCE). In this study, PCE was adsorbed in several natural sorbents, i.e., Pahokee peat, vermicompost, BionSoil®, and natural soil, in the batch experiments. Several sorption models such as linear, Freundlich, solubility-normalized Freundlich model, and Polanyi-Manes model (PMM) were used to analyze sorption isotherms. The relationship between sorption model parameters, organic carbon content (foc), and elemental C/N ratio was studied. The organic carbon normalized partition coefficient values (log Koc = 1.50-3.13) in four different sorbents were less than the logarithm of the octanol-water partition coefficient (log Kow = 3.40) of PCE due to high organic carbon contents. The log Koc decreased linearly with log foc and log C/N ratio, but increased linearly with log O/C, log H/C, and log (N+O)/C ratio. Both log KF,oc or log KF,oc decreased linearly with log foc (R2 = 0.88-0.92) and log C/N ratio (R2 = 0.57-0.76), but increased linearly with log (N+O)/C (R2 = 0.93-0.95). The log qmax,oc decreased linearly as log foc and log C/N increased, whereas it increased with log O/C, log H/C and log (N+O)/C ratios. The log qmax,oc increased linearly with (N+O)/C indicating a strong dependence of qmax,oc on the polarity index. The results showed that PCE sorption behaviors were strongly correlated with the physicochemical properties of soil organic matter (SOM).
Keywords
Elemental ratio; Sorption; Sorbent; Solubility-normalization; Soil organic matter; Tetrachloroethylene;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Kim, J.-H., Shin, W.S., Song, D.-I., and Choi, S.J., 2005, Multistep competitive sorption and desorption of chlorophenols in surfactant modified montmorillonite, Water. Air. Soil Pollut., 166, 367-380. https://doi.org/10.1007/s11270-005-6329-5   DOI
2 Allen-King, R.M., Grathwohl, P., and Ball, W.P., 2002, New modeling paradigms for the sorption of hydrophobic organic chemicals to heterogeneous carbonaceous matter in soils, sediments, and rocks, Adv. Water Resour., 25(8-12), 985-1016. https://doi.org/10.1016/S0309-1708(02)00045-3   DOI
3 Carmo, A.M., Hundal, L.S., and Thompson, M.L., 2000, Sorption of hydrophobic organic compounds by soil materials: Application of unit equivalent Freundlich coefficients, Environ. Sci. Technol., 34(20), 4363-4369. https://doi.org/10.1021/es000968v   DOI
4 Chiou, C.T. and Kile, D.E., 1998, Deviations from sorption linearity on soils of polar and nonpolar organic compounds at low relative concentrations, Environ. Sci. Technol. 32(3), 338-343. https://doi.org/10.1021/es970608g   DOI
5 Christensen, E.R., Wang, Y., Huo, J., and Li, A., 2022, Properties and fate and transport of persistent and mobile polar organic water pollutants: A review, J. Environ. Chem. Eng., 10(2), 107201. https://doi.org/10.1016/j.jece.2022.107201   DOI
6 Cornelissen, G., Gustafsson, O., Bucheli, T.D., Jonker, M.T.O., Koelmans, A.A., and Van Noort, P.C.M., 2005, Extensive sorption of organic compounds to black carbon, coal, and kerogen in sediments and soils: Mechanisms and consequences for distribution, bioaccumulation, and biodegradation, Environ. Sci. Technol., 39(18), 6881-6895. https://doi.org/10.1021/es050191b   DOI
7 Devore, C.L., Rodriguez-Freire, L., Villa, N., Soleimanifar, M., Gonzalez-Estrella, J., Ali, A.M.S., Lezama-Pacheco, J., Ducheneaux, C., and Cerrato, J.M., 2022, Mobilization of As, Fe, and Mn from contaminated sediment in aerobic and anaerobic conditions: Chemical or microbiological triggers?, ACS Earth Space Chem., 6(7), 1644-1654. https://doi.org/10.1021/acsearthspacechem.1c00370   DOI
8 Feng, C., Liu, F., Huang, F., Chen, L., and Bi, E., 2023b, Dense nonaqueous phase liquids back diffusion controlled by biodegradation and heterogeneous sorption-desorption, J. Clean. Prod., 382, 135370. https://doi.org/10.1016/j.jclepro.2022.135370   DOI
9 Kan, A.T., Fu, G., Hunter, M., Chen, W., Ward, C.H., and Tomson, M.B., 1998. Irreversible sorption of neutral hydrocarbons to sediments: Experimental observations and model predictions, Environ. Sci. Technol., 32(7), 892-902. https://doi.org/10.1021/es9705809   DOI
10 Kile, D.E., Wershaw, R.L., and Chiou, C.T., 1999, Correlation of soil and sediment organic matter polarity to aqueous sorption of nonionic compounds, Environ. Sci. Technol., 33(12), 2053-2056. https://doi.org/10.1021/es980816o   DOI
11 Li, W., Zhu, N., Yuan, H., and Shen, Y., 2021, Influence of sludge organic matter on elimination of polycyclic aromatic hydrocarbons (PAHs) from waste activated sludge by ozonation: Controversy over aromatic compounds, Sci. Total Environ., 797, 149232. https://doi.org/10.1016/j.scitotenv.2021.149232   DOI
12 Liu, S., Yan, E.Z., Turyk, M.E., Katta, S.S., Rasti, A.F., Lee, J.H., Alajlouni, M., Wallace, T.E., Catt, W., and Aikins, E.A., 2022, A pilot study characterizing tetrachloroethylene exposure with exhaled breath in an impacted community, Environ. Pollut., 297, 118756. https://doi.org/10.1016/j.envpol.2021.118756   DOI
13 Masud M. A. A., and Shin W. S. 2022, Single and binary competitive sorption of phenanthrene and pyrene in natural and syntheic sorbents, J. Soil Groundwater Environ., 27(6), 11-21. https://doi.org/10.7857/JSGE.2022.27.6.011   DOI
14 Masud, M.A. Al, Shin, W.S., and Kim, D.G., 2023, Degradation of phenol by ball-milled activated carbon (ACBM) activated dual oxidant (persulfate/calcium peroxide) system: Effect of preadsorption and sequential injection, Chemosphere, 312, 137120. https://doi.org/10.1016/j.chemosphere.2022.137120   DOI
15 Yin, X., Hua, H., Dyer, J., Landis, R., Fennell, D., and Axe, L., 2023, Degradation of chlorinated solvents with reactive iron minerals in subsurface sediments from redox transition zones, J. Hazard. Mater., 445, 130470. https://doi.org/10.1016/j.jhazmat.2022.130470   DOI
16 Qi, S., 2004, Comment on "Sorption nonlinearity for organic contaminants with diesel soot: Method development and isotherm interpretation", Environ. Sci. Technol., 38(20), 5485. https://doi.org/10.1021/es0404771   DOI
17 Rani, C.N. and Karthikeyan, S., 2021, Synergic effects on degradation of a mixture of polycyclic aromatic hydrocarbons in a UV slurry photocatalytic membrane reactor and its cost estimation, Chem. Eng. Process. - Process Intensif., 159, 108179. https://doi.org/10.1016/j.cep.2020.108179   DOI
18 Xiao, B. and Huang, W., 2011, The equilibria of bisolute sorption on soil, Chemosphere, 83(7), 1005-1013. https://doi.org/10.1016/j.chemosphere.2011.02.009   DOI
19 Masud, M.A. Al, Kim, D.G., and Shin, W.S., 2022, Degradation of phenol using Fe(II)-activated CaO2: effect of ball-milled activated carbon (ACBM) addition, Environ. Res., 214, 113882. https://doi.org/10.1016/j.envres.2022.113882   DOI
20 Dutta, N., Usman, M., Ashraf, M.A., Luo, G., and Zhang, S., 2022, A critical review of recent advances in the bio-remediation of chlorinated substances by microbial dechlorinators, Chem. Eng. J. Adv., 12, 100359. https://doi.org/10.1016/j.ceja.2022.100359   DOI
21 Prajapati, A., Narayan Vaidya, A., and Kumar, A.R., 2022, Microplastic properties and their interaction with hydrophobic organic contaminants: a review, Environ. Sci. Pollut. Res., 29, 49490-49512. https://doi.org/10.1007/s11356-022-20723-y   DOI
22 Akinpelu, A.A., Ali, M.E., Johan, M.R., Saidur, R., Qurban, M.A., and Saleh, T.A., 2019, Polycyclic aromatic hydrocarbons extraction and removal from wastewater by carbon nanotubes: A review of the current technologies, challenges and prospects, Process Saf. Environ. Prot. 122, 68-82. https://doi.org/10.1016/j.psep.2018.11.006   DOI
23 Al-Masud, M.A., Kim, D.G., and Shin, W.S., 2022, Highly efficient degradation of phenolic compounds by Fe(II)-activated dual oxidant (persulfate/calcium peroxide) system, Chemosphere, 299, 134392. https://doi.org/10.1016/j.chemosphere.2022.134392   DOI
24 Brusseau, M.L., Schnaar, G., Johnson, G.R., and Russo, A.E., 2012, Nonideal transport of contaminants in heterogeneous porous media: 10. Impact of co-solutes on sorption by porous media with low organic-carbon contents, Chemosphere, 89, 1302-1306. https://doi.org/10.1016/j.chemosphere.2012.05.027   DOI
25 Kan, A.T., Fu, G., Hunter, M.A., and Tomson, M.B., 1997, Irreversible adsorption of naphthalene and tetrachiorobiphenyl to Lula and surrogate sediments, Environ. Sci. Technol., 31(8), 2176-2185. https://doi.org/10.1021/es9601954   DOI
26 Choi, J. and Shin, W.S., 2020, Removal of salicylic and ibuprofen by hexadecyltrimethylammonium-modified montmorillonite and zeolite, Minerals, 10(10), 898, 1-15. https://doi.org/10.3390/min10100898   DOI
27 Cornelissen, G., Kukulska, Z., Kalaitzidis, S., Christanis, K., and Gustafsson, O., 2004, Relations between environmental black carbon sorption and geochemical sorbent characteristics, Environ. Sci. Technol., 38(13), 3632-3640. https://doi.org/10.1021/es0498742   DOI
28 Feng, C., Liu, F., Huang, F., Chen, L., and Bi, E., 2023a, Dense nonaqueous phase liquids back diffusion controlled by biodegradation and heterogeneous sorption-desorption, J. Clean. Prod., 382, 135370. https://doi.org/10.1016/j.jclepro.2022.135370   DOI
29 Kleineidam, S., Schuth, C., and Grathwohl, P., 2002, Solubility-normalized combined adsorption-partitioning sorption isotherms for organic pollutants, Environ. Sci. Technol., 36(21), 4689-4697. https://doi.org/10.1021/es010293b   DOI
30 Ozcan, A., Oncu, E.M., and Ozcan, A.S., 2006, Kinetics, isotherm and thermodynamic studies of adsorption of Acid Blue 193 from aqueous solutions onto natural sepiolite, Colloids Surfaces A Physicochem. Eng. Asp., 277, 90-97. https://doi.org/10.1016/j.colsurfa.2005.11.017   DOI
31 Ran, Y., Xing, B., Rao, P.S.C., and Fu, J., 2004, Importance of adsorption (hole-filling) mechanism for hydrophobic organic contaminants on an aquifer kerogen isolate, Environ. Sci. Technol., 38(16), 4340-4348. https://doi.org/10.1021/es035168+   DOI
32 Shin, W.S. and Song, D.I., 2005, Solubility-normalized Freundlich isotherm for the prediction of sorption of phenols in HDTMA modified montmorillonite, Geosci. J., 9, 249-259. https://doi.org/10.1007/BF02910585   DOI
33 Sekar, A., Varghese, G.K., and Varma, R., 2022, Exposure to volatile organic compounds and associated health risk among workers in lignite mines, Int. J. Environ. Sci. Technol., https://doi.org/10.1007/s13762-022-04056-4   DOI