• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.4
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• pp.55-64
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• 2014

This work was investigated on pilot injection strategy of blended fuels(Diesel-DME) for combustion and emissions in a single cylinder direct injection compression ignition engine. Diesel and DME were blended by the method of weight ratio. Weight ratios for diesel and DME were 95:05 and 90:10 respectively. dSOI between main and pilot injection timing was varied. A total amount of injected fuels(single injection) was adjusted to obtain the fixed BMEP as 4.2 bar in order to compare with the fuel conditions. Also, the amount of pilot injection fuel was varied by 5%, 10% and 20% of total injection fuel. The engine was equipped with common rail and injection pressure is 700 bar at 1200 rpm. As a result, when mixing ratio increase, indicated thermal efficiency was increased in comparison with DD 100 and CO, THC and smoke were lower than DD 100. The influence of reducing NOx by pilot injection was more effective than DD 100. When pilot injection quantity increase, abrupt increase of NOx was occured at pilot injection quantity of 20%.

• Journal of ILASS-Korea
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• v.22 no.4
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• pp.218-224
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• 2017

In order to improve the quality of air in urban areas, the emission regulations are being strengthened by the government. The on-road test of light-duty vehicles was started with PEMS because certification test mode does not sufficiently reflect on-road conditions. Therefore, The PEMS-based test was implemented from Sep. 2017 in Europe and Korea. However, this is lack of data on various on-road patterns in Korea. The purpose of the present study has analyzed the effect of speed per acceleration and acceleration on NOx emission on-road driving. The test route consisted of urban, rural, and motorway in Seoul. This study has been conducted by Euro-6 vehicles using on SCR system with PEMS. The on-road emission characteristics were evaluated by moving averaging windows (MAW) method. In results, RDE-NOx by severe driving pattern has been 1.4 times higher than soft driving pattern NIER Route 1.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.12
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• pp.965-973
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• 2015

Recently, an emission test procedure using a portable emissions measurement system(PEMS) has received much attention as an effective means of controlling real driving emissions from light-duty diesel vehicles. The PEMS-based test procedure will be implemented from 2017 in Europe and Korea as a complementary test procedure for certification and regulation. In the present study, on-road NOx emissions were measured for four kinds of Euro 5 Korean light-duty diesel vehicles under real driving conditions, including urban, rural, and motorway test routes. The real driving emission characteristics were evaluated using both a moving averaging window(MAW) and the weighted emission method(WEM). The evaluated NOx emission results (under real driving conditions) from the MAW and WEM showed similar tendencies for the test vehicles and routes, while exceeding the certification emission limit by 1.8~8.5 and 2.0~10.6 times, respectively.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.4
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• pp.401-411
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• 2005

This study was conducted to develop a method to be able to estimate the vehicular emissions according to spatial scales-Seoul province, 25 counties and hundreds of grids $(1km{\times}1km)$. First, the emissions at each spatial scale was calculated by using the road network and the travel volume and speed of each link modeled by travel demand model (TDM). Second, the emission at each spatial scale was calculated on the basis of average speeds estimated by using three kinds of averaging method. These are called the provincial, volume-delay function (VDF) and zonal method, respectively. Third, three kinds of emissions and those by TDM are compared each other at three spatial scales. In Seoul (provincial scale), three kinds of emissions are less than those by TDM, but the differences of TDM from three speed averaging methods (SAMs) are small. The relative ratios of three SAMs to TDM are $88\~90\%\;in\;CO,\;99\~100\%\;in\;NOx,\;84\~85\%$ in VOCs. At county scale, NOx among three pollutants showed the highest correlation between TDM and three SAMs and the zonal method among three SAMs was proven to be the highest correlation with TDM. NOx showed the coefficients $(R^2)$ greater than 0.9 in all three SAMs but CO and VOC showed the coefficients $(R^2)$ greater than 0.9 in only zonal method. Slopes of co..elations of all pollutants showed the values close to '1' in zonal method. In the other two SAMs, slopes of NOx showed the values close to '1', but those of CO and VOC showed the values less than 0.85. At grid scale, correlations between TDM and three SAMs were not high. CO showed $0.68\~0.77\;in\;R^2s\;and\;58\~0.68$ in slopes. NOx showed $0.90\~0.94\;in\;R^2s\;and\;0.86\~0.94$ in slopes. VOC showed $0.56\~0.70\;in\;R^2s\;and\;0.48\~0.57$ in slopes. There are not high correlations between TDM and three SAMs in grid scale. This study showed that there is the most suitable method for calculating the average travel speed at each spatial scale and it is thought that the zonal method is more suitable than the VDF or provincial method.

• Korean Journal of Remote Sensing
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• v.39 no.5_1
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• pp.563-576
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• 2023

In this study nitrogen dioxide (NO₂), formaldehyde (HCHO) from the Ozone Monitoring Instrument (OMI) and TROPOspheric Monitoring Instrument (TROPOMI), OMI/ Microwave Limb Sounder (MLS) tropospheric column ozone (TCO), and Airkorea ground-based O₃ data were analyzed to examine the photochemical reaction relationship between tropospheric ozone and its precursors nitrogen oxides (NOx) and volatile organic compounds (VOCs). As a result of analyzing the trend of long-term changes from 2006 to 2020 using OMI satellite data, TCO showed an increasing trend, NO₂ steadily decreased, and HCHO continued to increase in Northeast Asia. In addition, formaldehyde nitrogen dioxide ratio (FNR; HCHO/NO₂ ratio), an indicator of ozone sensitivity, is gradually increasing, which means that the VOC-limited regime is decreasing. This study conducted a sensitivity analysis of ozone generation using TROPOMI FNR and ground-based ozone (O₃) over the recent years (2019~2022) to identify the possible cause for the continuous increase of ozone in Korea. Similar to the previous studies, VOC-limited and transitional regimes appeared in megacities, and VOC-limited regimes also appeared in areas where major power plants were located. In VOC-limited regimes, in other words, areas where NOx is excessively saturated, the reduction in NOx emissions may have weakened the ozone titration and thus led to the increase of ozone. Therefore, VOC emissions should be reduced in the short term rather than NOx emissions to reduce ozone concentrations under the VOC-limited regime.

• Clean Technology
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• v.25 no.4
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• pp.331-335
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• 2019

Interest in environmental pollution is increasing all over the world, and technology development to solve it is actively carried out. In areas where heat is used, especially, combustion is causing countless pollutants in the air environment. Combustion catalyst is a technology that reduces NOx and CO by lowering combustion temperature and enabling complete combustion. Traditional combustion catalysts are expensive and complex in the synthesis process using precious metal catalyst. In this study, hexaaluminate, a high-temperature combustion catalyst, was manufactured using urea, and the properties were investigated according to the synthesis time. The combustion performance and characteristics were evaluated using this catalyst. As the temperature increased, the changing methane conversion rate was shown in two patterns. The conversion rates for 1 hour, 9 hours, and 12 hours were similar, while the conversion rates for 3 hours and 6 hours showed similar patterns. Methane combustion performance increased rapidly as the synthesis time increased from 6 hours to 9 hours, whereas the temperature at T50 was approximately 745 ℃. The performance of the synthesized combustion catalyst for 9 hours was optimum as the NOx emission of this combustion catalyst was not present and the maximum emission of CO was 72 ppm.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.4
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• pp.220-228
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• 2017

Since the fine particulate matters occurred from mainly combustion in industry and road transport effect to human respiratory health, the interest and importance are getting increased. In 2013, the World Health Organization (WHO) concluded that outdoor air pollution is carcinogenic to humans, with the particulate matter component ($PM_{10}$ and $PM_{2.5}$) of air pollution most closely associated with increased cancer incidence, especially cancer of the lung. Therefore, many researches have been studied in the quantification and data development of fine particulate matters. Currently, the Ministry of Environment and cities/regions are developing the fine particulate matter data and air emission information. Particularly just $PM_{10}$ and $PM_{2.5}$ data is used in the fine particulate matters warning and alert. The data of NOx, SOx, $NH_3$, which have the particulate matter formation potential are not well considered. Also, the researches related with particulate matter formation potential and respiratory effects by industrial sectors and cities/regions are not conducted well. Therefore, the purpose of this study is to evaluate and calculate particulate matter formation potential and respiratory effects in 11 industrial sectors and cities using NOx, SOx, $PM_{10}$, $NH_3$ data (developed by Ministry of Environment and National Institute of Environmental Research) in 2001 and 2013. The results of this study will be provided the particulate matter formation potential and respiratory effects and will be used for future the fine particulate matter researches.

• Journal of Korea Port Economic Association
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• v.37 no.1
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• pp.143-157
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• 2021

International organizations such as the World Health Organization, the Organization for Economic Development and Cooperation, and major developed countries recognize the seriousness of air pollution. International organizations such as the International Maritime Organization have also implemented various regulations to reduce air pollution from ships. In line with this international trend, the government has also enacted a special law on improving air quality in port areas, and is making efforts to reduce air pollution caused by ports. The purpose of the Special Act is to implement comprehensive policies to improve air quality in port areas. This study sought to identify the emissions of each source of air pollutants originating from the port and prepare basic data on setting the policy priorities. To this end, the analysis was conducted in six categories: ships, vehicles, loading and unloading equipment, railways, unloading/wild ash dust, road ash dust, and the methodology presented by the European Environment Agency(EEA) and the United States Environmental Protection Agency(EPA). The pollutants subject to analysis were analyzed for carbon monoxide(CO), nitrogen oxides (NOX), sulfur oxides(SOX), total airborne materials(TSP), particulate matter(PM10, PM2.5), and ammonia(NH3). The analysis showed a total of 7,122 tons of emissions. By substance, NOX accounted for the largest portion of 5,084 tons, followed by CO (984 tons), SOX (530 tons), and TSP (335 tons). By source of emissions, ships accounted for the largest portion with 4,107 tons, followed by vehicles with 2,622 tons, showing high emissions. This proved to be the main cause of port air pollution, with 57.6% and 36.8% of total emissions, respectively, suggesting the need for countermeasures against these sources.

• Journal of the Korean Applied Science and Technology
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• v.35 no.4
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• pp.1421-1432
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• 2018

Water soluble oil was obtained from the pyrolysis of coconut waste as a biomass at $600^{\circ}C$. It was studied that the combustion characteristics of bio-emulsion fuel by mixing and emulsifying 15~20% of water soluble oil which obtained from pyrolysis of coconut waste as a biomass and MDO(marine diesel oil) as a marine fuel. Engine dynamometer was used for detecting emissions, temperature, and power. The temperature of combustion chamber was decreased because the moisture in bio-emulsion fuel deprived of heat of evaporation in combustion chamber. While combustion, micro-explosion took place in the combustion chamber by water in the bio-emulsion fuel, MDO fuel scattered to micro particles and it caused to smoke reduction. The temperature reduction of combustion chamber by using bio-emulsion fuel reduced the NOx emission. The increasing of bio-oil content caused increasing water content in bio-emulsion fuel so total calorific value was reduced. So the characteristics of power was decreased in proportion to using the increasing amount of bio-emulsion fuel. Heavy oil as a marine fuel exhausts a lot of smoke and NOx. We expect that we can reduce the exhaust gas of marine engine such as smoke and NOx by using of bio-emulsion fuel as a marine fuel.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.4
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• pp.626-631
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• 2019

The policy-making and technological development for the supply expansion of eco-friendly automobiles has been continuing, but the internal combustion engines still accounts for about 95%. Also, in order to meet the stricter emission regulations of internal combustion engines based on fossil fuels, the proportion of after-treatments for vehicles and (ocean going) vessels is gradually increasing. This study is a basic study for the post-Euro-VI exhaust response of CNG buses, and it is to investigate the basic characteristics according to Pd substitution transition metal effect, catalyst volume effect and space velocity. A catalysts was prepared and tested using a model gas reactor. The NGOC catalyst with 3Pd exhibited the highest catalytic activity with 22% at $300^{\circ}C$, 48% at $350^{\circ}C$ and about 75% at $500^{\circ}C$. 3Co NGOC containing 3wt% of transition metal was excellent in oxidation ability, and it was small in size of 2nm, and the degree of catalyst dispersion was improved and de-NO/CO conversion was high. The volume of the NGOC-LNT-SCR catalyst system was optimal in the combination of 1.5+0.5+0.5 with a total score of 165, considering $de-CH_4/NOx$ performance and catalyst cost. For SV $14,000h^{-1}$, the $CH_4$ reduction performance was the highest at about 20%, while the SV $56,000h^{-1}$ was the lowest at about 5%. If the space velocity is small, the flow velocity decreases and the time remaining in the catalyst volume become long, so that the harmful gas was reduced.