• Title/Summary/Keyword: Nitrogen Oxide

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Improvement of Emission Performances of a HSDI Diesel Engine with Partial Premixed Compression Ignition Combustion Method (부분 예혼합 압축착화 연소기법을 적용한 HSDI 디젤엔진의 배기 성능 개선)

  • Chung, Jae-Woo;Kang, Jeong-Ho;Kim, Nam-Ho;Min, Kyoung-Doug;Lee, Ki-Hyung;Lee, Jeong-Hoon;Kim, Hyun-Ok;Kang, Woo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.6
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    • pp.88-96
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    • 2008
  • Currently, due to the serious world-wide air pollution by substances emitted from vehicles, emission control is enforced more firmly and it is expected that the regulation requirements for emission will become more severe. A new concept combustion technology that can reduce the NOx and PM in relation to combustion is urgently required. This study used a split injection method at a 4 cylinder common-rail direct injection diesel engine in order to apply the partially premixed charge compression ignition combustion method without significantly altering engine specifications And it is investigated that the effects of the injection ratio and SCV(swirl control valve) to emission characteristics. From these tests, soot(g) and NOx(g) emission could be reduced to 40% and 92% compared to base engine performance at specified engine driving conditions(6 points with weight factors) according to application of split injection and SCV(swirl control valve).

A study on Property of Emission Gas by the Content Variation of Urea (UREA의 함량 변화에 따른 배출가스 특성분석)

  • Kang, Hyungkyu;Doe, Jinwoo;Hwang, Inha;Im, Jaeheuk;Ha, Jonghan;Na, Byungki
    • Journal of Energy Engineering
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    • v.24 no.4
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    • pp.24-32
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    • 2015
  • National and international regulations on the exhaust gases of diesel engines are being strengthened, and a study of the combutsion engine and the post-porcessing system are in progress as a variety of ways. There are many techniques for the removal of nitrogen oxide like HC-SCR, LNT, Urea-SCR. And the technical development on the Urea-SCR owing to high conversion efficiency and fuel economy characteristics has being processed. This study investigated the physical/chemical properties of urea according to the change of the urea content, and were analysed the characteristic of exhaust gas. According to the increase of urea content, the contests of biuret aldehyde, phosphate content was increased and the changes of emission quantity of carbon monoxide, hydrocarbons and particulate matter in the exhaust gas was very slight. The emission quantity of NOx was decreased in accordance with increasing the urea content and it was shown to be more than 80 % in the urea solution having more than 30 wt%.

Changes in Blood Parameters and Blood Flow Subsequent to a Short-Term Raw Juice Diet (단기간 생즙섭취에 따른 혈액지표 및 혈류변화)

  • Kim, Sun-Hee;Yim, Jong-Eun;Yun, Mi-Eun
    • Journal of the Korean Dietetic Association
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    • v.26 no.1
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    • pp.14-29
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    • 2020
  • Dietary nitrate supplementation from green leafy vegetables and beetroot is involved in the 'nitrate-nitrite-nitric oxide (NO) pathway' and is reported to have important vascular impacts. This study evaluated the blood parameters and blood flow change subsequent to a raw juice diet program. The 28 subjects who voluntarily participated in the raw juice diet program at Sahmyook University were instructed to drink the juice composed of fruits and vegetables instead of partaking the usual meal, at a scheduled time daily. The study was approved by the research ethics council of the Sahmyook University (SYUIRB 2014-043). Evaluation of the participants after the required duration revealed decreased levels of soft lean mass (P<0.05), skeletal muscle mass (P<0.001), body fat mass (P<0.001), body mass index (P<0.001) and circulating levels of total cholesterol (P<0.001), triglycerides (P<0.05), HDL-cholesterol (P<0.01), LDL-cholesterol (P<0.01), and blood urea nitrogen (P<0.001). Conversely, circulating levels of creatinine (P<0.001), hemoglobin (P<0.001), and hematocrit (P<0.01) were increased after the intervention. The blood flow levels were also increased after the program (P<0.001). Our results indicate that a short-term raw juice diet contributes to the improvement of vascular blood flow and blood lipid parameters, and decreases the lean muscle mass related to dehydration.

A Study of the Reaction Characteristics on Hydrocarbon Selective Catalytic Reduction of NOx Over Various Noble Metal Catalysts (다양한 귀금속 촉매를 이용한 NOx의 탄화수소 선택적촉매환원 반응 특성에 관한 연구)

  • Kim, Sung-Su;Jang, Du-Hun;Hong, Sung-Chang
    • Clean Technology
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    • v.17 no.3
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    • pp.225-230
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    • 2011
  • Characteristics of hydrocarbon selective catalytic reduction of NOx using various noble metal catalysts were investigated. The best active metal is Pt, supports are $CeO_2$ and $TiO_2$ by strong interactions between active metals, and 55% of conversion rate of NOx is shown. Pd, Rh and Ag catalysts presented a conversion of less than 20% as active metals, and supports also showed the poor activity compared to $SiO_2$ and $ZrO_2$. Experiments were performed with different types of reducing agents, amount, concentration of oxygen and space velocity in order to investigate the performance of catalysts according to operating conditions. The results confirm that the methane is better than propane as a reducing agent, and as the ratio of methane/nitrogen oxide increases, the catalytic activity increased, as the concentration of oxygen increases and space velocity decreases, the performance of catalysts increased.

Korean red ginseng extract alleviates advanced glycation end product-mediated renal injury

  • Quan, Hai Yan;Kim, Do Yeon;Chung, Sung Hyun
    • Journal of Ginseng Research
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    • v.37 no.2
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    • pp.187-193
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    • 2013
  • The effect of Korean red ginseng (KRG) on diabetic renal damage was investigated using streptozotocin (STZ)-induced diabetic rats. The diabetic rats showed loss of body weight gain, and increases in kidney weight and urine volume, whereas the oral administration of KRG at a dose of 100 or 250 mg/kg of body weight per day for 28 d prevented these diabetes-induced physiological abnormalities. Among the kidney function parameters, elevated plasma levels of urea nitrogen and creatinine in diabetic control rats tended to be lowered in KRG-treated rats. In addition, administration of KRG at a dose of 100 mg/kg body weight in the diabetic rats showed significant decreases in serum glucose and tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$), implying that KRG might prevent the pathogenesis of diabetic complications caused by impaired glucose metabolism and oxidative stress. KRG also significantly reduced advanced glycation end product (AGE) formation and secretion from kidney of diabetic rats. Furthermore, KRG decreased the levels of N-(carboxymethyl) lysine and expression of AGE receptor. KRG also reduced the overexpression of cyclooxygenase-2 and inducible nitric oxide synthase in the kidney via deactivation of nuclear factor-kappa B. We also found that KRG prevented STZ-induced destruction of glomerular structure and significantly suppressed high glucose-induced fibronectin production. Taken together, KRG ameliorates abnormalities associated with diabetic nephropathy through suppression of inflammatory pathways activated by TNF-${\alpha}$ and AGEs. These findings indicate that KRG has a beneficial effect on pathological conditions associated with diabetic nephropathy.

The Protective Effects of Acupuncture on Oxidative Stress Caused by Cadmium in the Kidney (카드뮴으로 유발된 산화적 스트레스에 대한 침 자극의 신장 보호 효과)

  • Shin, Hwa Young;Lee, Hyun Jong;Kim, Jae Soo
    • Journal of Acupuncture Research
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    • v.32 no.1
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    • pp.1-11
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    • 2015
  • Objectives : This study was performed to inquire into the protective effects of acupuncture on oxidative stress caused by cadmium accumulation in the kidney. Methods : Sprague-Dawley male($150{\pm}30g$) rats were stabilized for 1 week and divided into 5 groups: normal, control, $LR_3$ acupuncture, $BL_{23}$ acupuncture and sham acupuncture. For three days experimental groups received oral doses of cadmium 2 mg/kg twice a day. Acupuncture was applied bilaterally at each point 10 times for two weeks. The depth of stimulation was 1 mm at right angles and torsion of acupuncture was produced 2 times per second for 1 minute. The kidneys were extracted and weighed after two weeks, and renal function was confirmed through blood urea nitrogen(BUN). We measured reactive oxygen species of the serum and kidney, and compared expression levels of superoxide dismutase(SOD), catalase, glutathione peroxidase(Gpx), nuclear factor erythroid derived 2-related factor 2(Nrf-2), heme oxygenase-1(HO-1), nuclear factor-${\kappa}B$(NF-${\kappa}B)$, cyclooxygenase-2(COX-2), inducible nitric oxide synthase (iNOS), Bax and Cytochrome c. Results : The $LR_3$ acupuncture group and $BL_{23}$ acupuncture group experienced significantly increased kidney weight, and decreased BUN compared to control group. In terms of oxidative stress, the $LR_3$ acupuncture group and $BL_{23}$ acupuncture group experienced significantly reduced reactive oxygen species compared to the control group. Conclusions : The $LR_3$ acupuncture group and $BL_{23}$ acupuncture group experienced showed the effects of antioxidant, anti-inflammatory and apoptosis protection. The $BL_{23}$ acupuncture group was more effective than $LR_3$ acupuncture group.

A study of decomposition of sulfur oxides(harmful gas) using calcium dihydroxide catalyst by plasma reactions (Ca(OH)2촉매를 이용한 플라즈마 반응에 의한 황산화물(유해가스)의 제거에 관한 연구)

  • Kim, Dayoung;Hwang, Myungwhan;Woo, Insung
    • Journal of the Korea Safety Management & Science
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    • v.16 no.2
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    • pp.237-246
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    • 2014
  • Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.

Synthesis and Characterization of Molybdeum Complexes with Schiff-Bases(II), Dioxobis(N-aryl-3-methoxysalicyaldiminato) Molybdenum(VI) Complexes (몰리브덴의 시프-염기착물의 합성과 그 성질 (제2보). 다이옥소비스(질소-아릴-3-메톡시살리실알디미나토)몰리브데늄(VI) 착물)

  • O, Sang O;Gu, Bon Gwon
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.257-264
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    • 1985
  • Dioxobis(3-methoxysalicyaldehydato)molybdeum(VI) complex has been synthesized by reactions of 3-methoxysalicylaldehyde and ammonium paramolybdate in methanol solution. With appropriate primary amine, the resulting complex gave schiff-base complexes, MoO$_2$(CH$_3$O-sal-N-R)$_2$ in which C=O oxide ligands had been replaced by nitrogen. The properties and possible molecular structure of these complexes were discussed by elemental analysis, spectroscopic studies and electric conductivities measurements. It was found that the Mo(VI) complexes contain a cis-MoO$_2$ group since their infrared spectra two Mo=O band at about 900cm$^{-1}$ and the combining ratios for MoO$_2$-ligand are 1 : 2. Also, electronic spectra of molybdenyl complexes assigned to ligand-to-metal charge transfer transition. All of these complexes are yellow or orange, depolar compound and slightly soluble in alcohol, dichloromethane, chloroform and N,N-dimethylformamide.

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Analysis of statistical models on temperature at the Seosan city in Korea (충청남도 서산시 기온의 통계적 모형 연구)

  • Lee, Hoonja
    • Journal of the Korean Data and Information Science Society
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    • v.25 no.6
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    • pp.1293-1300
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    • 2014
  • The temperature data influences on various policies of the country. In this article, the autoregressive error (ARE) model has been considered for analyzing the monthly and seasonal temperature data at the northern part of the Chungcheong Namdo, Seosan monitoring site in Korea. In the ARE model, five meteorological variables, four greenhouse gas variables and five pollution variables are used as the explanatory variables for the temperature data set. The five meteorological variables are wind speed, rainfall, radiation, amount of cloud, and relative humidity. The four greenhouse gas variables are carbon dioxide ($CO_2$), methane ($CH_4$), nitrous oxide ($N_2O$), and chlorofluorocarbon ($CFC_{11}$). And the five air pollution explanatory variables are particulate matter ($PM_{10}$), sulfur dioxide ($SO_2$), nitrogen dioxide ($NO_2$), ozone ($O_3$), and carbon monoxide (CO). The result showed that the monthly ARE model explained about 39-63% for describing the temperature. However, the ARE model will be expected better when we add the more explanatory variables in the model.

The Effects of Engine Speed and Load of the Partial Premixed Diesel Compressed Ignition Engine Applied with the Split Injection Method on Exhaust Gas and IMEP Characteristics (2단 분사방식을 적용한 부분 예혼합 디젤 압축착화 연소 엔진의 회전속도 및 부하 변화가 배출 가스 및 IMEP특성에 미치는 영향)

  • Kang, Jeong-Ho;Lee, Sung-Man;Chung, Jae-Woo;Kang, Woo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.1
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    • pp.162-170
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    • 2007
  • Currently, due to the serious world-wide air pollution by substances emitted from vehicles, emission control is enforced more firmly and it is expected that the regulation requirements for emission will become more severe. Anew concept combustion technology that can reduce the NOx and PM in relation to combustion is urgently required. Due to such social requirement, technologically advanced countries are making efforts to develop an environment-friendly vehicle engine at the nation-wide level in order to respond to the reinforced emission control. As a core combustion technology among new combustion technologies for the next generation engine, the homogeneous charge compression ignition (HCCI) is expanding its application range by adopting multiple combustion mode, catalyst, direct fuel injection and partially premixed combustion. This study used a 2-staged injection method in order to apply the HCCI combustion method without significantly altering engine specifications in the aspect of multiple combustion mode and practicality by referring to the results of studies on the HCCI engine. And it is investigated that the effects of the engine rpm and load(or A/F) to emission characteristics.