• 대한기계학회논문집A
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• 제38권4호
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• pp.451-457
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• 2014

최근에는 법공학 분야에 구조해석 및 구조-유동 연성해석을 이용한 다양한 시뮬레이션 기법을 활용하여 안전사고 및 재난사고에 대한 법적 책임문제를 해명하고, 보다 정확한 원인분석을 통해 원인을 규명하고 있는 추세이다. 본 연구에서 다룬 플레이트 거더교 사고는 교각과 교대 사이의 기존 교각에 대하여 확장 교각을 신설하던 중 방호벽 콘크리트 타설이 완료되는 시점에 전도 추락되어 발생되었다. 본 사고는 설계와 다른 시공 작업과 설계 시 고려되지 않은 추가 하중 등으로 인해 확장 교량에 부반력이 발생하여 구조적 불안정을 가져와 붕괴된 사고로 MIDAS 구조 해석을 통해 설계와 실제 시공 시 작업 하중에 대한 구조적 안정성을 비교 평가하여 정확한 공학적 사고의 원인을 규명하고자 한다.

• 분석과학
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• 제11권6호
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• pp.440-447
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• 1998

브롬 치환기를 가지는 여러자리 시프염기인 5-Br-BSDT(bis(5-bromosalicylaldehyde)diethy- lenetriamine), 5-Br-BSTT(bis(5-bromosalicylaldehyde)triethylenetetramine)와 5-Br-BSTP(bis(5-bromosalicylaldehyde)tetraethylenepentamine)를 합성하여 DMSO 용매에서 이들 리간드들과 구리(II), 니켈(II) 및 아연(II) 등의 전이금속과의 안정도 상수값을 폴라로그래피를 이용하여 구하였다. 이때 금속과 리간드는 1 : 1착물을 형성하였고, 안정도 상수값은 금속으로서는 Cu(II)>Ni(II)>Zn(II) 순서로, 리간드로서는 5-Br-BSTP>5-Br-BSTT>5-Br-BSDT 순서로 나타남으로서 주개 원자수의 증가에 의존한다는 사실을 알았다. 엔탈피와 엔트로피는 모두 음의 값을 나타내었는데 흡열반응으로서 금속이온과 리간드가 매우 강하게 결합하고 있음을 알 수 있고 극성을 가지는 금속착물이 생성되어 용매인 DMSO와 아주 강한 상호작용을 함으로써 큰 음의 엔트로피 값을 가진 것으로 생각된다.

• 한국전자파학회논문지
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• 제27권12호
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• pp.1112-1115
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• 2016

위성항법시스템은 민간 및 군수 분야에서 널리 사용되고 있는 유용한 시스템이다. 그러나 지구 상공 2만 km 이상 원거리 송신 신호로 인한 수신 감도 미약으로, 위성항법시스템의 신호는 항재밍 공격에 취약하다. 본 논문에서는 항재밍 소형 GPS 배열안테나 설계를 위한 선행 연구로 전기적으로 초소형인 GPS 안테나 소자를 효율적으로 정합하는 비 포스터 정합회로에 대한 연구를 수행하였다. 전기적으로 소형인 GPS 안테나는 높은 품질계수로 인해 방사 이득이 낮고, 광대역 정합이 어렵다. 이를 해결하기 위해 소형 GPS 안테나용 비 포스터 정합회로(non-Foster matching circuit)를 설계하였다. Linvill의 교차 결합쌍 트랜지스터로 구성된 네거티브 임피던스 변환기 회로를 제작하였으며, 시간 영역에서 안정도 검증을 통해 안정성을 확인하였다. 비 포스터 정합회로를 이용한 소형 GPS 안테나 무반사실 측정결과, 전면방향이득이 17 dB 이상 개선됨을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제11권6호
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• pp.521-527
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• 1990

The binding characteristics and analytical applications of anilinium ion complexes with 18-crown-6 were studied by polarography and NMR. First, the electrochemical reduction of the 10 species of mono and dimethylsubstituted anilinium ion complexes with 18-crown-6 as host in methanol are examined. The addition of 18-crown-6 to anilinium guest solution the polarographic waves remain well defined but shifted toward more negative potentials, indicating the complex formation. The values of formation constants, log Κ for 10 species of methylsubstituted anilinium ion complexes with 18-crown-6 varies from 2.7 to 4.8 in methanol at $25^{\circ}C$. The stability order of complexes for 18-crown-6 is anilinilum > 4-methyl > 3,4-dimethyl > 3-methyl > 3,5-dimethyl > 2,4-dimethyl > 2,5-dimethyl > 2,3-dimethyl > 2-methyl > 2,6-dimethylanilinium ion. The steric hindrance shows significant effect. Second, Proton NMR was used to elucidate their interaction characteristics. From the results of so called NMR titration techniques, the behaviors of binding sites on complexation, and the stoichiometry and stability order of complex were obtained. And the later results show the satisfactory agreement with the quantitative values obtained by polarography. Finally, the individual determinations of anilinium ion mixtures were also accomplished by addition of 18-crown-6. In some mixtures of methyl or dimethylanilinium ions the reduction peaks of differential pulse method appeared into one unresolved wave attributed to the small difference of half-wave potential, ${\Delta}E_{1/2}$. In the presence of 18-crown-6, the polarographic waves were resolved into individual maxima because of the shift toward more negative direction by the difference of selectivity of anilinium ions with 18-crown-6. It may be concluded that quantitative analysis of methylanilinium ion mixture make possible because the half-wave potential shift by the selectivity difference due to the steric hindrance between methyl group and 18-crown-6 on complexation.

• 한국콘텐츠학회논문지
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• 제21권3호
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• pp.653-663
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• 2021

본 연구는 중년여성을 대상으로 양가적 성차별주의와 포커싱적 태도가 자기개념에 미치는 영향을 살펴보았다. 자기개념 척도, 포커싱적 태도 척도, 양가적 성차별주의 척도를 사용하여 만35세이상 만55세이하 중년여성을 대상으로 온라인 커뮤니티를 통해 실시하였다. SPSS 21.0을 사용하여 분석한 결과 적대적 성차별주의와 온정적 성차별주의와 유의한 정적 상관이 있으며 양가적 성차별주의가 자기개념에 유의한 부적영향을 나타났다. 양가적 성차별주의의 적대적 성차별주의가 높을수록 중년여성의 자기개념의 모든 요인이 낮아지는 경향을 보였으며 포커싱적 태도는 자기개념에 유의한 정적영향이 나타났으나 하위요인별로 달랐다. 포커싱적 태도의 표현하기와 받아들이기, 여유갖기가 자기개념에 유의한 정적영향을, 알아차리기는 부적영향이 있는 것으로 나타났으며, 되새겨보기는 유의한 영향이 나타나지 않았다. 마지막으로 본 연구의 한계점에 대해 논의하였다.

• 아동학회지
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• 제34권6호
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• pp.97-122
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• 2013

The aim of this study was to develop and validate measures of a mother's reaction to children's negative emotions. After construct factors of a mother's reaction to children's negative emotions based on the theoretical basis and existing scales were explored, the first preliminary items were extracted. After the content validity was confirmed by expert opinions, the second preliminary items were composed, and the initial survey was carried out. Using exploratory factor analysis, three principal factors and 21 items were revealed to be most suitable. The factors of the scale consist of emotion-coaching-reactions, oversensitive reactions, and emotion-minimizing-reactions, respectively. In addition, the reliability analysis and validation analysis of the scale was conducted, by means of surveying 413 elementary students. The internal coherence reliability and test-retest reliability were verified as was the general internal coherence and timing stability of the scale. There were three additional verifications to validate the scale. (1)For the evidence based on internal structure, the confirmatory factor analysis and convergent-discriminant evidence; this resulted in confirming the factor structure of the scale as being reliable. (2)In order to understand the relationships to other variables, the correlation analysis came in effect to the overall scale and each of its sub-factors, showing that they are significantly correlated with the scale of the child's perception on rearing attitudes of the mother. (3)As for evidence based on the consequences of the test, the correlation analysis produced a result showed that sub-factors of the scale have as significant correlation with the child's emotional intelligence and resilience.

• Transactions on Electrical and Electronic Materials
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• 제17권6호
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• pp.341-350
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• 2016

The current study is dedicated to design a novel coordinated controller to effectively increase power system rotor angle stability. In doing so, the coordinated design of an AVR (automatic voltage regulator), PSS2B, and TCSC (thyristor controlled series capacitor)-based POD (power oscillation damping) controller is proposed. Although the recently employed coordination between a CPSS (conventional power system stabilizer) and a TCSC-based POD controller has been shown to improve power system damping characteristics, neglecting the negative impact of existing high-gain AVR on the damping torque by considering its parameters as given values, may reduce the effectiveness of a CPSS-POD controller. Thus, using a technologically viable stabilizer such as PSS2B rather than the CPSS in a coordinated scheme with an AVR and POD controller can constitute a well-established design with a structure that as a high potential to significantly improve the rotor angle stability. The design procedure is formulated as an optimization problem in which the ITSE (integral of time multiplied squared error) performance index as an objective function is minimized by employing an IPSO (improved particle swarm optimization) algorithm to tune adjustable parameters. The robustness of the coordinated designs is guaranteed by concurrently considering some operating conditions in the optimization process. To evaluate the performance of the proposed controllers, eigenvalue analysis and time domain simulations were performed for different operating points and perturbations simulated on 2A4M (two-area four-machine) power systems in MATLAB/Simulink. The results reveal that surpassing improvement in damping of oscillations is achieved in comparison with the CPSS-TCSC coordination.

• 한국전기전자재료학회논문지
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• 제33권1호
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• pp.6-9
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• 2020

Thin film transistors (TFTs) with large-area, high mobility, and high reliability are important factors for next-generation displays. In particular, thin transistors based on IGZO oxide semiconductors are being actively researched for this application. In this study, several methods for improving the reliability of a-IGZO TFTs by applying various materials on a passivation layer are investigated. In the literature, inorganic SiO₂, TiO₂, Al₂O₃, ZTSO, and organic CYTOP have been used for passivation. In the case of Al₂O₃, excellent stability is exhibited compared to the non-passivation TFT under the conditions of negative bias illumination stress (NBIS) for 3 wavelengths (R, G, B). When CYTOP passivation, SiO₂ passivation, and non-passivation devices were compared under the same positive bias temperature stress (PBTS), the Vth shifts were 2.8 V, 3.3 V, and 4.5 V, respectively. The Vth shifts of TiO₂ passivation and non-passivation devices under the same NBTS were -2.2 V and -3.8 V, respectively. It is expected that the presented results will form the basis for further research to improve the reliability of a-IGZO TFT.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.41.2-41.2
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• 2011

Recently, scaling down of ULSI (Ultra Large Scale Integration) circuit of CMOS (Complementary Metal Oxide Semiconductor) based electronic devices become much faster speed and smaller size than ever before. However, very narrow interconnect line width causes some drawbacks. For example, deposition of conformal and thin barrier is not easy moreover metallization process needs deposition of diffusion barrier and glue layer. Therefore, there is not enough space for copper filling process. In order to overcome these negative effects, simple process of copper metallization is required. In this research, Cu-V thin alloy film was formed by using RF magnetron sputter deposition system. Cu-V alloy film was deposited on the plane $SiO_2$/Si bi-layer substrate with smooth and uniform surface. Cu-V film thickness was about 50 nm. Cu-V layer was deposited at RT, 100, 150, 200, and $250^{\circ}C$. XRD, AFM, Hall measurement system, and XPS were used to analyze Cu-V thin film. For the barrier formation, Cu-V film was annealed at 200, 300, 400, 500, and $600^{\circ}C$ (1 hour). As a result, V-based thin interlayer between Cu-V film and $SiO_2$ dielectric layer was formed by itself with annealing. Thin interlayer was confirmed by TEM (Transmission Electron Microscope) analysis. Barrier thermal stability was tested with I-V (for measuring leakage current) and XRD analysis after 300, 400, 500, 600, and $700^{\circ}C$ (12 hour) annealing. With this research, over $500^{\circ}C$ annealed barrier has large leakage current. However V-based diffusion barrier annealed at $400^{\circ}C$ has good thermal stability. Thus, thermal stability of vanadium-based thin interlayer as diffusion barrier is good for copper interconnection.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2005년도 ICCAS
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• pp.700-705
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• 2005

The purpose of this project is the derivation and development of techniques for the new estimation of robustness for the systems having uncertainties. The basic ideas to analyze the system which is the originally nonlinear is Lyapunov direct theorems. The nonlinear systems have various forms of terms inside the system equations and this investigation is confined in the form of bounded uncertainties. Bounded means the uncertainties are with same positive/negative range. The number of uncertainties will be the degree of freedoms in the calculation of the stability region. This is so called the robustness bounds. This proposition adopts the theoretical analysis of the Lyapunov direct methods, that is, the sign properties of the Lyapunov function derivative integrated along finite intervals of time, in place of the original method of the sign properties of the time derivative of the Lyapunov function itself. This is the new sufficient criteria to relax the stability condition and is used to generate techniques for the robust design of control systems with structured perturbations. Using this relaxing stability conditions, the selection of Lyapunov candidate function is of various forms. In this paper, the quadratic form is selected. this generated techniques has been demonstrated by recent research interest in the area of robust control design and confirms that estimation of robustness bounds will be improved upon those obtained by results of the original Lyapunov method. In this paper, the symbolic algebraic procedures are utilized and the calculating errors are reduced in the numerical procedures. The application of numerical procedures can prove the improvements in estimations of robustness for one-and more structured perturbations. The applicable systems is assumed to be linear with time-varying with nonlinear bounded perturbations. This new techniques will be extended to other nonlinear systems with various forms of uncertainties, especially in the nonlinear case of the unstructured perturbations and also with various control method.