• Title/Summary/Keyword: Nanoparticle Fabrication

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Polyvalent Nanoparticle-oligonudleotide conjugates: Synthesis, Properties, and Biodiagnostic/Therapeutic Applications

  • Lee, Jae-Seung
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.7.2-7.2
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    • 2009
  • Polyvalent nanoparticle-DNA conjugates exhibit a variety of unique features such as programmable assembly and disassembly, sharp melting transitons, intense optical properties, high stability, enhanced binding properties, and easy fabrication of the surface nature by chemical and physical modification. The unique properties of nanoparticle-DNA conjugates enable one to build up a number of versatile assay schemes for the detection of various targets. In addition, nanoparticle-RNA conjugates also demonstrate great promise of therapeutic applications in the context of RNA interference when combined with polymeric materials. In this presentation, representative examples of each aspect of nanoparticle-oligonucleotide conjugates will be discussed.

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Atomic Force Microscopy (AFM) Tip based Nanoelectrode with Hydrogel Electrolyte and Application to Single-Nanoparticle Electrochemistry

  • Kyungsoon Park;Thanh Duc Dinh;Seongpil Hwang
    • Journal of Electrochemical Science and Technology
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    • v.15 no.2
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    • pp.261-267
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    • 2024
  • An unconventional fabrication technique of nanoelectrode was developed using atomic force microscopy (AFM) and hydrogel. Until now, the precise control of electroactive area down to a few nm2 has always been an obstacle, which limits the wide application of nanoelectrodes. Here, the nanometer-sized contact between the boron-doped diamond (BDD) as conductive AFM tip and the agarose hydrogel as solid electrolyte was well governed by the feedback amplitude of oscillation in the non-contact mode of AFM. Consequently, this low-cost and feasible approach gives rise to new possibilities for the fabrication of nanoelectrodes. The electroactive area controlled by the set point of AFM was investigated by cyclic voltammetry (CV) of the ferrocenmethanol (FcMeOH) combined with quasi-solid agarose hydrogel as an electrolyte. Single copper (Cu) nanoparticle was deposited at the apex of the AFM tip using this platform whose electrocatalytic activity for nitrate reduction was then investigated by CV and Field Emission-Scanning Electron Microscopy (FE-SEM), respectively.

Thermal Assisted UV-Ozone Treatment to Improve Reliability of Ag Nanoparticle Thin Films

  • Lee, Inhwa;Kim, Taek-Soo
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.1
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    • pp.41-44
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    • 2014
  • We employed UV-Ozone treatment method for the fabrication of dense and highly conductive nanoparticle thin films. We demonstrated the UV-Ozone treatment effect on the silver nanoparticle thin films as a function of time and temperature. The capping layers of nanoparticles were decomposed after UV-Ozone treatment and dense nanoparticle thin films were obtained. Moreover, electrical and mechanical properties of the thin films after UV-Ozone treatment were measured by using resistance measurements under tension in an in-situ tensile tester. The initial resistance of nanoparticle thin films was decreased by 82.6% with optimized UV-Ozone treatment condition of $150^{\circ}C$ for 20 minutes.

A p-n Heterojunction Diode Constructed with A p-Si Nanowire and An n-ZnO Nanoparticle Thin-Film by Dielectrophoresis (Dielectrophoresis 방법으로 제작한 Si 나노선과 ZnO 나노입자 필름 기반 p-n 이종접합 다이오드)

  • Kim, Kwang-Eun;Lee, Myeong-Won;Yun, Jung-Gwon;Kim, Sang-Sig
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.1
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    • pp.105-108
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    • 2011
  • Newly-developed fabrication of a p-n heterojunction diode constructed with a p-Si nanowire (NW) and an n-ZnO nanoparticle (NP) thin-film by the dielectrophoresis (DEP) technique is demonstrated in this study. With the bias of 20 Vp-p at the input frequency of 1 MHz, the most efficient assembly of the n-ZnO NPs is shown for the fabrication of the p-n heterojunction diode with a p-Si NW. The p-n heterojunction diode fabricated in this study represents current rectifying characteristics with the turn on voltage of 1.1 V. The diode can be applied to the fabrication of optoelectrical devices such as photodetectors, light-emitting diodes (LEDs), or solar cells based on the high conductivity of the NW and the high surface to volume ratio of the NP thin film.

Study on Formation of Semitransparent Cu Nanoparticle Layers for Realizing Metal Nanoparticle-Dielectric Bilayer Structures (금속나노입자-유전체 이층 구조 구현을 위한 반투명 Cu 나노입자층 형성에 관한 연구)

  • Yoon, Hye Ryeon;Jo, Yoon Ee;Yoon, Hoi Jin;Lee, Seung-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.6
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    • pp.460-464
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    • 2020
  • This study reports the fabrication and application of semitransparent Cu nanoparticle layers. Spin coating and subsequent drying of a Cu colloid solution were performed to deposit Cu nanoparticle layers onto Si and glass substrates. As the spin speed of the spin coating increases, the density of the nanoparticles on the substrate decreases, and the agglomeration of nanoparticles is suppressed. This microstructural variation affects the optical properties of the nanoparticle layers. The transmittance and reflectance of the Cu nanoparticle layers increase with increasing spin speed, which results from the trade-off between the exposed substrate area and surface coverage of the Cu nanoparticles. Since the glass substrates coated with Cu nanoparticle layers are semitransparent and colored, it is anticipated that the application of a Cu nanoparticle-dielectric bilayer structure to transparent solar cells will improve the cell efficiency as well as aesthetic appearance.

Uniform PMMA-CH3NH3PbBr3 Nanoparticle Composite Film for Optoelectronic Application

  • Kirakosyan, Artavazd;Yun, Seokjin;Choi, Jihoon
    • Korean Journal of Materials Research
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    • v.27 no.6
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    • pp.307-311
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    • 2017
  • Organometal halide perovskite materials, due to the tunability of their electronic and optical properties by control of composition and structure, have taken a position of significant importance in optoelectronic applications such as photovoltaic and lighting devices. Despite numerous studies on the structure - property relationship, however, practical application of these materials in electronic and optical devices is still limited by their processability during fabrication. Achieving nano-sized perovskite particles embedded in a polymer matrix with high loading density and outstanding photoluminescence performance is challenging. Here, we demonstrate that the careful control of nanoparticle formation and growth in the presence of poly(methyl methacrylate) results in perovskite nanoparticle - polymer nanocomposites with very good dispersion and photoluminescence. Furthermore, this approach is found to prevent further growth of perovskite nanoparticles, and thus results in a more uniform film, which enables fabrication using the perovskite nanoparticles.

Fabrication of Hydrogen Sensors Using Graphenes Decorated Nanoparticles and Their Characteristics (나노입자가 코팅된 그래핀 기반 수소센서의 제작과 그 특성)

  • Kim, Kang-San;Chung, Gwiy-Sang
    • Journal of Sensor Science and Technology
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    • v.21 no.6
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    • pp.425-428
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    • 2012
  • This paper presents the fabrication and characterization of graphene based hydrogen sensors. Graphene was synthesized by annealing process of Ni/3C-SiC thin films. Graphene was transferred onto oxidized Si substrates for fabrication of chemiresistive type hydrogen sensors. Au electrode on the graphene shows ohmic contact and the resistance is changed with hydrogen concentration. Nanoparticle catalysts of Pd and Pt were decorated. Response factor and response (recovery) time of hydrogen sensors based on the graphene are improved with catalysts. The response factors of pure graphene, Pt and Pd doped graphenes are 0.28, 0.6 and 1.26, respectively, at 50 ppm hydrogen concentration.

Fabrication of Hemoglobin/Silver Nanoparticle Heterolayer for Electrochemical Signal-enhanced Bioelectronic Application

  • Lee, Taek;Yoon, Jinho;Choi, Jeong-Woo
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.556-560
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    • 2017
  • A hemoglobin/silver nanoparticle heterolayer was fabricated for bioelectronic device with electrochemical signal-enhancement effect. As a device element, a hemoglobin, the metalloprotein, contained the heme group that showed the redox property was introduced for charge storage element. For electron transfer facilitation, a silver nanoparticle was introduced for electrochemical signal facilitation, the hemoglobin was immobilized onto Au substrate using chemical linker 6-mercaptohexanoic acid (6-MHA). Then, the silver nanoparticle was immobilized onto fabricated hemoglobin/6-MHA heterolayers by layer-by-layer (LbL) method. The surface morphology and surface roughness of fabricated heterolayer were investigated by atomic force microscopy (AFM). The redox property of hemoglobin/silver nanoparticle heterolayer was investigated by a cyclic voltammetry (CV) experiment for obtaining an oxidation potential and reduction potential. Moreover, for the assessing charge storage function, a chronoamperometry (CA) experiment was conducted to hemoglobin/silver nanoparticle-modified heterolayer electrode using oxidation and reduction potentials, respectively. Based on the results, the fabricated hemoglobin/silver nanoparticle heterolayer showed that an increased charge storage effect compared to hemoglobin monolayer-modified electrode.