• Title/Summary/Keyword: Nano-domain boundary

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Observation of Nano-scale Domain Boundary in $LiTaO_3$ Single Crystals ($LiTaO_3$ 단결정의 도메인 바운더리 관찰)

  • Jeong, Dae-Yong;Kim, Jin-Sang;Park, Young-Wook;Yoon, Seok-Jin;Cho, Yasuo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.327-327
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    • 2007
  • $LiTaO_3$ single crystal has been studied for surface acoustic wave(SAW) applications. There are two kinds of $LiTaO_3$ single crystals, stoichiometric $LiTaO_3$ (SLT) and congruent $LiTaO_3$ (CLT). These two crystals show quite different dielectrical properties, which might be related with defects in crystals. In this study, we observed the domain boundary of SLT and CLT with scanning nonlinear dielectric microscopy and discussed the stress distribution in $LiTaO_3$ single crystals.

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Ferroelectric domain inversion in $LiNbO_3$ crystal plate during heat treatment for Ti in-diffusion ($Ti:LiNbO_3$ 도파로 제작을 위한 열처리 과정 동안 강유전 도메인 특성에 미치는 영향)

  • Yang, W.S.;Lee, H.Y.;Kwon, S.W.;Kim, W.K.;Lee, H.Y.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.3
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    • pp.124-127
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    • 2005
  • It is demonstrated that the annealing process for Ti in-diffusion to z-cut $LiNbO_3$ at temperature lower than the curie temperature in a platinum (Pt) box can cause a ferroelectric micro-domain inversion at the +z surface and Li out-diffusion, therefore which should be avoided or suppressed for waveguide type periodically poled lithium niobate (PPLN) devices. The depth of the inversion layer depends on the Ti-diffusion conditions such as temperature, atmosphere, the sealing method of $LiNbO_3$ in the Pt box and crystal orientation is experimentally examined. The result shows that the polarization-inverted domain boundary appears at the only +z surface and its thickness is about $1.6{\mu}m$. Also, for the etched $LiNbO_3$, surface the domain shape was observed by the optical microscope and atomic force microscopy (AEM), and distribution of the cation concentrations in the $LiNbO_3$ crystal by the secondary ion mass spectrometry (SIMS).

Forced vibrations of an elastic rectangular plate supported by a unilateral two-parameter foundation via the Chebyshev polynomials expansion

  • Zekai Celep;Zeki Ozcan
    • Structural Engineering and Mechanics
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    • v.90 no.6
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    • pp.551-568
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    • 2024
  • The present study deals with static and dynamic behaviors including forced vibrations of an elastic rectangular nano plate on the two-parameter foundation. Firstly, the rectangular plate is assumed to be subjected to uniformly distributed and eccentrically applied concentrated loads. The governing equations of the problem are derived by considering the dynamic response of the plate, employing a series of the Chebyshev polynomials for the displacement function and applying the Galerkin method. Then, effects of the non-essential boundary conditions of the plate, i.e., the boundary conditions related to the shearing forces, the bending moments and the corner forces, are included in the governing equation of motion to compensate for the non-satisfied boundary conditions and increase the accuracy of the Galerkin method. The approximate numerical solution is accomplished using an iterative process due to the non-linearity of the unilateral property of the two-parameter foundation. The plate under static concentrated load is investigated in detail numerically by considering a wide range of parameters of the plate and the foundation stiffnesses. Numerical treatment of the problem in the time domain is carried out by assuming a stepwise variation of the concentrated load and the linear acceleration procedure is employed in the solution of the system of governing differential equations derived from the equation of motion. Time variations of the contact region and those of the displacements of the plate are presented in the figures for various numbers of the two-parameter of the foundation, as well as the classical and nano parameters of the plate particularly focusing on the non-linearity of the problem due to the plate lift-off from the unilateral foundation. The effects of classical and nonlocal parameters and loading are investigated in detail. Definition of the separation between the plate and the two-parameter foundation is presented and applied to the given problem. The effect of the lift-off on the static and dynamic behavior of the rectangular plate is studied in detail by considering various loading conditions. The numerical study shows that the effect of nonlocal parameters on the behavior of the plate becomes significant, when nonlinearity becomes more profound, due to the lift-off of the plate. It is seen that the size effects are significant in static and dynamic analysis of nano-scaled rectangular plates and need to be included in the mechanical analyses. Furthermore, the corner displacement of the plate is affected more significantly from the lift-off, whereas it is less marked in the time variation of the middle displacement of the plate. Several numerical examples are presented to examine the sensibility of various parameters associated with nonlocal parameters of the plate and foundation. Both stiffening and softening nonlocal parameters behavior of the plate are identified in the numerical solutions which show that increasing the foundation stiffness decreases the extent of the contact region, whereas the stiffness of the shear layer increases the contact region and reduces the foundation settlement considerably.

High-k ZrO2 Enhanced Localized Surface Plasmon Resonance for Application to Thin Film Silicon Solar Cells

  • Li, Hua-Min;Zang, Gang;Yang, Cheng;Lim, Yeong-Dae;Shen, Tian-Zi;Yoo, Won-Jong;Park, Young-Jun;Lim, Jong-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.276-276
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    • 2010
  • Localized surface plasmon resonance (LSPR) has been explored recently as a promising approach to increase energy conversion efficiency in photovoltaic devices, particularly for thin film hydrogenated amorphous silicon (a-Si:H) solar cells. The LSPR is frequently excited via an electromagnetic (EM) radiation in proximate metallic nanostructures and its primary con sequences are selective photon extinction and local EM enhancement which gives rise to improved photogeneration of electron-hole (e-h) pairs, and consequently increases photocurrent. In this work, high-dielectric-constant (k) $ZrO_2$ (refractive index n=2.22, dielectric constant $\varepsilon=4.93$ at the wavelength of 550 nm) is proposed as spacing layer to enhance the LSPR for application to the thin film silicon solar cells. Compared to excitation of the LSPR using $SiO_2$ (n=1.46, $\varepsilon=2.13$ at the wavelength of 546.1 nm) spacing layer with Au nanoparticles of the radius of 45nm, that using $ZrO_2$ dielectric shows the advantages of(i) ~2.5 times greater polarizability, (ii) ~3.5 times larger scattering cross-section and ~1.5 times larger absorption cross-section, (iii) 4.5% higher transmission coefficient of the same thickness and (iv) 7.8% greater transmitted electric filed intensity at the same depth. All those results are calculated by Mie theory and Fresnel equations, and simulated by finite-difference time-domain (FDTD) calculations with proper boundary conditions. Red-shifting of the LSPR wavelength using high-k $ZrO_2$ dielectric is also observed according to location of the peak and this is consistent with the other's report. Finally, our experimental results show that variation of short-circuit current density ($J_{sc}$) of the LSPR enhanced a-Si:H solar cell by using the $ZrO_2$ spacing layer is 45.4% higher than that using the $SiO_2$ spacing layer, supporting our calculation and theory.

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Exact solution for dynamic response of size dependent torsional vibration of CNT subjected to linear and harmonic loadings

  • Hosseini, Seyyed A.H.;Khosravi, Farshad
    • Advances in nano research
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    • v.8 no.1
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    • pp.25-36
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    • 2020
  • Rotating systems concern with torsional vibration, and it should be considered in vibration analysis. To do this, the time-dependent torsional vibrations in a single-walled carbon nanotube (SWCNT) under the linear and harmonic external torque, are investigated in this paper. Eringen's nonlocal elasticity theory is considered to demonstrate the nonlocality and constitutive relations. Hamilton's principle is established to derive the governing equation of motion and consequently related boundary conditions. An analytical method, called the Galerkin method, is utilized to discretize the driven differential equations. Linear and harmonic torsional loads, along with determined amplitude, are applied to the SWCNT as the external torques. SWCNT is considered under the clamped-clamped end supports. In free vibration, analysis of small scale effect reveals the capability of natural frequencies in different modes, and this results desirably are in coincidence with another study. The forced torsional vibration in the time domain, especially for carbon nanotubes, has not been done before in the previous works. The previous forced studies were devoted to the transverse vibrations. It should be emphasized that the dynamical analysis of torsion is novel, workable, and at the beginning of the path. The variations of nonlocal parameter, CNT's thickness, and the influence of excitation frequency on time-dependent angular displacement and nondimensional angular displacement are investigated in the context.

Ordered Micropatterns by Confined Dewetting of an Imprinted Polymer Thin Film and Their Microlens Application

  • Lee, Geun-Tak;Yoon, Bo-Kyung;Acharya, Himadri;Park, Cheol-Min;Huh, June
    • Macromolecular Research
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    • v.17 no.3
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    • pp.181-186
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    • 2009
  • We fabricated ordered micro/nano patterns induced by controlled dewetting on the topographically patterned PS/P4VP bilayer thin film. The method is based on utilizing microimprinting lithography to induce a topographically heterogeneous bilayer film that allows the controlled dewetting upon subsequent thermal annealing. The dewetting that was initiated strictly at the boundary of the thicker and thinner regions was guided by the presence of the topographic structure. The dewetting front velocity of the microdomains in the confined regions was linearly proportional to the measurement time, which enabled us to control the size of the dewet domain with annealing time. In particular, the submicron sized dot arrays between lines were generated with ease when the dewetting was confined into geometry with a few microns in size. The kinetically driven, non-lithographical pattern structures accompanied the pattern reduction to 400%. The pattern arrays on a transparent glass substrate were especially useful for non-circular microlens arrays where the focal length of the lens was easily tunable by controlling the thermal annealing.

Propagating and evanescent waves in a functionally graded nanoplate based on nonlocal theory

  • Cancan Liu;Jiangong Yu;Bo Zhang;Xiaoming Zhang;Xianhui Wang
    • Advances in nano research
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    • v.14 no.5
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    • pp.463-474
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    • 2023
  • The purpose of this paper is to present the analysis of propagating and evanescent waves in functionally graded (FG) nanoplates with the consideration of nonlocal effect. The analytical integration nonlocal stress expansion Legendre polynomial method is proposed to obtain complete dispersion curves in the complex domain. Unlike the traditional Legendre polynomial method that expanded the displacement, the presented polynomial method avoids employing the relationship between local stress and nonlocal stress to construct boundary conditions. In addition, the analytical expressions of numerical integrations are presented to improve the computational efficiency. The nonlocal effect, inhomogeneity of medium and their interactions on wave propagation are studied. It is found that the nonlocal effect and inhomogeneity of medium reduce the frequency bandwidth of complex evanescent Lamb waves, and make complex evanescent Lamb waves have a higher phase velocity at low attenuation. The occurrence of intersections of propagating Lamb wave in the nonlocal homogeneous plate needs to satisfy a smaller Poisson's ratio condition than that in the classical elastic theory. In addition, the inhomogeneity of medium enhances the nonlocal effect. The conclusions obtained can be applied to the design and dynamic response evaluation of composite nanostructures.

A Stress-Based Gradient Elasticity in the Smoothed Finite Element Framework (평활화 유한요소법을 도입한 응력기반 구배 탄성론)

  • Changkye Lee;Sundararajan Natarajan
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.37 no.3
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    • pp.187-195
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    • 2024
  • This paper presents two-dimensional boundary value problems of the stress-based gradient elasticity within the smoothed finite element method (S-FEM) framework. Gradient elasticity is introduced to address the limitations of classical elasticity, particularly its struggle to capture size-dependent mechanical behavior at the micro/nano scale. The Ru-Aifantis theorem is employed to overcome the challenges of high-order differential equations in gradient elasticity. This theorem effectively splits the original equation into two solvable second-order differential equations, enabling its incorporation into the S-FEM framework. The present method utilizes a staggered scheme to solve the boundary value problems. This approach efficiently separates the calculation of the local displacement field (obtained over each smoothing domain) from the non-local stress field (computed element-wise). A series of numerical tests are conducted to investigate the influence of the internal length scale, a key parameter in gradient elasticity. The results demonstrate the effectiveness of the proposed approach in smoothing stress concentrations typically observed at crack tips and dislocation lines.