• Title/Summary/Keyword: Nano-composite Material

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The nano scale bending and dynamic properties of isolated protein microtubules based on modified strain gradient theory

  • Benmansour, Djazia Leila;Kaci, Abdelhakim;Bousahla, Abdelmoumen Anis;Heireche, Houari;Tounsi, Abdelouahed;Alwabli, Afaf S.;Alhebshi, Alawiah M.;Al-ghmady, Khalid;Mahmoud, S.R.
    • Advances in nano research
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    • v.7 no.6
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    • pp.443-457
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    • 2019
  • In this investigation, dynamic and bending behaviors of isolated protein microtubules are analyzed. Microtubules (MTs) can be considered as bio-composite structures that are elements of the cytoskeleton in eukaryotic cells and posses considerable roles in cellular activities. They have higher mechanical characteristics such as superior flexibility and stiffness. In the modeling purpose of microtubules according to a hollow beam element, a novel single variable sinusoidal beam model is proposed with the conjunction of modified strain gradient theory. The advantage of this model is found in its new displacement field involving only one unknown as the Euler-Bernoulli beam theory, which is even less than the Timoshenko beam theory. The equations of motion are constructed by considering Hamilton's principle. The obtained results are validated by comparing them with those given based on higher shear deformation beam theory containing a higher number of variables. A parametric investigation is established to examine the impacts of shear deformation, length scale coefficient, aspect ratio and shear modulus ratio on dynamic and bending behaviors of microtubules. It is remarked that when length scale coefficients are almost identical of the outer diameter of MTs, microstructure-dependent behavior becomes more important.

Wear evaluation of CAD-CAM dental ceramic materials by chewing simulation

  • Turker, Izim;Kursoglu, Pinar
    • The Journal of Advanced Prosthodontics
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    • v.13 no.5
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    • pp.281-291
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    • 2021
  • PURPOSE. To evaluate the wear of computer-aided design/computer-aided manufacturing (CAD-CAM) dental ceramic materials opposed by enamel as a function of increased chewing forces. MATERIALS AND METHODS. The enamel cusps of healthy human third molar teeth (n = 40) opposed by materials from CAD-CAM dental ceramic groups (n = 10), including Vita Enamic® (ENA), a polymer-infiltrated ceramic network (PICN); GC Cerasmart® (CERA), a resin nanoceramic; Celtra® Duo (DUO), a zirconia-reinforced lithium silicate (ZLS) ceramic; and IPS e.max ZirCAD (ZIR), a polycrystalline zirconia, were exposed to chewing simulation (1,200,000 cycles; 120 N load; 1 Hz frequency; 0.7 mm lateral and 2 mm vertical motion). The wear of both enamel cusps and materials was quantified using a 3D laser scanner, and the wear mechanisms were evaluated by scanning electron microscopy (SEM). The results were analysed using Welch ANOVA and Kruskal Wallis test (α = .05). RESULTS. ZIR showed lower volume loss (0.02 ± 0.01 mm3) than ENA, CERA and DUO (P = .001, P = .018 and P = .005, respectively). The wear of cusp/DUO [0.59 mm3 (0.50-1.63 mm3)] was higher than cusp/CERA [0.17 mm3 (0.04-0.41 mm3)] (P = .007). ZIR showed completely different wear mechanism in SEM. CONCLUSION. Composite structured materials such as PICN and ZLS ceramic exhibit more abrasive effect on opposing enamel due to their loss against wear, compared to uniform structured zirconia. The resin nano-ceramic causes the lowest enamel wear thanks to its flexible nano-ceramic microstructure. While zirconia appears to be an enamel-friendly material in wear volume loss, it can cause microstructural defects of enamel.

Construction of Strontium Titanate/Binary Metal Sulfide Heterojunction Photocatalysts for Enhanced Visible-Light-Driven Photocatalytic Activity

  • Yu, Yongwei;Yang, Qing;Ma, Jiangquan;Sun, Wenliang;Yin, Chong;Li, Xiazhang;Guo, Jun;Jiang, Qingyan;Lu, Zhiyuan
    • Nano
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    • v.13 no.11
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    • pp.1850130.1-1850130.12
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    • 2018
  • A novel strontium titanate/binary metal sulfide ($SrTiO_3/SnCoS_4$) heterostructure was synthesized by a simple two-step hydrothermal method. The visible-light-driven photocatalytic performance of $SrTiO_3/SnCoS_4$ composites was evaluated in the degradation of methyl orange (MO) under visible light irradiation. The photocatalytic performance of $SrTiO_3/SnCoS_4-5%$ is much higher than that of pure $SrTiO_3$, $SnCoS_4$, $SrTiO_3/SnS_2$ and $SrTiO_3/CoS_2$. The $SrTiO_3/SnCoS_4$ composite material with 5 wt.% of $SnCoS_4$ showed the highest photocatalytic efficiency for MO degradation, and the degradation rate could reach 95% after 140 min irradiation time. The enhanced photocatalytic activity was ascribed to not only the improvement of visible light absorption efficiency, but also the construction of a heterostructure which make it possible to effectively separate photoexcited electrons and holes in the two-phase interface.

Bending analysis of nano-SiO2 reinforced concrete slabs resting on elastic foundation

  • Mohammed, Chatbi;Baghdad, Krour;Mohamed A., Benatta;Zouaoui R., Harrat;Sofiane, Amziane;Mohamed Bachir, Bouiadjra
    • Structural Engineering and Mechanics
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    • v.84 no.5
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    • pp.685-697
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    • 2022
  • Nanotechnology has become one of the interesting technique used in material science and engineering. However, it is low used in civil engineering structures. The purpose of the present study is to investigate the static behavior of concrete plates reinforced with silica-nanoparticles. Due to agglomeration effect of silica-nanoparticles in concrete, Voigt's model is used for obtaining the equivalent nano-composite properties. Furthermore, the plate is simulated mathematically with higher order shear deformation theory. For a large use of this study, the concrete plate is assumed resting on a Pasternak elastic foundation, including a shear layer, and Winkler spring interconnected with a Kerr foundation. Using the principle of virtual work, the equilibrium equations are derived and by the mean of Hamilton's principle the energy equations are obtained. Finally, based on Navier's technique, closed-form solutions of simply supported plates have been obtained. Numerical results are presented considering the effect of different parameters such as volume percent of SiO2 nanoparticles, mechanical loads, geometrical parameters, soil medium, on the static behavior of the plate. The most findings of this work indicate that the use of an optimum amount of SiO2 nanoparticles on concretes increases better mechanical behavior. In addition, the elastic foundation has a significant impact on the bending of concrete slabs.

X-ray/gamma radiation shielding properties of Aluminium-Bariume-Zinc Oxide nanoparticles synthesized via low temperature solution combustion method

  • K.V. Sathish;K.N. Sridhar;L. Seenappa;H.C. Manjunatha;Y.S. Vidya;B. Chinnappa Reddy;S. Manjunatha;A.N. Santhosh;R. Munirathnam;Alfred Cecil Raj;P.S. Damodara Gupta;B.M. Sankarshan
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1519-1526
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    • 2023
  • For the first time Aluminium-BariumeZinc oxide nanocomposite (ZABONC) was synthesized by solution combustion method where calcination was carried out at low temperatures (600℃) to study the electromagnetic (EM) (X/γ) radiation shielding properties. Further for characterization purpose standard techniques like PXRD, SEM, UV-VISIBLE, FTIR were used to find phase purity, functional groups, surface morphology, and to do structural analysis and energy band gap determination. The PXRD pattern shows (hkl) planes corresponding to spinel cubic phase of ZnAl2O4, cubic Ba(NO3)2, α and γ phase of Al2O3 which clearly confirms the formation of complex nano composite. From SEM histogram mean size of nano particles was calculated and is in the order of 17 nm. Wood and Tauc's relation direct energy band gap calculation gives energy gap of 2.9 eV. In addition, EM (X/γ) shielding properties were measured and compared with the theoretical ones using standard procedures (NaI (Tl) detector and multi channel analyzer MCA). For energy above 356 keV the measured shielding parameters agree well with the theory, while below this value slight deviation is observed, due to the influence of atomic/crystallite size of the ZABONC. Hence synthesized ZABONC can be used as a shielding material in EM (X/γ) radiation shielding.

Multiscale Virtual Testing Machines of Concrete and Other Composite Materials: A Review (콘크리트 및 복합재료용 멀티스케일 가상 시험기계에 관한 소고)

  • Haile, Bezawit F.;Park, S.M.;Yang, B.J.;Lee, H.K.
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.31 no.4
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    • pp.173-181
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    • 2018
  • Recently composite materials have dominated most engineering fields, owing to their better performance, increased durability and flexibility to be customized and designed for a specific required property. This has given them unprecedented superiority over conventional materials. With the help of the ever increasing computational capabilities of computers, researchers have been trying to develop accurate material models for the complex and integrated properties of these composites. This has led to advances in virtual testing of composite materials as a supplement or a possible replacement of laboratory experiments to predict the properties and responses of composite materials and structures. This paper presents a review on the complex multi-scale modelling framework of the virtual testing machines, which involve computational mechanics at various length-scales starting with nano-mechanics and ending in structure level computational mechanics, with a homogenization technique used to link the different length scales. In addition, the paper presents the features of some of the biggest integrated virtual testing machines developed for study of concrete, including a multiscale modeling scheme for the simulation of the constitutive properties of nanocomposites. Finally, the current challenges and future development potentials for virtual test machines are discussed.

High Coulombic Efficiency Negative Electrode(SiO-Graphite) for Lithium Ion Secondary Battery (리튬이온이차전지용 고효율 음극(SiO-Graphite))

  • Shin, Hye-Min;Doh, Chil-Hoon;Kim, Dong-Hun;Kim, Hyo-Seok;Ha, Kyung-Hwa;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Kim, Ki-Won;Oh, Dae-Hui
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.47-50
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    • 2008
  • A new anode composition material comprising of SiO and Graphite has been prepared by adopting High energy ball milling (HEBM) technique. The anode material shows high initial charge and discharge capacity values of 1139 and 568 mAh/g, respectively. The electrode sustains reversible discharge capacity value of 719 mAh/g at 30th cycle with a high coulombic efficiency${\sim}99%$. Since the materials formed during initial charge process the nano silicon/$Li_4SiO_3$ and $Li_2O$ remains as interdependent, it may be expected that the composite exhibiting higher amount of irreversibility$(Li_2O)$ will deliver higher reversible capacity. In this study, constant current-constant voltage (CC-CV) charge method was employed in place of usual constant current (CC) method in order to convert efficiently all the SiO particles which resulted high initial discharge capacity at the first cycle. We improved considerably the initial discharge specific capacity of SiO/G composite by pretreatment(CC-CV).

Investigation of Interfacial Adhesion of Different Shapes of Nano Carbon Fillers Reinforced Glass Fiber/Epoxy Composites by Spray Coating (형상이 다른 나노입자 스프레이 코팅에 따른 탄소계 강화 유리섬유와 에폭시 수지간 계면강도 관찰)

  • Kwon, Dong-Jun;Wang, Zuo-Jia;Choi, Jin-Young;Shin, Pyeong-Su;Lee, En-Seon;Park, Joung-Man
    • Composites Research
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    • v.27 no.3
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    • pp.109-114
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    • 2014
  • Manufacture of nancomposites has simple process for developing nanocomposites due to the increasing applications using nanofillers. This work studied nanofiller coated glass fiber for reinforcing material with good wetting and conductivity and the morphology of nanofiller coated glass fiber was analyzed by FE-SEM. The durability of reinforced glass fiber was investigated with different shapes of nanofillers using sonication rinsing method. Fatigue test was performed to evaluate the adhesion of reinforcing interface and stability of nanofiller coating layer for single fiber reinforced composites. Apparent modulus and conductivity of nanofiller coating layer were evaluated to realize multifunctional of nanocomposites. Fiber type of nanofiller was better than plate type due to better cohesion between fiber and nanofillers. At last, the stability of fiber type nanofiller of coating layer has better durability and conductivity than plate type case.

A Study on the Applicability of CNT/Aluminum Nanocomposites to Automotive Parts (CNT강화 알루미늄 나노복합재의 자동차용 부품 적용성 연구)

  • Min, Byung Ho;Nam, Dong Hoon;Park, Hoon Mo;Lee, Kyung Moon;Lee, Jong Kook
    • Composites Research
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    • v.28 no.4
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    • pp.226-231
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    • 2015
  • Various characteristics(thermal expansion, microstructure, etc.) and mechanical properties of CNT-aluminum nano composites manufactured by volume production system were evaluated. Also, formability and durability were evaluated for potential applications in automotive parts, via compared with high-elasticity material (A390) and the current commercial product. As a result, this composite has excellent mechanical properties and formability, therefore, to verity its potential for application as light and high strength materials in automobile part.

Development of Hybrid Metals Coated Carbon Fibers for High-Efficient Electromagnetic Interference Shielding (고효율 전자파 차폐를 위한 이종금속 코팅 탄소섬유 개발)

  • Moon, Jai Joung;Park, Ok-Kyung;Lee, Joong Hee
    • Composites Research
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    • v.33 no.4
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    • pp.191-197
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    • 2020
  • In this study, a hybrid metals such as copper (Cu) and nickel (Ni) coated carbon fibers (Ni-Cu/CFs) was prepared by wet laid method to develop a randomly oriented sheet material for high-efficiency electromagnetic interference shielding with the enhanced durability. The prepared sheet materials show a high electromagnetic interference shielding efficiency of 69.4 to 93.0 dB. In addition, the hybrid metals coated Ni-Cu/CFs sheets showed very high durability with harsh chemical/thermal environments due to the effective corrosive and mechanical resistances of Ni surface. In this context, the Ni-Cu/CF sheet possesses longer service life than the Cu/CF sheet, that is, 1.7 times longer.