• Title/Summary/Keyword: Nano Scale

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Influence of Cooling Rate and Alloy Composition on The Microstructural Evolution of Al-Ag Eutectic System ($Al-Ag_2Al$ 공정계 합금의 조성 및 냉각 속도에 따른 미세조직 고찰)

  • Sohn, Sung-Woo;Park, Jin-Man;Kim, Tae-Eung;Lim, Ka-Ram;Kim, Won-Tae;Kim, Do-Hyang
    • Journal of Korea Foundry Society
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    • v.29 no.2
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    • pp.64-69
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    • 2009
  • In the present study the effect of cooling rate during solidification on the microstructural characteristics of Al-xAg (x = 31, 33, 35 at.%) in-situ binary eutectic composites has been investigated. To provide a wide range of cooling rate three different casting techniques, i.e. conventional casting, injection casting, and melt spinning have been used. The observed microstructure is very much dependent on the cooling rate. The fcc ${\alpha}$-Al and hcp $Ag_2Al$ phases exhibits an orientation of (111)Al//(0001)$Ag_2Al$, [1-10]Al//[11- 20]$Ag_2Al$. The microstructure of the melt-spun samples contains Widmanstatten structure resulting from solid-state transformation and nano scale two-phase structure resulting from solid-state phase separation. The microstructure of injection-cast samples contains eutectic structure and solid state phase-separated structure. On the other hand, conventional-cast samples exhibit a microstructure consisted of plate-type eutectic structure.

Genotoxicity of Aluminum Oxide ($Al_2O_3$) Nanoparticle in Mammalian Cell Lines

  • Kim, Youn-Jung;Choi, Han-Saem;Song, Mi-Kyung;Youk, Da-Young;Kim, Ji-Hee;Ryu, Jae-Chun
    • Molecular & Cellular Toxicology
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    • v.5 no.2
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    • pp.172-178
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    • 2009
  • Nanoparticles are small-scale substances (<100 nm) with unique properties, complex exposure and health risk implications. Aluminum oxide ($Al_2O_3$) nanoparticles (NP) have been widely used as abrasives, wear-resistant coatings on propeller shafts of ships, to increase the specific impulse per weight of composite propellants used in solid rocket fuel and as drug delivery systems to increase solubility. However, recent studies have shown that nano-sized aluminum (10 nm in diameter) can generate adverse effects, such as pulmonary response. The cytotoxicity and genotoxicity of $Al_2O_3$ NP were investigated using the dye exclusion assay, the comet assay, and the mouse lymphoma thymidine kinase (tk$^{+/-}$) gene mutation assay (MLA). IC$_{20}$ values of $Al_2O_3$ NP in BEAS-2B cells were determined the concentration of 273.44 $\mu$g/mL and 390.63 $\mu$g/mL with and without S-9. However IC$_{20}$ values of $Al_2O_3$ NP were found nontoxic in L5178Y cells both of with and without S-9 fraction. In the comet assay, L5178Y cells and BEAS-2B cells were treated with $Al_2O_3$ NP which significantly increased 2-fold tail moment with and without S-9. Also, the mutant frequencies in the $Al_2O_3$ NP treated L5178Y cells were increased compared to the vehicle controls with S-9. The results of this study indicate that $Al_2O_3$ NP can cause primary DNA damage and cytotoxicity but not mutagenicity in cultured mammalian cells.

Microchips and their Significance in Isolation of Circulating Tumor Cells and Monitoring of Cancers

  • Sahmani, Mehdi;Vatanmakanian, Mousa;Goudarzi, Mehdi;Mobarra, Naser;Azad, Mehdi
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.3
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    • pp.879-894
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    • 2016
  • In micro-fluid systems, fluids are injected into extremely narrow polymer channels in small amounts such as micro-, nano-, or pico-liter scales. These channels themselves are embedded on tiny chips. Various specialized structures in the chips including pumps, valves, and channels allow the chips to accept different types of fluids to be entered the channel and along with flowing through the channels, exert their effects in the framework of different reactions. The chips are generally crystal, silicon, or elastomer in texture. These highly organized structures are equipped with discharging channels through which products as well as wastes of the reactions are secreted out. A particular advantage regarding the use of fluids in micro-scales over macro-scales lies in the fact that these fluids are much better processed in the chips when they applied as micro-scales. When the laboratory is miniaturized as a microchip and solutions are injected on a micro-scale, this combination makes a specialized construction referred to as "lab-on-chip". Taken together, micro-fluids are among the novel technologies which further than declining the costs; enhancing the test repeatability, sensitivity, accuracy, and speed; are emerged as widespread technology in laboratory diagnosis. They can be utilized for monitoring a wide spectrum of biological disorders including different types of cancers. When these microchips are used for cancer monitoring, circulatory tumor cells play a fundamental role.

Pilot-Scale Simulation of Desalination Process Using Water Integrated Forward Osmosis System (물통합형 정삼투 시스템을 이용한 파일럿 스케일 담수 공정 모사)

  • Kim, Bongchul;Hong, Seungkwan;Choi, Juneseok
    • Journal of Korean Society on Water Environment
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    • v.33 no.4
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    • pp.403-408
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    • 2017
  • In these days, wastewater reclamation and seawater desalination play essential role in addressing the challenge of worldwide water scarcity. Particularly, reverse osmosis (RO) for seawater desalination process is commonly used due to less energy consumption than conventional thermodynamic systems. However, membrane fouling and electrical energy consumption during operation of RO system for seawater desalination haver continued to be a obstruction to its application. In this study, therefore, wastewater secondary effluent is used for osmotic dilution of seawater. Firstly, fouling behaviour of RO by simulating wastewater effluent in osmotic dilution process was measured and we calculated energy consumption of overall desalination process by theoretical equations and commercial program. Our results reveal that RO membrane fouling can be efficiently controlled by pre-treatment systems such as nano filtration (NF) or forward osmosis (FO) process. Especially FO system for osmotic dilution process is a non-pressurized membrane system and, therefore, the operating energy consumption of overall desalination system was the lowest. Moreover, fouling layer on FO membrane is comparatively weak and reversible enough to be disrupted by physical cleaning. Thus, RO system with low salinity feed water through FO process is possible as a less energy consuming desalination system with efficient membrane fouling control.

A Study on the Surface Oxidation Behavior of Cube-textured Nickel Substrate (양축 정렬된 니켈기판의 표면 산화반응 연구)

  • Ahn Ji-hyun;Kim Byeong-Joo;Kim Jae-Geun;Kim Ho-Jin;Hong Gye-Won;Lee Hee-Gyoun;Yoo Jai-Moo;Pradeep Halder
    • Progress in Superconductivity
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    • v.7 no.1
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    • pp.58-63
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    • 2005
  • We investigated the surface oxidation behavior of cube-textured polycrystalline nickel at various oxidation conditions. Cube-textured NiO film was formed on a cube-textured polycrystalline nickel regardless of oxidation conditions but different growth behavior of NiO crystals was observed depending on the oxidation conditions. The introduction of water vapor into $O_2$ did not affect the texture evolution, but rough and porous microstructure was developed. Microstructure of NiO film tends to be denser as the oxygen partial pressure increases. It is interesting that (111) peak of theta - two theta diffraction pattern started to get stronger in air atmosphere and (111) plane became the major texture in the substrate oxidized in high purity argon gas. Small amount of high index crystallographic plane NiO peak crystal was observed when $N_{2}O$ was used as an oxidant while only (200) plane crystal was formed in dry $O_2$ atmosphere. Flat and smooth surface was changed into rough faceted one when ramping rate to oxidation temperature was faster. The grain size of NiO was decreased when the oxygen partial pressure was low. It was also observed that the modification of nickel surface suppressed the development of (200) texture.

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Effects of Excess Yttrium Addition on YBCO Thin Films Prepared by TFA-MOD Process (MOD-TFA 공정에 의한 YBCO박막제조시 과잉 yttrium첨가 효과에 관한 연구)

  • Lee Seung-Yi;Song Seul-A;Kim Byeong-Joo;Park Jin-A;Kim Ho-Jin;Lee Hee-Gyoun;Hong Gye-Won;Jang Seog Heon;Joo Jinho;Yoo Jai-Moo;Pradeep Halder
    • Progress in Superconductivity
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    • v.7 no.1
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    • pp.87-91
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    • 2005
  • [ $YBa_{2}Cu_{3}O_{7-x}$ ] thin films were fabricated on $LaAlO_3$(100) substrate by TFA-MOD process. Yttrium-excess (0, 2.5, 5, 10, 15, 20 $at\%$) coating solution was prepared by adding extra amount of yttrium into a stoichiometric(Y:Ba:Cu=1:2:3) TFA precursor solution. Results are presented concerning the influence of excess yttrium additions on the microstructure development and superconducting properties of $YBa_{2}Cu_{3}O_{7-x}$ film. Large sized CuO particles was observed by SEM EDS investigation. The addition of excess yttrium affected little on $T_c$ of $YBa_{2}Cu_{3}O_{7-x}$ film. $J_c$ of YBCO film was enhanced with excess yttrium addition. Jc maximum of $2.21\;MA/cm^2$ (77 K, self field) appeared with the $15\;at\%$ addition of excess yttrium. With further yttrium addition up to $20\;at\%$, Jc decreased down to $0.9\;MA/cm^2$.

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A Study on The Comparison of The Program Efficiency in The Conventional CHE Injection Method and a novel Hot Electron Injection Method Using A Substrate forward Bias (CHE 주입방법과 기판 순바이어스를 이용한 새로운 고온 전자 주입방법의 프로그램 효율성 비교에 관한 연구)

  • Zhang, Yong-Jie;An, Ho-Myoung;Kim, Hee-Dong;Kim, T.G.
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.1
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    • pp.1-5
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    • 2010
  • In this paper, we directly compare the program efficiency of conventional channel hot electron (CHE) injection methods and a novel hot electron injection methods using substrate forward biases in our silicon-oxide-nitride-oxide-silicon (SONOS) cell. Compared with conventional CHE injection methods, the proposed injection method showed improved program efficiency including faster program operation at lower bias voltages as well as localized trapping features for multi-bit operation with a threshold voltage difference of 1 V at between the forward and reverse read. This program method is expected to be useful and widely applied for future nano-scale multi-bit SONOS memories.

Mechanical analysis of cutout piezoelectric nonlocal nanobeam including surface energy effects

  • Eltaher, Mohamed A.;Omar, Fatema-Alzahraa;Abdalla, Waleed S.;Kabeel, Abdallah M.;Alshorbagy, Amal E.
    • Structural Engineering and Mechanics
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    • v.76 no.1
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    • pp.141-151
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    • 2020
  • This manuscript tends to investigate influences of nanoscale and surface energy on a static bending and free vibration of piezoelectric perforated nanobeam structural element, for the first time. Nonlocal differential elasticity theory of Eringen is manipulated to depict the long-range atoms interactions, by imposing length scale parameter. Surface energy dominated in nanoscale structure, is included in the proposed model by using Gurtin-Murdoch model. The coupling effect between nonlocal elasticity and surface energy is included in the proposed model. Constitutive and governing equations of nonlocal-surface perforated Euler-Bernoulli nanobeam are derived by Hamilton's principle. The distribution of electric potential for the piezoelectric nanobeam model is assumed to vary as a combination of a cosine and linear variation, which satisfies the Maxwell's equation. The proposed model is solved numerically by using the finite-element method (FEM). The present model is validated by comparing the obtained results with previously published works. The detailed parametric study is presented to examine effects of the number of holes, perforation size, nonlocal parameter, surface energy, boundary conditions, and external electric voltage on the electro-mechanical behaviors of piezoelectric perforated nanobeams. It is found that the effect of surface stresses becomes more significant as the thickness decreases in the range of nanometers. The effect of number of holes becomes significant in the region 0.2 ≤ α ≤ 0.8. The current model can be used in design of perforated nano-electro-mechanical systems (PNEMS).

Satisfaction on Fitness and Motion Suitability of Korean male Military Winter Jacket (한국 남자 군인 현 방한복의 치수, 동작적합성 만족도에 관한 연구)

  • Han, Hyunsook;Han, Hyunjung;Cho, Jayoung;Koh, Joonseok
    • Fashion & Textile Research Journal
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    • v.18 no.5
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    • pp.685-694
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    • 2016
  • This study investigates the problems of fitness and motion suitability for Korean male military winter jackets (inner and outer) and provides data for new pattern development. We analyzed fitness and motion suitability by a questionnaire survey with 140 Korean male soldiers and a wearing evaluation with 7 subjects of central army male size. A survey of male soldiers indicated that the fitness and motion suitability satisfaction was over 3.0 (Likert scale) for both inner and outer jackets. There were opinions that the sleeve length was short for the inner jacket and the waist girth and hem girth was slightly large for the outer jacket. In the wearing evaluation results with subjects of central army male size, fitness of total length, sleeve length and collar height showed a score lower than 3.0 for the inner jacket and collar height on the outer jacket. The motion suitability result showed a low score (1.0-2.0) in an arm raising motion for the inner jacket and 2.0-3.0 at neck motion in the outer jacket. In conclusion, there is more dissatisfaction in inner jackets than outer jackets. For the inner jacket, sleeve is short, sleeve hem is narrow, collar height is a little high and the sleeve creeps up during arm motion. The waist girth and hem girth was slightly large and collar height was a little high for the outer jacket.

Growth and characterization of periodically polarity-inverted ZnO structures grown on Cr-compound buffer layers

  • Park, J.S.;Goto, T.;Hong, S.K.;Chang, J.H.;Yoon, E.;Yao, T.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.259-259
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    • 2010
  • Periodically polarity inverted (PPI) ZnO structures on (0001) Al2O3 substrates are demonstrated by plasmas assisted molecular beam epitaxy. The patterning and re-growth methods are used to realize the PPI ZnO by employing the polarity controlling method. For the in-situ polarity controlling of ZnO films, Cr-compound buffer layers are used.[1, 2] The region with the CrN intermediate layer and the region with the Cr2O3 and Al2O3 substrate were used to grow the Zn- and O-polar ZnO films, respectively. The growth behaviors with anisotropic properties of PPI ZnO heterostructures are investigated. The periodical polarity inversion is evaluated by contrast images of piezo-response microscopy. Structural and optical interface properties of PPI ZnO are investigated by the transmission electron microcopy (TEM) and micro photoluminescence ($\mu$-PL). The inversion domain boundaries (IDBs) between the Zn and the O-polar ZnO regions were clearly observed by TEM. Moreover, the investigation of spatially resolved local photoluminescence characteristics of PPI ZnO revealed stronger excitonic emission at the interfacial region with the IDBs compared to the Zn-polar or the O-polar ZnO region. The possible mechanisms will be discussed with the consideration of the atomic configuration, carrier life time, and geometrical effects. The successful realization of PPI structures with nanometer scale period indicates the possibility for the application to the photonic band-gap structures or waveguide fabrication. The details of application and results will be discussed.

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