• Title/Summary/Keyword: Nano 입자

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Surface Tension Change of Simulant Gel Propellant according to the Metal Particle Addition (금속입자 첨가에 따른 모사젤 추진제의 표면장력 변화)

  • Kim, Kyehwan;Kim, Sijin;Han, Seungjoo;Kim, Jinkon;Moon, Heejang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.3
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    • pp.34-40
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    • 2017
  • In this study, the surface tension of simulant gel propellants was measured by Du $No{\ddot{u}}y$ ring method. The variation of the surface tension was investigated with respect to the amount of the gelling agent, and metal particle addition. Distilled water was used as the base fluid for the preparation of the simulant gel propellant where Carbopol 941 was used as a gelling agent and SUS304 spherical metal particles (mean diameter : 100 nm) as simulant energetic particles. As a result of measurements, surface tension increased with increasing gelling agent concentration while, in the presence of metal particle, different behavior of surface tension has been observed.

High-Performance Ionic Polymer-Metal Composite Actuators Based on Nafion/Conducting Nanoparticulate Electrospun Webs (나피온/전도성 나노입자 전기방사 웹을 이용한 고성능 이온성 고분자-금속 복합체 구동기의 제조)

  • Jung, Yo-Han;Lee, Jang-Woo;Yoo, Young-Tai
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.434-439
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    • 2012
  • To improve the performance of ionic polymer-metal composite (IPMC) actuators, Nafion films sandwiched with Nafion/conducting nanoparticulate electrospun webs were used as polymer electrolytes of IPMC. Multiwalled carbon nanotube (MWNT) and silver were the conducting nanoparticulates and the nanoparticles dispersed in a Nafion solution were electrospun. IPMCs with the Nafion/conducting nanoparticulate electrospun webs displayed improved displacements, response rates, and blocking forces. MWNT was superior to silver in terms of displacement and blocking force, and the webs without the conducting fillers also caused enhanced performances compared with the conventional IPMCs. These improvements were attributed to an elevated electrolyte flux through highly porous interlayers and capacitance induced by well dispersed conducting fillers, and low interfacial resistance between electrolyte and electrodes.

Study on Improvement of Thermal Stability of Dendrite-shape Copper Particles by Electroless Silver Plating (Dendrite 형상 구리 입자의 무전해 은 도금에 의한 열적 안정성 향상에 관한 연구)

  • Hwang, In-Seong;Nam, Kwang Hyun;Chung, Dae-won
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.574-580
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    • 2022
  • While in the process of electroless plating of dendrite-shape copper with silver, various silver-coated copper (Ag@Cu) particles were prepared by using both displacement plating and reducing electroless plating. The physicochemical properties of Ag@Cu particles were analyzed by scanning electron microscope- energy-dispersive X-ray spectroscopy (SEM-EDS), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and Brunauer-Emmett-Teller analysis (BET), and it was confirmed that the silver coated by the reducing electroless plating was formed as nano-particles on the copper surface. Ag@Cu particles were compounded with an epoxy resin to prepare a conductive film, and its thermal stability was evaluated. We investigated the effect of the difference between the displacement plating and reducing electroless plating on the initial resistance and thermal stability of conductive films.

Study on the size-based separation of nano to micron particles in natural water and soil using flow and sedimentaion Field-flow fractionation (흐름 및 침강 장-흐름 분획법에 의한 자연수 및 토양 중 나노 크기로부터 마이크론 입자들의 크기별 분리에 관한 연구)

  • Eum, Chul Hun;Kang, Dong Young;Lee, Tae Woo;Lee, Seungho
    • Analytical Science and Technology
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    • v.22 no.1
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    • pp.75-81
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    • 2009
  • A flow and sedimentation field-flow fractionation method has been used to characterize colloidal particles in environmental samples. The opposed flow sample concentration (OFSC) method was employed. The OFSC procedure was optimized for the analysis of particles in ground water with respect to various experimental parameters including sample introduction time, flow rates, etc. The effectiveness in low concentration and characterization of the OFSC-FlFFF was demonstrated with GW-1 and GW-2 ground water samples. Ground water of upto 100 mL has been successfully loaded, concentrated, and characterized by OFSC-FlFFF. The OFSC technique allow the application of FlFFF possible for the separation and characterization of colloidal particles in very low concentrations. The results show FFF provides a simplified alternative to existing off-line concentration procedures, and shows a high potential for the applications to the analysis of dilute colloidal particles in the environmental samples.

Evaluation of MWCNT Exposure and the Wear Characteristics of MWCNT-containing PC/ABS Composites (다중벽 탄소나노튜브를 함유한 PC/ABS 복합재의 마모 특성 및 다중벽 탄소나노튜브의 유출 평가)

  • Lee, Hyun-Woo;Kim, Kyung-Shik;Lee, Jae-Hyeok;Kim, Hyo-Sop;Kim, Jae-Ho;Oh, Dong-Hoon;Ryu, Sang-Hyo;Jang, Young-Chan;Kim, Jae-Hyun;Lee, Hak-Joo;Kim, Kwang-Seop
    • Tribology and Lubricants
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    • v.30 no.5
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    • pp.278-283
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    • 2014
  • Carbon nanotubes (CNTs) are used in various composite materials to enhance electrical, thermal and mechanical properties of composite materials. In this study, we investigate the wear characteristics of polycarbonate/acrylonitrile-butadiene-styrene (PC/ABS) blends containing multi-walled carbon nanotubes (MWCNTs). PC/ABS blends are commonly used in many industrial applications such as cellular phones and display cases and MWCNTs have been added to the PC/ABS blends to improve their electromagnetic interference shielding (EMS). We performed wear tests on PC/ABS blends containing MWCNTs under reciprocating linear sliding conditions with chrome steel balls as a counterpart material. The normal loads were 10, 30, 50, 70, 100 N, the sliding speed was 10 mm/s, the stroke length was 15 mm, and the tests lasted 900 s. The MWCNTs included in the PC/ABS blends lower the wear volume and friction coefficient of the composites. We analyzed the wear debris collected from the composites during the tests in terms of the MWCNT concentration using inductively coupled plasma optical emission spectroscopy. The results show that the quantity of MWCNTs in the debris is proportional to the concentration of MWCNTs in the composite, indicating that the exposure of the MWCNTs to environments by wear could be increased with their concentration in the composite.

Antioxidant Activities and Skin-Whitening Effects of Nano-encapsuled Water Extract from Rubus coreanus Miquel (복분자 추출물의 나노입자화를 통한 항산화 및 미백 효과 증진)

  • Jeong, Hyang-Suk;Han, Jae-Gun;Han, Ji-Hye;Kim, Young;Oh, Sung-Ho;Kim, Seoung-Seop;Jeong, Myoung-Hoon;Choi, Geun-Pyo;Park, Uk-Yeon;Lee, Hyeon-Yong
    • Korean Journal of Medicinal Crop Science
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    • v.17 no.2
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    • pp.83-89
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    • 2009
  • This study was performed to improve antioxidant activities and skin-whitening effects of Rubus coreanus Miquel extracts by nano-encapsulation. R. coreanus was extracted at $60^{\circ}C$ and encapsulated by lecithin and gelagine. Nano-encapsulated extracts showed highest free radical scavengering effect as 97.62% in adding sample ($500\;{\mu}g/m{\ell}$), compared to the extracts from conventional processes. It was showed strong inhibition effect on melanin production test by Clone M-3 cells as 55.23%. High inhibitory potency on tyrosinase was also measured as 155.8% by adding nano-sample of 1 $mg/m{\ell}$. The improvement of biological activity was demonstrated by real time confocal microscope. We could consider that the water soluble extracts of R. coreanus could be definitely enhanced by nano-encapsulated as a potent natural resources for antioxidant and skin-whitening agent.

Synthesis and Swelling Characteristics of Poly(N-isopropylacrylamide) Containing Polydimethylsiloxane and Nano Clay (Nano Clay와 Polydimethylsiloxane을 포함하는 Poly(N-isopropylacrylamide) 공중합체의 합성과 팽윤거동)

  • Nho, Hui-Cheol;Lee, Chan-Woo;Park, Sang-Youn;Yoon, Koo-Sik
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.166-171
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    • 2010
  • Poly(N-isopropylacrylamide)(PNIPAAm) containing polydimethylsiloxane(PDMS) block and nano clay was obtained by the polymerization of NIPAAm and [3-(methacryloylamino)propyl]trimethyl ammonium montmorillonite(MAPTAC-MMT) with PDMS-macroinitiator. The polymer was characterized with FT-IR, XRD and DSC. The addition of PDMS in the polymers did not affect the value of the lower critical solution temperature(LCST) and the glass transition temperature($T_g$) of the PNIPAAm. However, the swelling ratio decreased with increasing PDMS contents. In the case of PNIPAAm containing nano clay, the content of MAPTAC-MMT did not affect swellability, but the $T_g$ of the PNIPAAm decreased with increasing nano clay contents.

A study on the Ni formation by reduction of NiO nano crystals (NiO 나노 결정의 환원 반응에 의한 Ni 형성 거동에 관한 연구)

  • Kim, Chang-Sam;Kang, Seung-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.5
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    • pp.246-250
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    • 2009
  • The Ni formation behavior from the reduction of NiO nano crystals in the $H_2/N_2$ gas mixtures. The NiO nano crystals were synthesized by heat-treating nickel nitrate$(Ni(NO_3)_2\cdot6H_O)$ in the air at $500^{\circ}C$, and had an octahedral shape and the particle size of 200~500 nm. The NiO nano-crystals had well-developed (111) planes which is hardly formed in normal synthetic conditions. The reduction process was carried out at 300 and $600^{\circ}C$ for 15 and 60 minutes, respectively. When the NiO nano-crystals were reduced at $300^{\circ}C$, the Ni particles sustained the same octahedral shape as NiO, while Ni particles were to agglomerate at $600^{\circ}C$.

Effect of Polymers to Nano-emulsion Stability (나노에멀젼 안정성에 대한 폴리머의 영향)

  • Cho, Wan-Goo;Kim, Eun-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.339-347
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    • 2013
  • Nano-emulsions are submicron sized emulsions that are under extensive investigation as drug carriers for improving the delivery of therapeutic agents. The aim of this research is to investigate the stability of nano-emulsions containing polymers. Nano-emulsions containing high concentrations of Carbopol 941, Aristoflex AVC, Aronbis M, Permulen TR 2 and Aculyn 44 were unstable compared with macroemulsions with polymers. The size of emulsion droplet manufactured by adding polymer before emulsification were larger than that of emulsion manufactured by adding polymer after the emulsification. The stability of nano-emulsion containing a low concentration of polymer was also decreased, however the effect was lower than that in the high concentration of polymer. Under similar viscosity of polymer, the sequence of unstability was Aristoflex AVC < Carbopol 941 < Permulen TR2 < Carbopol 941 + Aculyn 44 < Aronbis M.

Enhancement of Immune Activities of Natural Water-Soluble Sulforaphane by Nano Encapsulation Process (천연 수용성 설포라판의 나노입자화를 통한 면역 활성 증진)

  • Ha, Ji-Hye;Han, Jae-Gun;Jeong, Hyang-Suk;Oh, Sung-Ho;Kwon, Min-Chul;Choi, Young-Beom;Ko, Jung-Rim;Lee, Hyeon-Yong
    • Korean Journal of Medicinal Crop Science
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    • v.16 no.6
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    • pp.402-408
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    • 2008
  • This study was performed to investigate improving immune activities of natural water-soluble sulforaphane extracted from Brassica oleracea var. italica by nano encapsulation process. The nanoparticles of the sulforaphane extracted with ultrasonification process at $60^{\circ}C$ promoted human B and T cell growth, about $7{\sim}35%$ compared to the control. The secretion of IL-6 and TNF-${\alpha}$ from T cells were also enhanced as $2.6{\times}10^{-4}pg/cell$ and $2.1{\times}10^{-4} pg/cell$, respectively, by the adding nano samples. NK cell activation was improved about 8%, compare to the control in adding cultured medium of T cell added nano samples. It was also found that sulforaphane extracted from B. oleracea var. italica had highly inhibitory activity on hyaluronidase as $IC_{50}$ about $200\;{\mu}g/m{\ell}$. It can be concluded that natural water-soluble sulforaphane samples by nano-encapsulation, each size is 200 nm, extracted from B. oleracea var. italica has high immune activities through higher efficiency of bio-activation than conventional extracts.