• Title/Summary/Keyword: Multilayer composites

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Automatic Layer-by-layer Dipping System for Functional Thin Film Coatings (다층박막적층법 적용 기능성 박막 코팅을 위한 자동화 시스템)

  • Jang, Wonjun;Kim, Young Seok;Park, Yong Tae
    • Composites Research
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    • v.32 no.6
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    • pp.314-318
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    • 2019
  • A simple and very flexible automatic dipping machine was constructed for producing functional multilayer films on wide substrates via the layer-by-layer (LbL) assembly technique. The proposed machine exhibits several features that allow a fully automated coating operation, such as various depositing recipes, control of the dipping depth and time, operating speed, and rinsing flow, air-assist drying nozzles, and an operation display. The machine uniformly dips a substrate into aqueous mixtures containing complementary (e.g., oppositely charged, capable of hydrogen bonding, or capable of covalent bonding) species. Between the dipping of each species, the sample is spray cleaned with deionized water and blow-dried with air. The dipping, rinsing, and drying areas and times are adjustable by a computer program. Graphene-based thin films up to ten-bilayers were prepared and characterized. This film exhibits the highly filled multilayer structures and low thermal resistance, indicating that the robotic dipping system is simple to produce functional thin film coatings with a variety of different layers.

Light Scattering Amplification on Dye Sensitized Solar Cells Assembled by Hollyhock-shaped CdS-TiO2 Composites

  • Lee, Ga-Young;Lee, Hu-Ryul;Um, Myeong-Heon;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.3043-3047
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    • 2012
  • To investigate the scattering layer effect of a $TiO_2$ multilayer in dye-sensitized solar cells (DSSCs), we designed a new DSSC system, assembled with a CdS-$TiO_2$ scattering layer electrode. A high-magnification SEM image exhibited hollyhock-like particles with a width of 1.5-2.0 ${\mu}m$ that were aggregated into 10-nm clumps in a hexagonal petal shape. The efficiency was higher in the DSSC assembled with a CdS-$TiO_2$ scattering layer than in the DSSC assembled with $TiO_2$-only layers, due to the decreased resistance in electrochemical impedance spectroscopy (EIS). The short-circuit current density ($J_{sc}$) was increased by approximately 7.26% and the open-circuit voltage ($V_{oc}$) by 2.44% over the 1.0 wt % CdS-$TiO_2$ composite scattering layer and the incident photon-to-current conversion efficiency (IPCE) in the maximum peak was also enhanced by about 5.0%, compared to the DSSC assembled without the CdS-$TiO_2$scattering layer.

Impact of composite patch on the J-integral in adhesive layer for repaired aluminum plate

  • Kaci, D. Ait;Madani, K.;Mokhtari, M.;Feaugas, X.;Touzain, S.
    • Advances in aircraft and spacecraft science
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    • v.4 no.6
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    • pp.679-699
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    • 2017
  • The aim of this study is to perform a finite element analysis of the Von Mises stresses distribution in the adhesive layer and of the J-Integral for a damaged plate repaired by a composite patch. Firstly, we study the effect of the fiber orientation, especially the position of the layers that have orientation angle different of $0^{\circ}$ from the first layer which is in all cases of our study oriented at ($0^{\circ}$) on the J-Integral. Secondly, we evaluate the effects of the mechanical properties of the patch and the use of a hybrid patch on the reduction of stresses distribution and J-Integral. The results show clearly that the stacking sequence for the composite patch must be selected to absorb optimally the stresses from the damaged area and to position the various layers of the composite under the first layer whose fibers orientation will remain in all cases equal to $0^{\circ}$. The use of a hybrid composite reduces significantly the J-Integral and the stresses in both damaged plate and the adhesive layer.

Effect of Electrode Diameter on Pine Ceramic Pattern Formed by Using Pin-To-Pin Type Electro-Hydrodynamic Printing (핀-핀 형 전극의 전기-수력학 프린팅에서 전극 직경이 미세 세라믹 패턴 형성에 미치는 영향)

  • Lee Dae-Young;Yu Jae-Hun;Yu Tae-U;Hwang Jungho;Kim Yong-Jun
    • Transactions of the Society of Information Storage Systems
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    • v.1 no.1
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    • pp.108-114
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    • 2005
  • The generation of fine relics of suspensions is a significant interest as it holds the key to the fabrication of electronic devices. These processes offer opportunities for miniaturization of multilayer circuits, for production of functionally graded materials, ordered composites and far small complex-shaped components. Some novel printing methods of depositing ceramic and metal droplets were suggested in recent years. In an electro-hydrodynamic printing, the metallic capillary nozzle can be raised to several kilovolts with respect to the infinite ground plate or pin-type electrode positioned a few millimeters from the nozzle tip. Depending on the electrical and physical properties of the liquid, for a given geometry, it Is possible to generate droplets in any one of three modes, dripping, cone-jet and multi-jet. In this experiment, an alumina suspension flowing through a nozzle was subjected to electro-hydrodynamic printing using pin-type electrodes in the cone-jet mode at different applied voltages. The pin-type electrodes of 1, 100, 1000${\mu}m$ in diameter were used to form fine ceramic patterns onto the substrates. Various feature sizes with applied voltages and electrode diameters were measured. The feature sizes increased with the electrode diameter and applied voltages. The feature size was as fine as $30 {\mu}m$.

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Enhanced $Al_2O_3/Ti$ Interfacial Properties Using $NbC_xC_{1-x}/Y_2O_3$ Interlayers - (1) Sputtering and Thermal Stability ($NbC_xC_{1-x}/Y_2O_3$ 박막코팅을 이용한 $Al_2O_3/Ti$ 계면특성향상 - (1) 스퍼터링 및 열안정성)

  • 문철희
    • Journal of the Korean Ceramic Society
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    • v.34 no.8
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    • pp.908-913
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    • 1997
  • Multilayer NbCxC1-x/Y2O3/Ti were sputter-coated on the alumina substrate, starting with a 0.7 ㎛ thick NbCxC1-x layer grown on substrate, followed by 0.7 ㎛ thick Y2O3 layer and 1 ㎛ thick Ti layer. To find out the optimum conditions for thickness uniformity and adhesion, sputtering works have been done with the variation of sputtering power and Ar pressure. After vacuum annealing at 950℃ and 1000℃, the thermal stability of the NbCxC1-x/Y2O3/Ti coated alumina substrates has been investigated by peel off test. The coating scheme didn't cause any debonded layer after an annealing at 950℃ for 3hrs. However, it was peeled off after annealing at 1000℃ for 3hr. It was found that the thermal stability of Al2O3/NbCxC1-x/Y2O3/Ti coating scheme changed with the NbCxC1-x composition.

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Composite $BaTiO_3$ Embedded capacitors in Multilayer Printed Circuit Board (다층 PCB에서의 $BaTiO_3$ 세라믹 Embedded capacitors)

  • You, Hee-Wook;Park, Yong-Jun;Koh, Jung-Hyuk
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.17 no.2
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    • pp.110-113
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    • 2008
  • Embedded capacitor technology is one of the effective packing technologies for further miniaturization and higher performance of electric packaging system. In this paper, the embedded capacitors were simulated and fabricated in 8-layered printed circuit board employing standard PCB processes. The composites of barium titanante($BaTiO_3$) powder and epoxy resin were employed for the dielectric materials in embedded capacitors. Theoretical considerations regarding the embedded capacitors have been paid to understand the frequency dependent impedance behavior. Frequency dependent impedance of simulated and fabricated embedded capacitors was investigated. Fabricated embedded capacitors have lower self resonance frequency values than that of the simulated embedded capacitors due to the increased parasitic inductance values. Frequency dependent capacitances of fabricated embedded capacitors were well matched with those of simulated embedded capacitors from the 100MHz to 10GHz range. Quality factor of 20 was observed and simulated at 2GHz range in the 10 pF embedded capacitors. Temperature dependent capacitance of fabricated embedded capacitors was presented.

Elastomeric High Barrier Materials for Vehicle (고차단성 자동차 부품용 고무소재)

  • Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.2-9
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    • 2011
  • Permeability to gases and vapors is an important function in tires, rubber tubes and diaphragms. It mainly depends on the rubber material. Generally, permeability increases in the following order: silicone rubber > NR > EPDM > SBR > NBR > FPM > ECO > IIR. And, for an elastomer permeability is also very much dependent on compounding. Many research works are reported in the area of gas permeability for formed rubber,$^{1-7}$ however, few studies are found for unformed elastomer products. Incorporation of nano-particles, use of thermoplastic elastomers and applying high barrier multilayer coatings are the main approaches to obtain a high barrier elastomeric product. In this paper, barrier article for vehicle is introduced.

Application of ultra-high-temperature ceramics to oxidation-resistant and anti-ablation coatings for carbon-carbon composite (탄소-탄소 복합재의 내삭마 내산화 코팅을 위한 초고온 세라믹스의 적용)

  • Kim, Hyun-Mi;Choi, Sung-Churl;Cho, Nam Choon;Lee, Hyung Ik;Choi, Kyoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.283-293
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    • 2019
  • As applications in extreme environments such as aerospace, high-energy plasma and radio-active circumstances increases, the demand for materials that require higher melting points, higher mechanical strength and improved thermal conductivity continues to increase. Accordingly, in order to improve the oxidation/abrasion resistance of the carbon-carbon composite, which is a typical heat-resistant material, a method of using ultra high temperature ceramics was reviewed. The advantages and disadvantages of CVD coating, pack cementation and thermal plasma spraying, the simplest methods for synthesizing ultra-high temperature ceramics, were compared. As a method for applying the CVD coating method to C/C composites with complex shapes, the possibility of using thermodynamic calculation and CFD simulation was proposed. In addition, as a result of comparing the oxidation resistance of the TaC/SiC bi-layer coating and TaC/SiC multilayer coating produced by this method, the more excellent oxidation resistance of the multilayer coating on C/C was confirmed.

Synthesis of Three-Dimensional Graphene Using Porous Nickel Nanostructure (다공성 니켈 나노 구조체를 이용한 3차원 그래핀의 합성)

  • Song, Wooseok;Myung, Sung;Lee, Sun Sook;Lim, Jongsun;An, Ki-Seok
    • Composites Research
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    • v.29 no.4
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    • pp.151-155
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    • 2016
  • Graphene has been a valuable candidate for use as electrodes for supercapacitors. In order to improve the surface area of graphene, three-dimensional graphene was synthesized on porous Ni nanostructure using thermal chemical vapor deposition and microwave plasma chemical vapor deposition. The structural and chemical characterization of synthesized graphene was performed by scanning electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. It was confirmed that three-dimensional and high-crystalline multilayer graphene onto various substrates was synthesized successfully.

A Study on Growth of Graphene/metal Microwires and Their Electrical Properties (금속/그래핀 이중 구조 와이어의 합성 및 전기적 특성 연구)

  • Jeong, Minhee;Kim, Dongyeong;Rho, Hokyun;Shin, Han-Kyun;Lee, Hyo-Jong;Lee, Sang Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.1
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    • pp.67-71
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    • 2021
  • In this study, graphene layer was grown on metal microwire using chemical vapor deposition. The difference of carbon solubility between copper and nickel resulted in the formation of mono-layer and multi-layer graphene were formed on the surfaces of copper and nickel microwires, respectively. During the growth of graphene at high temperature, copper and nickel were recrytallized and the grain size increased. The ampacity of graphene/copper microwire was improved by approximately 27%, 1.91×105 A/㎠, compared to pristine copper microwire. Similar to this behavior, the ampacity of multilayer graphene/nickel microwire was 4.41×104 A/㎠ which is about about 36% improved compared to the pure nickel microwire. The excellent electrical properties of graphene/metal composites are beneficial for supplying the electrical energy to the high-power electronic devices and equipment.