• 제목/요약/키워드: Molecular Property

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초미세분쇄를 이용한 옥수수 변성전분의 물리적 특성 변화 구명 (Investigation of Physical Property Change in Modified Corn Starch by Ultra Fine Pulverization)

  • 한명륜;김애정;장문정;이수정;김희선;김명환
    • 산업식품공학
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    • 제13권4호
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    • pp.335-340
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    • 2009
  • 본 연구는 초미세분쇄기술을 이용하여 옥수수전분의 입자구조파괴가 이루어졌을 때 분자구조적, 물리적 변화가 어떻게 이루어지는지를 구명하고자 하였다. 초미세 분쇄처리 후 옥수수전분의 평균직경은 약 50% 감소가 이루어졌으며 비표면적은 567% 증가하였다. 초미세분쇄처리 전 후의 옥수수전분에 대한 분자량분포를 GPC로 측정한 결과 분쇄 후 저분자량의 Peak II의 면적이 21.0%에서 86.5%로 상승하였다. 손상전분 함량은 각각 9.63%와 83.57%로 초미세분쇄처리에 의하여 크게 증가하였다. 옥수수전분의 경우는 겔(gel)을 형성하였으나 초미세분쇄처리 후에는 전분의 분쇄과정에서 전분입자파괴와 아울러 옥수수전분의 분자량이 저분자화 되면서 겔 형성능력이 크게 저하되었다.

메소-1,2-디아민을 이용한 Salen-코발트 착화합물의 합성과 항암효과 (Synthesis of Salens and Their Cobalt Complexes from Meso-1,2-Diamine and Their Anti-Cancer Property)

  • 고동수
    • Journal of Applied Biological Chemistry
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    • 제53권2호
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    • pp.108-111
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    • 2010
  • New salens (3) and their Cobalt complexes (4) were prepared from meso-1,2-bis(ortho-hydroxyphenyl)-1,2-diaminoethane (1) and substituted salicylic aldehydes (2). In contrast to symmetric structure of salen ligand (3), salen-Co(III) complexes (4) showed dissymmetric molecular structure due to participation of three hydroxyl groups in complex formation. One of the salens (3b) revealed decrease in Cyclin D1 expression, which represents anti-cancer property.

미강유를 이용한 효모균체 단백질의 특성 (Property of Yeast Cell Protein from Rice Bran Oil)

  • 안태영
    • 한국식품영양학회지
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    • 제3권1호
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    • pp.35-38
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    • 1990
  • For the purpose of the production of single cell protein from rice bran oil, yeast was isolating from soil. It was belonging to Candida albicans Species. These experiments were conducted to find out the property on yeast cell from rice bran oil Molecular weight for the main protein on yeast cell protein from rice bran oil separated by 1% SDS polyacrylamide gel electrophorosis was 22, 000.

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셀룰로오즈 트리아세테이트와 폴리에스테르의 분자복합체 (II) -고체성질- (Molecular Composite of Cellulose Triacetate and Polyester (II) -Bulk Property-)

  • Hong, Young Keun
    • 한국염색가공학회지
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    • 제4권1호
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    • pp.26-29
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    • 1992
  • Ternary solutions that cellulose triacetate (CTA) and polyethylene terephthate (PET) were mixed in a solvent trifiuoroacetic acid (TFA)/methylene chloride (MC) (6/4 : v/v) showed phase separation and mesophase formation. The ternary systems which were mesomorphic were spun into a methanol both and relatively strong cellulosic fillaments were successfully produced. Analysis showed that CTA/PET fibers have fibrillar structure and high orientation parallel to the fiber axis. These fibers proved to be molecular composite and have relatively high strength and modulus as spun.

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An approach to Photorefractive Device Fabrication Utilizing Crosslinking Systems

  • Suh, Sang Chul;Shim, Sang Chul;Yoo, Dong Jin
    • Journal of Photoscience
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    • 제10권3호
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    • pp.251-255
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    • 2003
  • The composites fabricated by blending nonlinear optical (NLO) chromophore such as {4-[2-(4-nitrophenyl)-vinyl] phenyl}diphenylamine (NVPDA) with photoconducting crosslinkable matrix, bis-(4-ethynylphenyl)-(4-octyloxy-phenyl)amine (BEOPEA), showed photorefractive property. Many problems faced in typical organic photorefractive systems such as time-consuming chemical synthesis, difficulty in rational design, intrinsic instability and phase separation could be avoided by this fabrication method.

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반도체 소재의 나노미터 스케일의 변형거동 해석 (Deformation pathway of semiconductor materials in nanometer scale)

  • 김동언;오수익
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.518-520
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    • 2007
  • Since all essential property of semiconductor materials are structure-sensitive, the understanding of the deformation mechanism and the deformed structure which can be formed in the nanometer-scale devices is very crucial. To investigate the deformation mechanism and the corresponding structures, nanometer-scale contact loading simulations are carried out using molecular dynamics in silicon and gallium-arsenide.

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SITE-DIRECTED MUTATION STUDY ON HYPERTHERMOSTABILITY OF RUBREDOXIN FROM PYROCOCCUS FURIOSUS USING MOLECULAR DYNAMICS SIMULATIONS IN WATER

  • Jung, Dong-Hyun;Kang, Nam-Sook;Jhon, Mu-Shik
    • 한국생물물리학회:학술대회논문집
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    • 한국생물물리학회 1996년도 정기총회 및 학술발표회
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    • pp.21-21
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    • 1996
  • The hyperthermostable protein, rubredoxin from Pyrococcus furiosus is 53-residue protein with a three-stranded anti-parallel $\beta$-sheet and several loops. To investigate the effect of changes of electrostatic and hydrophobic interactions on the structure and dynamic property of P. furiosus rubredoxin, molecular dynamics simulations in water were performed on three mesophilic rubredoxins, P, furiosus rubresoxin, and 5 mutants of P. furiosus rubredoxin. (omitted)

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Theoretical Study on the [3,3]-Sigmatropic Rearrangement of Allylic Esters by Comparative Molecular Field Analysis (CoMFA)

  • Yoo, Sung-Eun;Cha, OKJa
    • Bulletin of the Korean Chemical Society
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    • 제15권10호
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    • pp.889-890
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    • 1994
  • A comparative molecular field analysis (CoMFA) on the substituent effect of the palladium(Ⅱ) catalyzed [3,3]-sigmatropic rearrangement of allylic esters was studied to show a good correlation between the electrostatic property of substituents and the reaction rate. The CoMFA result suggests that the reaction rate will increase as the electron-donating ability of substituents increases.

CMP 공정에서 연마패드 경도에 따른 연마 특성 변화 분자동력학 연구 (Molecular Dynamics Study on Property Change of CMP Process by Pad Hardness)

  • 권오근;최태호;이준하
    • 반도체디스플레이기술학회지
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    • 제12권1호
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    • pp.61-65
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    • 2013
  • We investigated the wearable dynamics of diamond spherical abrasive during the substrate surface polishing under the pad compression via classical molecular dynamics modeling. We performed three-dimensional molecular dynamics simulations using the Morse potential functions for the copper substrate and the Tersoff potential function for the diamond abrasive. The pad hardness had a big impact on the wearable dynamics of the abrasive. The moving speed of the abrasive decreased with increasing hardness of the pad. As the hardness decreased, the abrasive was indented into the pad and then the sliding motion of the abrasive was increased. So the pad hardness was greatly influenced on the slide-to-roll ratio as well as the wearable rate.