• Title/Summary/Keyword: Molecular Property

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Investigation of Physical Property Change in Modified Corn Starch by Ultra Fine Pulverization (초미세분쇄를 이용한 옥수수 변성전분의 물리적 특성 변화 구명)

  • Han, Myung Ryun;Kim, Ae Jung;Chang, Moon Jeong;Lee, Soo Jeong;Kim, Hee Sun;Kim, Myung Hwan
    • Food Engineering Progress
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    • v.13 no.4
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    • pp.335-340
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    • 2009
  • This study was performed to analyze changes in the molecular structural and physical properties of modified corn starch, in which particle structure was broken using high impact planetary mill and ultra fine pulverizing techniques. The average diameter and specific surface area of the modditied corn starch after pulverization decreased 50% and increased 567%, respectively. Content of low molecular substances mersured using gel permeation chromatography (GPC) increased from 21.0% to 86.5% after pulverizing corn starch. Damaged starch content also increased from 9.63% to 83.57% after pulverizing corn starch. After pulverization, gel formation capacity corn starch was reduced compared to that of control by structure breakdown.

Synthesis of Salens and Their Cobalt Complexes from Meso-1,2-Diamine and Their Anti-Cancer Property (메소-1,2-디아민을 이용한 Salen-코발트 착화합물의 합성과 항암효과)

  • Koh, Dong-Soo
    • Journal of Applied Biological Chemistry
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    • v.53 no.2
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    • pp.108-111
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    • 2010
  • New salens (3) and their Cobalt complexes (4) were prepared from meso-1,2-bis(ortho-hydroxyphenyl)-1,2-diaminoethane (1) and substituted salicylic aldehydes (2). In contrast to symmetric structure of salen ligand (3), salen-Co(III) complexes (4) showed dissymmetric molecular structure due to participation of three hydroxyl groups in complex formation. One of the salens (3b) revealed decrease in Cyclin D1 expression, which represents anti-cancer property.

Property of Yeast Cell Protein from Rice Bran Oil (미강유를 이용한 효모균체 단백질의 특성)

  • 안태영
    • The Korean Journal of Food And Nutrition
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    • v.3 no.1
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    • pp.35-38
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    • 1990
  • For the purpose of the production of single cell protein from rice bran oil, yeast was isolating from soil. It was belonging to Candida albicans Species. These experiments were conducted to find out the property on yeast cell from rice bran oil Molecular weight for the main protein on yeast cell protein from rice bran oil separated by 1% SDS polyacrylamide gel electrophorosis was 22, 000.

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Molecular Composite of Cellulose Triacetate and Polyester (II) -Bulk Property- (셀룰로오즈 트리아세테이트와 폴리에스테르의 분자복합체 (II) -고체성질-)

  • Hong, Young Keun
    • Textile Coloration and Finishing
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    • v.4 no.1
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    • pp.26-29
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    • 1992
  • Ternary solutions that cellulose triacetate (CTA) and polyethylene terephthate (PET) were mixed in a solvent trifiuoroacetic acid (TFA)/methylene chloride (MC) (6/4 : v/v) showed phase separation and mesophase formation. The ternary systems which were mesomorphic were spun into a methanol both and relatively strong cellulosic fillaments were successfully produced. Analysis showed that CTA/PET fibers have fibrillar structure and high orientation parallel to the fiber axis. These fibers proved to be molecular composite and have relatively high strength and modulus as spun.

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An approach to Photorefractive Device Fabrication Utilizing Crosslinking Systems

  • Suh, Sang Chul;Shim, Sang Chul;Yoo, Dong Jin
    • Journal of Photoscience
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    • v.10 no.3
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    • pp.251-255
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    • 2003
  • The composites fabricated by blending nonlinear optical (NLO) chromophore such as {4-[2-(4-nitrophenyl)-vinyl] phenyl}diphenylamine (NVPDA) with photoconducting crosslinkable matrix, bis-(4-ethynylphenyl)-(4-octyloxy-phenyl)amine (BEOPEA), showed photorefractive property. Many problems faced in typical organic photorefractive systems such as time-consuming chemical synthesis, difficulty in rational design, intrinsic instability and phase separation could be avoided by this fabrication method.

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Deformation pathway of semiconductor materials in nanometer scale (반도체 소재의 나노미터 스케일의 변형거동 해석)

  • Kim, Dong-Earn;Oh, Soo-Ik
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.518-520
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    • 2007
  • Since all essential property of semiconductor materials are structure-sensitive, the understanding of the deformation mechanism and the deformed structure which can be formed in the nanometer-scale devices is very crucial. To investigate the deformation mechanism and the corresponding structures, nanometer-scale contact loading simulations are carried out using molecular dynamics in silicon and gallium-arsenide.

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SITE-DIRECTED MUTATION STUDY ON HYPERTHERMOSTABILITY OF RUBREDOXIN FROM PYROCOCCUS FURIOSUS USING MOLECULAR DYNAMICS SIMULATIONS IN WATER

  • Jung, Dong-Hyun;Kang, Nam-Sook;Jhon, Mu-Shik
    • Proceedings of the Korean Biophysical Society Conference
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    • 1996.07a
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    • pp.21-21
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    • 1996
  • The hyperthermostable protein, rubredoxin from Pyrococcus furiosus is 53-residue protein with a three-stranded anti-parallel $\beta$-sheet and several loops. To investigate the effect of changes of electrostatic and hydrophobic interactions on the structure and dynamic property of P. furiosus rubredoxin, molecular dynamics simulations in water were performed on three mesophilic rubredoxins, P, furiosus rubresoxin, and 5 mutants of P. furiosus rubredoxin. (omitted)

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Theoretical Study on the [3,3]-Sigmatropic Rearrangement of Allylic Esters by Comparative Molecular Field Analysis (CoMFA)

  • Yoo, Sung-Eun;Cha, OKJa
    • Bulletin of the Korean Chemical Society
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    • v.15 no.10
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    • pp.889-890
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    • 1994
  • A comparative molecular field analysis (CoMFA) on the substituent effect of the palladium(Ⅱ) catalyzed [3,3]-sigmatropic rearrangement of allylic esters was studied to show a good correlation between the electrostatic property of substituents and the reaction rate. The CoMFA result suggests that the reaction rate will increase as the electron-donating ability of substituents increases.

Molecular Dynamics Study on Property Change of CMP Process by Pad Hardness (CMP 공정에서 연마패드 경도에 따른 연마 특성 변화 분자동력학 연구)

  • Kwon, Oh Kuen;Choi, Tae Ho;Lee, Jun Ha
    • Journal of the Semiconductor & Display Technology
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    • v.12 no.1
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    • pp.61-65
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    • 2013
  • We investigated the wearable dynamics of diamond spherical abrasive during the substrate surface polishing under the pad compression via classical molecular dynamics modeling. We performed three-dimensional molecular dynamics simulations using the Morse potential functions for the copper substrate and the Tersoff potential function for the diamond abrasive. The pad hardness had a big impact on the wearable dynamics of the abrasive. The moving speed of the abrasive decreased with increasing hardness of the pad. As the hardness decreased, the abrasive was indented into the pad and then the sliding motion of the abrasive was increased. So the pad hardness was greatly influenced on the slide-to-roll ratio as well as the wearable rate.