• Title/Summary/Keyword: MoM

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Synthesis of Pt-$MoO_3$ Electrode by Electrodeposition Method for Direct Methanol Fuel Cell (전기화학적 증착법에 의한 직접 메탄올 연료전지(DMFC)용 백금-삼산화몰리브테늄 전극제조)

  • Shin, Ju-Kyung;Jung, So-Mi;Baeck, Sung-Hyeon;Tak, Yong-Suk
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.435-439
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    • 2010
  • Pt-$MoO_3$ electrodes were fabricated on ITO-coated glass by electrodeposition method using 20 mM hydrogen hexachloroplatinate ($H_2PtCl_6$) and 10 mM Mo-peroxo electrolyte. Deposition order was varied, and catalytic activities of synthesized electrodes were compared with that of pure Pt electrode. Scanning Electron Microscopy (SEM) was utilized to examine surface morphology. The crystallinity of synthesized films was analyzed by X-ray Diffraction (XRD), and the oxidation state of both the platinum and molybdenum were determined by X-ray Photoelectron Spectroscopy (XPS) analyses. The catalytic activity and stability for methanol oxidation were measured using cyclic voltammetry (CV) and chronoamperometry (CA) in a mixture of 0.5 M $H_2SO_4$ and 0.5 M $CH_3OH$ aqueous solution. $MoO_3$ electrodeposited on the surface of Pt showed much higher catalytic acitivity and stability than pure Pt electrode due to the good contact between Pt and $MoO_3$.

Solidification Behavior of 3%C-5%Mo-5%W-10%(Cr or V) White Cast Irons (3%C-5%Mo-5%W-10%(Cr or V) 백주철의 응고거동에 관현 연구)

  • Ryu, Seong-Gon
    • Korean Journal of Materials Research
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    • v.10 no.2
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    • pp.144-147
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    • 2000
  • 10%C-5%Mo-5%W-10%Cr 및 10%C-5%Mo-5%W-10%V 백주철의 응고거동을 열분석을 통하여 연구하였다. 15Kg 용량의 고주파 유도옹해로에 선철, 고철, Fe-Mo, Fe-W, Fe-Cr, Fe-V 등을 장입시켜 용해시킨 후 슬래그를 제거시키고 $1550^{\circ}C$에서 Y블럭의 펩 주형에 주입하였다. 응고거동을 조사하기 위하여 50g을 Y블럭에서 채취한 뒤 알루미나 도가니에 넣어 재용해시킨 후 1$0^{\circ}C$/min의 냉각속도로 냉각시키면서 여섯 종류의 다른 온도에서 도중에 급냉시켜 응고조직을 광학현미경으로 관찰하였다. 10%C-5%Mo-5%W-10%Cr 백주철의 경우 초정 오스테나이트, 오스테나이트와 M(sub)7C(sob)3의 공정, 오스테나이트와 M(sub)6C의 공정으로, 10%C-5%Mo-5%W-10%V 백주철의 경우 초정 MC, 오스테나이트와 MC의 공정, 오스테나이트와 M(sub)2C의 공정으로 각각 순차적으로 정출하였다. 정출하였다.

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Effects of Sintering Conditions on the Properties of Sintered Molybdenum

  • Kadokura, Takanori;Hiraoka, Yutaka;Nakabayashi, Seiji;Yamamoto, Yoshiharu
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1153-1154
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    • 2006
  • Effects of sintering conditions such as sintering temperature and heating rate on oxygen content, density, microstructure and toughness of sintered Mo were investigated. The oxygen content of the sintered Mo significantly depended on the sintering conditions. The oxygen content of the primary sintered(below 1673 K) Mo influenced the densifications. The number of pores at grain boundaries of the secondary sintered(at 2073 K)Mo depended on the oxygen content of the primary sintered Mo. Grain growth of the secondary sintered Mo was inhibited by the existence of pores at the grain boundaries. The secondary sintered Mo having larger number of pore and smaller grain size demonstrated higher strength.

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MoM Forward Solver for Medical Microwave Imaging (의용 전자파 영상을 위한 모멘트법 순방향 해석 알고리즘)

  • Kim, Bo-Ra;Lee, Taek-Kyung;Son, Seong-Ho;Jeon, Soon-Ik
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.8
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    • pp.797-805
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    • 2009
  • In this paper, we developed MoM(Moment of Method) forward solver to implement the inverse scattering by using BIM(Born Iterative Method) for the detection of cancer in human body Especially, we adopted two-dimensional breast structure to analyze electromagnetic scattered phenomena. For the two-dimensional scattering structure, the integral equations is solved with MoM employing two-dimensional Green's function. Also, calculated results are compared with the measured results obtained from breast cancer detecting equipment.

Analysis of Induced Currents on the Dielectric Cube by the Fusion of MoM and PMCHW Integral Equation (MoM과 PMCHW 적분방정식 융합에 의한 유전체 육면체의 유도전류 계산)

  • Lim, Joong-Soo
    • Journal of the Korea Convergence Society
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    • v.6 no.5
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    • pp.9-14
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    • 2015
  • In this paper, we analysis the electromagnetic scattering of an arbitrary shape dielectric cube subjected to plane wave incidence in three dimensions. MoM(Method of Moments)in which a surface of a body is divided with small triangular patches and equivalence principle are used to fuse the PMCHW(Poggio, Miller, Chang, Harrington, and Wu) Integral Equations with respect to equivalent currents on a dielectric body. Triangular patch and loop-patch basis functions that is robust in wide frequency ranges are used for MoM formulations. Proposed method is very useful to analysis the induced current of arbitrary dielectric bodies and numerical results for a dielectric cube are presented.

Effects of Cr, V, Mo and W on Solidefication Structure of Multi-Component White Cast Iron (다합금계 백주철에 있어서 Cr, V, Mo 및 W가 응고조직에 미치는 영향)

  • Ryu, Seong-Gon
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.607-612
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    • 1998
  • 다합금계백주철의 성분원소인 Cr, V, Mo 및 W 의 첨가량을 변화시켜 응고조직을 관찰하였다. MC탄화물은 초정 austenite dendrite 내에 괴상 및 구상으로 M7C3탄화물은 intercellular boundary에 꽃형태 또는 bar 형태로, 그리고 M2C 탄화물은 M7C3탄화물과 마찬가지로 intercellular boundary에 침상으로 정출하였다. 기지조직은 주방상태에서 pealite 또는 (pearlite + austenite)의 혼합조직으로 구성되어 있었으며, 또한 EPMA 분석결과 MC탄화물은 V, M7C3 탄화물은 Cr 그리고 M2C탄화물은 Mo 및 W가 주성분으로 되어 있음을 알 수 있었다. 냉각곡선을 측정한 결과 액상에서 MC, M7C3, M2C 순으로 공정반응이 일어나고 있었으며 또한 X-선 회절시험을 통해 각 탄화물의 회절 peak를 관찰하였는바 응고조직의 사진과 잘 일치하고 있음을 알 수 있었다.

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A Study on the Correlation between Advanced Small Punch Test and Charpy V-notch Test on X20CrMoV121 and 2.25Cr1Mo steels Weldment (X20CrMoV121강과 2.25Cr1Mo강 용접부의 ASP 시험과 CVN 충격 시험의 상관관계에 대한 연구)

  • Lee, Dong-Hwan;Kim, Hyoung-Sup
    • Journal of Welding and Joining
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    • v.26 no.3
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    • pp.37-44
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    • 2008
  • Charpy V-Notch test is commonly used to evaluate fracture toughness. However, since the region to be evaluated is limited to bulk material due to the specimen size required, individual evaluation of micro-structures on weldment is very difficult. In this study, ASP(Advanced Small Punch) test was carried out to evaluate material degradation and fracture toughness on the B.M, W.M and each micro-structures of HAZ for X20CrMoV121 and 2.25Cr1Mo steels with artificial aging time. In addition, to evaluate fracture toughness and material degradation of B.M and W.M of X20CrMoV121 steels with aging times, CVN (Charpy V-notch) test was performed. And then the correlation between ASP and CVN test on X20CrMoV121 steels was obtained. Furthermore, through this correlation, material degradation property of each micro-region of the HAZ in weldment, which was impossible to be evaluated by the CVN test, can be estimated and determined.

Ferroelectric Properties of Substituted Aurivillius Phases SrBi2Nb2-xMxO9 (M=Cr, Mo)

  • Moon, S.-Y.;Choi, K. S.;Jung, K. W.;Lee, H.;Jung, D.
    • Bulletin of the Korean Chemical Society
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    • v.23 no.10
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    • pp.1463-1482
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    • 2002
  • Partially doped Aurivillius phases SrBi2N$b_{2-x}M_xO_9$ (M=Cr and Mo) were successfully synthesized and characterized. The extent of the substitution was limited at ~20 mole % because of the size differences between $Nb^{5+}$ and $Cr^{6+}$, and between $Nb^{5+}$ and $Mo^{6+}$. When the amount of substitution exceeded ~20 mole%, the phases began to collapse and the second phases were made. The dielectric constants of substituted compounds were enlarged nevertheless Cr or Mo is substituted. The increment is bigger in the Mo substituted compound than in the Cr doped one although the Nb(Cr)$O_6$ octahedra could be more strongly distorted than the Nb(Mo)$O_6$ octahedra since the ionic size difference between $Nb^{5+}$ and of $Cr^{6+}$ is much bigger than that between $Nb^{5+}$ and $Mo^{6+}$. Consequently, the dielectric constant of the substituted Aurivillius phase $Bi_2$A_{n-1}B_{n-x}M_xO_{3n+1}$$ depends on the extent of distortion of the B$O_6$ octahedra and more strongly on the polarizability of the metal.