• Title/Summary/Keyword: Mixture Electrode

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Concurrent Electrocatalysis and Sensing of Hydrazine and Sulfite and Nitrite Ions using Electrodeposited Gold Nanostructure-Modified Electrode

  • Seo, Yeji;Manivannan, Shanmugam;Kang, Inhak;Shin, Woo-Seung;Kim, Kyuwon
    • Journal of Electrochemical Science and Technology
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    • v.8 no.1
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    • pp.25-34
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    • 2017
  • Concurrent electrocatalysis and sensing of hydrazine, sulfite ions, and nitrite ions in a mixture were studied using electrodes modified by electrodeposited Au nanostructures (NSs). The ${\beta}$-cyclodextrin-mixed silicate sol-gel composite was drop-casted on the electrode surface and nucleation guided by ${\beta}$-cyclodextrin occurred, followed by the electrodeposition of Au NSs. The additive, ${\beta}$-cyclodextrin, played an evident role as a structure-directing agent; thus, small raspberry-like Au NSs were obtained. The modified electrodes were characterized by surface characterization techniques and electrochemical methods. The Au NSs-modified electrodes effciently electrocatalyzed the oxidation of toxic molecules such as hydrazine and sulfite and nitrite ions even in the absence of any other electron transfer mediator or enzyme immobilization. Well-resolved oxidation peaks along with decreased overpotentials were noticed during the electrooxidation process. The fabricated Au nanostructured electrode clearly distinguished the electrooxidation peaks of each of the three analytes from their mixture.

Discharge Characteristics of SF6 Mixture Gases due to Processing Status of needle electrode under Non-Uniform Fields (불평등 전계 하에서의 침전극 가공상태에 따른 SF6혼합가스의 방전특성)

  • Go, Y.S.;Seo, H.J.;Rhie, D.H.
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.198-199
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    • 2006
  • AC spark discharge voltage of SF6/C02and SF6/N2 containing various mixed rate in volume percent (1, 5 and 10%) of SF6 in non-uniform fields are investigated. The needle to plane electrode gap spacing was 5 and 10 mm, and the gas pressure was varied within the range of 0.1${\sim}$0.7 MPa. We have observed a N-characteristic typical for the electronegative gases even in gas mixtures of 1% SF6 with CO2 and N2 as buffer gases. Especially, the materials of the needle electrode affect the insulation properties of the gas mixtures drastically. On the contrary to the case of needle electrodes made by mild steel or high carbon steel, the N-characteristics are hardly perceived in the case of stainless steel needle in this experiment.

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Evaluation of Electrolyte and Electrode Spacing for Application of Electrokinetic Remediation (전기동력학적 정화기술 적용을 위한 최적의 전해질 선택 및 전극간의 거리 평가)

  • Park, Geun-Yong;Kim, Woo-Seung;Kim, Do-Hyung;Yang, Jung-Seok;Baek, Kitae
    • Journal of Soil and Groundwater Environment
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    • v.18 no.1
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    • pp.6-15
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    • 2013
  • The influence of processing fluids and electrode spacing on the electrokinetic process was evaluated to remediate As-, Cu-, Pb-contaminated soil. Single and mixture of sodium citrate, EDTA and NaOH was used to investigate the metal extraction. EDTA for washing reagent showed the highest removal efficiency. Based on the extraction result, the electrode spacing (20, 40, 60 cm) on the electrokinetic process was investigated to remove the multi-metals from soil. The highest removal was observed at the experiment with 60 cm of electrode spacing, however, the correlation between electrode spacing and removal of metals was not clear. The electrode spacing influenced the amount of accumulated electro-osmotic flow. BCR sequential extraction showed that electrokinetic process removed the fractionation of metals bound to Fe-Mn oxyhydroxide.

Physical Properties of ITO/PVDF as a function of Oxygen Partial Pressure (산소 분압 조절에 따른 ITO/PVDF 박막 물성 조절 연구)

  • Le, Sang-Yub;Kim, Ji-Hwan;Park, Dong-Hee;Byun, Dong-Jin;Choi, Won-Kook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.10
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    • pp.923-929
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    • 2008
  • On the piezoelectric polymer, PVDF (poly vinylidene fluoride), the transparent conducting oxide (TCO) electrode material thin film was deposited by roll to roll sputtering process mentioned as a mass product-friendly process for display application. The deposition method for ITO Indium Tin Oxides) as our TCO was DC magnetron sputtering optimized for polymer substrate with the low process temperature. As a result, a high transparent and good conductive ITO/PVDF film was prepared. During the process, especially, the gas mixture ratio of Ar and Oxygen was concluded as an important factor for determining the film's physical properties. There were the optimum ranges for process conditions of mixture gas ratio for ITO/PVDF From these results, the doping mechanism between the oxygen atom and the metal element, Indium or Tin was highly influenced by oxygen partial pressure condition during the deposition process at ambient temperature, which gives the conductivity to oxide electrode, as generally accepted. With our studies, the process windows of TCO for display and other application can be expected.

Protective effects of citrus based mixture drinks (CBMDs) on oxidative stress and restraint stress

  • Cho, MyoungLae;Kim, Dan-Bi;Shin, Gi-Hae;Kim, Jae-Min;Seo, Yoonhee;Choe, Soo Young;Cho, Ju Hyun;Kim, Young-Cheul;Lee, Jin-Ha;Lee, Ok-Hwan
    • Food Science and Biotechnology
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    • v.27 no.6
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    • pp.1801-1809
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    • 2018
  • In the current study investigated the protective effects of citrus based mixture drinks (CBMDs) using oxidative stress in human dermal fibroblast (HDF) cells and restraint-stressed rats. The CBMDs contained citrus bioflavonoids including narirutin and hesperidin. The cell viability of HDF cells treated with $H_2O_2$ was observed at 53.9% but treated with CBMD-1 and CBMD-2 ($500{\mu}g/mL$) on $H_2O_2$ exposed HDF cells significantly increased the relative cell viability at 65.0 and 72.2%, respectively. In the treadmill test, the time spent on the electrode plate in the restraint-stressed group was analyzed 24.1 s, but restraint-stressed rats with administered CBMDs (300 mg/kg) had significantly decreased the time at 2.4 (CBMD-1) and 4.7 (CBMD-2) s, respectively. In addition, number of touches the electrode plate in restraint-stressed group was observed at 42.4 ea, but, restraint-stressed rats with administered CBMD-1 and CBMD-2 (300 mg/kg) were significantly decreased at 7.0 and 10.2 ea, respectively.

Electrohydrodynamic (EHD) Enhancement of Boiling Heat Transfer of R113+WT4% Ethanol

  • Oh Si-Doek;Kwak Ho-Young
    • Journal of Mechanical Science and Technology
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    • v.20 no.5
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    • pp.681-691
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    • 2006
  • Nucleate boiling heat transfer for refrigerants, R113, and R113+wt4% ethanol mixture, an azeotropic mixture under electric field was investigated experimentally in a single-tube shell/ tube heat exchanger. A special electrode configuration which provides a more uniform electric field that produces more higher voltage limit against the dielectric breakdown was used in this study. Experimental study has revealed that the electrical charge relaxation time is an important parameter for the boiling heat transfer enhancement under electric field. Up to 1210% enhancement of boiling heat transfer was obtained for R113+wt4% ethanol mixture which has the electrical charge relaxation time of 0.0053 sec whereas only 280% enhancement obtained for R113 which has relaxation time of 0.97 sec. With artificially machined boiling surface, more enhancement in the heat transfer coefficient in the azeotropic mixture was obtained.

Electrochemical Properties of Fatty Acid Containing Azobenzene for Phospholipid (인지질에 따른 아조벤젠기를 함유한 지방산의 전기화학적 특성)

  • Park, Keun-Ho;Son, Tae-Chul;Lee, Kyoung-Goo;Kim, Nam-Suk;Park, Tae-Gon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.43-46
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    • 2002
  • We have investgated the photoisomerization using light irradiation 8A5H-phospholipid( L-$\alpha$-dimyristoylphosphatidylcholine[DMPC], L-$\alpha$-dilauroylphosphatidylcholine[DLPC]mixture LB film accumulated by monolayer on an ITO. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $NaClO_{4}$ solution at a variable concentration and variable number layers LB film. The scan rate was 100mV/s.

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New Electrode Shape for High Xe-content Gas in AC PDP

  • Park, Cha-Soo;Choi, Joon-Young;Kim, Goon-Ho;Kim, Joong-Kyun;Kim, Dong-Hyun;Lee, Ho-Jun;Park, Chung-Hoo
    • Journal of Information Display
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    • v.4 no.4
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    • pp.13-18
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    • 2003
  • One of the most important issues in AC PDP is the improvement of luminous efficiency. One possible method for achieving this aim is by increasing Xe partial pressure in discharge gas mixture. The increase of Xe ratio, however, causes the driving voltage to rise, even if brightness is increased. In this study, a new electrode shape is proposed. A test panel fabricated by using a new electrode shows that efficacy has improved by 25 % and sustain voltage has decreased by 20 % compared with the conventional structure.

Green Synthesized Cobalt Nano Particles for using as a Good Candidate for Sensing Organic Compounds

  • Siada, S. O. Ranaei
    • Journal of Electrochemical Science and Technology
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    • v.6 no.4
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    • pp.111-115
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    • 2015
  • In this work electrochemical oxidation of Ascorbic acid (AA) on the surface of Cobalt nano particle modified carbon paste electrode (CoNPsMCPE) was studied in alkaline media. CoNPs were green synthesized using Piper longum and a mixture of 5% (w/w) of it were made with carbon paste. CoNPs showed good electrocatalytic activity in alkaline media. Cyclic voltammetry (CV) and chronoamperometry (CA) were used to study the electrochemical performance of CoNPsMCPE. The number of monolayers on the surface of electrode was calculated as 1.08×109 mol cm−2 that is equal to that of metal Cobalt electrode. Diffusion coefficient of AA was determined using CA analysis which was equal to 1.5×10−6cm2 s−1.

Discharge Properties of an AC Plasma Display Panel with Comb-Type Electrodes (Comb형 전극구조를 갖는 AC 플라즈마 디스플레이 패널의 방전특성)

  • Kim, Dong-Su;Jang, Ji-Geun;Im, Seong-Gyu;Jang, Ho-Jeong
    • Korean Journal of Materials Research
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    • v.9 no.2
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    • pp.195-198
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    • 1999
  • The newly designed Ac-PDP(plasma display panel with comb-type electrode) structure was fabricated by using the screen printing method and the electrical and optical characteristics were measured under the various discharge conditions. The minimum firing voltages measured under pure Ne and Ne+Xe mixture gas with the application of 10 kHz square wave were 190V and 160V, respectively. The firing voltages of the PDP cell with the comb-type electrode were compared with those of the cell with matrix electrode under the same discharge condition. The firing voltage of the PDP cell with comb-type electrode was 15 V lower than that of the PDP cell with conventional matrix electrodes.

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