• Title/Summary/Keyword: Mixed Particle

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3-D Perspectives of Atmospheric Aerosol Optical Properties over Northeast Asia Using LIDAR on-board the CALIPSO satellite (CALIPSO위성 탑재 라이다를 이용한 동북아시아 지역의 대기 에어러솔 3차원 광학특성 분포)

  • Lee, Kwon-Ho
    • Korean Journal of Remote Sensing
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    • v.30 no.5
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    • pp.559-570
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    • 2014
  • Backscatter signal observed from the space-borne Light Detection And Ranging (LIDAR) system is providing unique 3-dimensional spatial distribution as well as temporal variations for atmospheric aerosols. In this study, the continuous observations for aerosol profiles were analyzed during a years of 2012 by using a Cloud-Aerosol LIDAR with Orthogonal Polarization (CALIOP), carried on the Cloud-Aerosol LIDAR and Infrared Pathfinder Satellite Observation (CALIPSO) satellite. The statistical analysis on the particulate extinction coefficient and depolarization ratio for each altitude was conducted according to time and space in order to estimate the variation of optical properties of aerosols over Northeast Asia ($E110^{\circ}-140^{\circ}$, $N20^{\circ}$ $-50^{\circ}$). The most frequent altitudes of aerosols are clearly identified and seasonal mean aerosol profiles vary with season. Since relatively high particle depolarization ratios (>0.5) are found during all seasons, it is considered that the non-spherical aerosols mixed with pollution are mainly exists over study area. This study forms initial regional 3-dimensional aerosol information, which will be extended and improved over time for estimation of aerosol climatology and event cases.

Production of Foamed Glass by Using Hydrolysis of Waste Glass (II) - Foaming Process of Hydrated Glass - (폐유리의 가수분해 반응에 의한 발포유리의 제조(II) - 가수분해된 유리의 발포 -)

  • Lee, Chul-Tae;Lee, Hong Gil;Um, Eui-Heum
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.760-767
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    • 2005
  • The goal of this study was to find an application method of the waste soda-lime glass as the feed material for foamed glass by foaming of hydrated waste glass. The proper conditions for the foaming of hydrated waste glass were found to be: temperature of $92.5^{\circ}C$; reaction time of 10~20 min; particle size of -325 mesh as the unhydrated glass starting materials; and graphite weight to the hydrated glass ratio of 0.003 as the foaming agent. The resulting formed glass made from hydrated mixed waste glass under above mentioned conditions had the characteristics of density less than $0.2g/cm^3$ and thermal conductivity of $0.05kcal/mh^{\circ}C$.

Characteristics of non-waxy rice starch/gum mixture gels (멥쌀 전분과 검물질 혼합물 겔의 특성)

  • Shin Malshick;Kwon Ji-Young;Song Ji-Young
    • Korean journal of food and cookery science
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    • v.21 no.6 s.90
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    • pp.942-949
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    • 2005
  • To improve the textural properties and stabilize the structure and gel matrix of non-waxy rice starch gels, non-waxy rice starch/gum mixture gels were prepared from various food gums, gum arabic, guar, algin, deacyl gellan, xanthan and gellan gums. The morphological and textural properties and freeze-thaw stability of their gels were compared. Rice starch/gum mixture gels with various gums formed a more homogeneous gel matrix with smaller particle size than rice starch gel without Em, but the trends differed depending on the gum types. The textural properties of rice starch/gum mixture gels were changed with the gum types. The shape of the rice starch/gum mixture gel matrix was desirable when mixed with gellan and algin. The textural properties of gels hardened in the rice starch/algin mixture gel and softened in the rice starch/algin mixture gel. The rice starch gels showed V-type crystallinity by x-ray diffractometer, but the peak at $2\theta$ = $20^{o}$ was decreased with increasing gum addition. The freeze-thaw stability increased with increasing gum addition. Gellan and algin were especially effective.

The Effect of the Self-Healing Microcapsules on the Quality and Healing Properties of Cement Composites (자기치유 마이크로캡슐이 시멘트 복합재료의 품질 및 치유특성에 미치는 영향)

  • Kim, Cheol-Gyu;Oh, Sung-Rok;Kim, Ji-Hun;Choi, Yun-Wang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.389-396
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    • 2021
  • In this paper, it was evaluated that the effect of self-healing microcapsules on the quality and healing properties of cement composites. In the mixing of microcapsules, the plastic viscosity and yield stress of the cement composites decreased due to the particle properties of the microcapsules, and decreased in proportion to the mixing ratio. The table flow showed a tendency to decrease as the core material acted as a stimulant due to the loss of microcapsules, and the compressive strength could be supplemented through unit quantity correction. As a result of evaluating the effect of microcapsule mixing on the healing properties of cement composites, it was found that the unit water flow rate decreased by the healing reaction immediately after crack initiation. When more than 3% of microcapsules were mixed, it was found that there was a healing rate of more than 95% at 7 days of healing age.

Synthesis of Highly Dispersed Pd Nanocatalysts Through Control of Organic Ligands and Their Electrochemical Properties for Oxygen Reduction Reaction in Anion Exchange Membrane Fuel Cells (유기 리간드 제어를 통한 고분산 팔라듐 나노 촉매의 합성 및 음이온교환막 연료전지를 위한 산소 환원 반응 특성 분석)

  • Sung, Hukwang;Sharma, Monika;Jang, Jeonghee;Jung, Namgee
    • Korean Journal of Materials Research
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    • v.28 no.11
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    • pp.633-639
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    • 2018
  • In anion exchange membrane fuel cells, Pd nanoparticles are extensively studied as promising non-Pt catalysts due to their electronic structure similar to Pt. In this study, to fabricate Pd nanoparticles well dispersed on carbon support materials, we propose a synthetic strategy using mixed organic ligands with different chemical structures and functions. Simultaneously to control the Pd particle size and dispersion, a ligand mixture composed of oleylamine(OA) and trioctylphosphine(TOP) is utilized during thermal decomposition of Pd precursors. In the ligand mixture, OA serves mainly as a reducing agent rather than a stabilizer since TOP, which has a bulky structure, more strongly interacts with the Pd metal surface as a stabilizer compared to OA. The specific roles of OA and TOP in the Pd nanoparticle synthesis are studied according to the mixture composition, and the oxygen reduction reaction(ORR) activity and durability of highly-dispersed Pd nanocatalysts with different particles sizes are investigated. The results of this study confirm that the Pd nanocatalyst with large particles has high durability compared to the nanocatalyst with small Pd nanoparticles during the accelerated degradation tests although they initially indicated similar ORR performance.

Investigation of shear behavior of soil-concrete interface

  • Haeri, Hadi;Sarfarazi, Vahab;Zhu, Zheming;Marji, Mohammad Fatehi;Masoumi, Alireza
    • Smart Structures and Systems
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    • v.23 no.1
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    • pp.81-90
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    • 2019
  • The shear behavior of soil-concrete interface is mainly affected by the surface roughness of the two contact surfaces. The present research emphasizes on investigating the effect of roughness of soil-concrete interface on the interface shear behavior in two-layered laboratory testing samples. In these specially prepared samples, clay silt layer with density of $2027kg/m^3$ was selected to be in contact a concrete layer for simplifying the laboratory testing. The particle size testing and direct shear tests are performed to determine the appropriate particles sizes and their shear strength properties such as cohesion and friction angle. Then, the surface undulations in form of teeth are provided on the surfaces of both concrete and soil layers in different testing carried out on these mixed specimens. The soil-concrete samples are prepared in form of cubes of 10*10*30 cm. in dimension. The undulations (inter-surface roughness) are provided in form of one tooth or two teeth having angles $15^{\circ}$ and $30^{\circ}$, respectively. Several direct shear tests were carried out under four different normal loads of 80, 150, 300 and 500 KPa with a constant displacement rate of 0.02 mm/min. These testing results show that the shear failure mechanism is affected by the tooth number, the roughness angle and the applied normal stress on the sample. The teeth are sheared from the base under low normal load while the oblique cracks may lead to a failure under a higher normal load. As the number of teeth increase the shear strength of the sample also increases. When the tooth roughness angle increases a wider portion of the tooth base will be failed which means the shear strength of the sample is increased.

Study on the Thermomechanical Properties of Epoxy-Silica Nanocomposites by FTIR Molecular Structure Analyses (FTIR 분자구조 해석을 통한 에폭시-실리카 나노복합소재의 열기계적 물성 연구)

  • Jang, SeoHyun;Han, Yusu;Hwang, DoSoon;Jung, Juwon;Kim, YeongKook
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.2
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    • pp.51-57
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    • 2021
  • This paper analyzed the effects of the concentration of nano-silica particles contained in epoxy resin on the thermomechanical properties of the composite materials. The 12nm sized nanoparticles were mixed with epoxy polymer by 5 different weight ratios for the test samples. The glass transition temperature, stress relaxation, and thermal expansion behaviors were measured using dymanic mechanical analyzer (DMA) and thermomechanical analyzer (TMA). It was shown that the nano particle mixing ratios had significant influences on the viscoelastic behaviors of the materials. As the content of the silica particles was increased, the elastic modulus was also increased, while the glass transition temperatures were decreased. Fourier Transform Infrared Spectroscopy (FTIR) results played an important role in determining the causes of the property changes by the filler contents in terms of the molecular structures, enabling the interpretations on the material behaviors based on the chemical structure changes.

Effect of Heat Treatment Temperatures on Photocatalytic Degradation of Methylene Blue by Mesoporous Titania (메틸렌블루 광촉매 분해반응에서 이산화티타늄 열처리 온도 영향)

  • Lim, Samryong;Nguyen-Phan, Thuy-Duong;Shin, Eun Woo
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.61-66
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    • 2011
  • In this study, we prepared $TiO_2$ with the sol-gel method and controlled physico-chemical properties by a simple heat treatment. All materials were applied to photocatalytic decomposition of methylene blue and the material treated at 473 K showed the highest photocatalytic efficiency. The high performance resulted from a high adsorption amount of methylene blue due to a high surface area of $229.8m^2/g$. However, the material treated at 873 K, despite of a low surface area of $23.8m^2/g$ and a large particle size of 28.38 nm, exhibits a good photocatalytic performance due to the effect of mixed cyrstalline rutile and anatase phases formed by the high heat treatment temperature.

Effect of Alloy Elements on Galvannealed Coating Quality in IF High Strength Steels (IF 고강도 합금화 용융아연도금강판의 표면품질에 미치는 합금원소의 영향)

  • Jeon, Sun-Ho;Chin, Kwang-Geun;Shin, Kwang-Soo;Sohn, Ho-Sang;Kim, Dai-Ryong
    • Korean Journal of Metals and Materials
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    • v.46 no.5
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    • pp.289-295
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    • 2008
  • The effect of the alloy elements(Si/Mn) ratio on the coating quality including wettabilty with molten zinc, galvannealing kinetics and crater has been investigated in interstitial-free high strength steel(IFHSS) containing Si and Mn. When the Si/Mn ratio was below 0.75, IF-HSS exhibited a good wettability leading to a good galvannealed coating quality after annealing at $800^{\circ}C$ for 40s in $15%H_2-N_2$ mixed gas with dew point $-60^{\circ}C$. In contrast, the wettability and galvannealed coating quality were deteriorated in the Si/ Mn ratio above 0.75. It is shown that they have relevance to oxides forms by selective oxidation on the steel surface. The oxide particles dispersed on the steel surface with a surface coverage of below 40% resulted in good wettability and galvannealed coating quality. The oxide particle is mainly consisted of $Mn_2SiO_4$ with low contact angle in molten zinc. On the other hand, the continuous oxide layer on the steel surface, such as network- and film-type,caused to poor wettability and galvannealed coating quality. The coverage of oxide layer was above 80%, and its chemical species was $SiO_2$ with high contact angle in molten zinc. Consequently, the Si/Mn alloy ratio played an importance role in galvannealed coating quality of IF-HSS.

Research on Afterglow Brightness of Sr4-(x+y+z)Al14O25 : Eux, Dyy, Agz by Solid State Synthesis (고상법으로 합성한 Sr4-(x+y+z)Al14O25 : Eux, Dyy, Agz계 축광성 형광체 장잔광의 연구)

  • Kim, Seung-woo;Kim, Jung-sik
    • Korean Journal of Metals and Materials
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    • v.49 no.4
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    • pp.348-354
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    • 2011
  • Long-lasting brightness $Sr_{4}Al_{14}O_{25}$ : $Eu^{2+}$, $Dy^{3+}$, $Ag^{+}$ phosphor was synthesized by modified solid state reaction and its photoluminescence was investigated. $Sr(NO_3)_{2}$ and $Al(NO_3)_3{\cdot}9H_{2}O$ as starting materials, and $B_{2}O_{3}$ as a flux were mixed with $Eu_{2}O_{3}$ as an activator, $Dy_{2}O_{3}$ as a coactivator, and $AgNO_{3}$ as a charge compensator. The crystalline of target powder showed a single-phase $Sr_{4}Al_{14}O_{25}$ by the XRD characterization and the average particle size was about 20-30 ${\mu}m$ from the FE-SEM observation. $Ag^{+}$ ion doping effects (0-0.06 mol) on $Sr_{4}Al_{14}O_{25}:Eu^{2+},\;Dy^{3+},\;Ag^{+}$ phosphor were measured by photoluminescence spectrometer and luminescence meter. The of photoluminescence intensity of the $Sr_{3.64}Al_{14}O_{25}:Eu_{0.11},\;Dy_{0.22},\;Ag_{0.03}$ phosphor was higher than other compositions and afterglow brightness was 0.186 $cd/m^{2}$.