• 한국분말재료학회지
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• 제20권6호
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• pp.439-444
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• 2013

Fe foam with above 90% porosity and 2 millimeter pore size was successfully fabricated by a slurry coating process. In this study, the binder contents were controlled to produce the Fe foam with different pore size, strut thickness and porosity. Firstly, the slurry was prepared by uniform mixing with Fe powders, distilled water and polyvinyl alcohol(PVA) as initial materials. After slurry coating on the polyurethane(PU) foam the sample was dried at $80^{\circ}C$. The PVA and PU foams were then removed by heating at $700^{\circ}C$ for 3 hours. The debinded samples were subsequently sintered at $1250^{\circ}C$ with holding time of 3 hours under hydrogen atmosphere. The three dimensional geometries of the obtained Fe foams with open cell structure were investigated using X-ray micro CT(computed tomography) as well as the pore morphology, size and phase.

• Geomechanics and Engineering
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• 제29권6호
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• pp.627-643
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• 2022

Water-rock interactions have a significant influence on the mechanical behavior of rocks. In this study, uniaxial compression and tension tests on different water-treated sandstone samples were conducted. Acoustic emission (AE) monitoring and micro-pore structure detection were carried out. Water-rock interactions and their effects on rock mechanical behavior were discussed. The results indicate that water content significantly weakens rock mechanical strength. The sensitivity of the mechanical parameters to water treatment, from high to low, are Poisson ratio (𝜇), uniaxial tensile strength (UTS), uniaxial compressive strength (UCS), elastic modulus (E), and peak strain (𝜀). After water treatment, AE activities and the shear crack percentage are reduced, the angles between macro fractures and loading direction are minimized, the dynamic phenomenon during loading is weakened, and the failure mode changes from a mixed tensile-shear type to a tensile one. Due to the softening, lubrication, and water wedge effects in water-rock interactions, water content increases pore size, promotes crack development, and weakens micro-pore structures. Further damage of rocks in fractured and caved zones due to the water-rock interactions leads to an extra load on the adjoining coal and rock masses, which will increase the risk of dynamic disasters.

• Bulletin of the Korean Chemical Society
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• 제9권2호
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• pp.94-98
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• 1988

An improvement over the method of pore size distribution analysis has been made in this work. The improved method is based upon the idea of the micro pore analysis of Mikhail, Brunauer, and Bodor, and utilizes the V-t curve of nitrogen adsorption. Two pore models are assumed, and the deviation of the initial slope of the V-t plot is ascribed to the pore filling and to the adsorption on the wall of unfilled pores. The improved method of this work is very convenient in that the analysis starts from the small pore regions. The method of this work is however quite distinct from the similar V-t plot method proposed by Sellevold and Radjy. The proposed method is applied to a few adsorbents, and very satisfactory results are obtained. The cumulative surface area calculated by this method also agrees very well with those obtained by the BET plot or by the t-method.

• 콘크리트학회논문집
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• 제16권2호
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• pp.277-282
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• 2004

In a hardened concrete, diffusion of oxygen, carbon dioxide, aggressive ions, and moisture from the environment to the concrete takes place through the pore network. It is well known that making dense cement matrix enhances the durability of concrete as well as all the characteristics including strength of concrete. In this paper,9 mix concretes with water to cementitious material ratio (40,45, and $50\%$) and replacement ratio of GGBFS (40 and $60\%$ of cement by weight) were studied on the micro-pore structure by mercury intrusion porosimetry and the accelerated chloride diffusion test by potential difference. From the results the average pore diameter and accelerated chloride diffusivity of concrete were ordered NPC > G4C > G6C. It is concluded that there is a good correlation between the average pore diameter and the chloride diffusivity, and the mineral admixtures has a filling effect, which increases the tortuosity of pore and makes large pores finer, on the pore structure of cement matrix due to the latent hydraulic reaction with hydrates of cement.

• 지질공학
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• 제20권4호
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• pp.461-465
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• 2010

암석에서의 풍화 및 투수성은 방사성폐기물 지하동굴처분 및 암반구조물의 안정성 확보 및 장기적 관리측면에서 매우 중요한 역할을 한다. 이들 암석의 풍화 및 투수성은 암석의 내 구조 특성에 따라 크게 영향을 받는다. 즉 암석 내부의 공극, 미소 크랙 등의 양적 정도에 의해 풍화가 빨리 진행되기도 한다. 또한 암석 내부구조의 양적 평가는 그 암석의 풍화 정도를 정량적으로 평가할 수 있는 수단이 되기도 한다. 따라서 암석의 내부구조를 3치원적으로 정확하게 파악한다는 것은 암반구조물의 장기적 관리 측면에서 매우 중요하다고 하겠다. 이 연구는 국내 신선한 화강암과 풍화된 화강암을 대상으로 X선 CT촬영을 실시하여 3차원으로 공극의 분포를 분석하였다. 분석 결과는 암석 내부의 공극의 분포와 공극률을 잘 표현하고 있다.

• 한국응용과학기술학회지
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• 제31권3호
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• pp.408-415
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• 2014

In order to prepare high-quality activated carbons (ACs), coal tar pitch (CTP), and mixtures of CTP and petroleum pitch (PP) were activated with KOH. The ACs prepared by activation of CTP in the range of $700{\sim}1000^{\circ}C$ for 1~5 h had very porous textures with large specific surface areas of $2470{\sim}3081m^2/g$. The optimal activation conditions of CTP were determined as CTP/KOH ratio of 1:4, activation temperature of $900^{\circ}C$, and activation time of 3 h. The obtained AC showed the highest micro-pore volume, and pretty high specific surface area and meso-pore volume. The micro-pore volumes and specific areas of activated mixtures of CTP and PP were similar to each other but the meso-pore volume could be increased. In order to change the degree of crystallinity of precursors before KOH activation process, the CTPs were carbonized in the range of $500{\sim}900^{\circ}C$. As the carbonization temperature increased, the specific surface area and pore volume of the activated ACs with the same activation conditions for CTP decreased dramatically. It was demonstrated that the increased pore size distribution of AC electrodes in the range of 1 to 2 nm plays an important role in the performance of electric double-layer capacitor.

• 대한금속재료학회지
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• 제47권9호
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• pp.597-603
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• 2009

The hydrogen reduction behavior of ultrasonic ball-milled $WO_3-CuO$ nanopowder, which is highly related with micro-pore structure, was investigated by thermogravimetry(TG) and hygrometry system. EDS and TEM results represented that the ultrasonic ball-milled $WO_3-CuO$ nanopowder consisted of the agglomerates which was confirmed as a homogeneous mixture of $WO_3$ and CuO particles. It was found that the reduction reaction of CuO was retarded by initial micro-pores which are smaller than 40 nm in the ultrasonic ball-milled $WO_3-CuO$ nanopowder. The earlier agglomeration of Cu particles at comparably low temperature decreased the volume of micro-pores in the $WO_3-CuO$ nanopowder which caused the retardation of $WO_3$ reduction reaction. These results clearly explain that the micro-pore structure significantly affected the reduction reaction of $WO_3$ and CuO in the $WO_3-CuO$ nanopowder.

• 대한토목학회논문집
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• 제43권1호
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• pp.1-7
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• 2023

서로 다른 밀도를 가진 기포콘크리트 시편을 생성하고, 각 시편의 특성을 SEM, micro-CT 등의 미세구조 분석 방법을 활용하여 분석하였다. 서로 다른 재령 일자에 대한 기포콘크리트 시편의 공극과 고체 구조를 분석함으로써, 재령 기간이 재료 특성 변화에 미치는 영향을 살펴보았다. 각 기포콘크리트 시편의 압축강도와 열전도도를 측정하여, 재료 물성과 미세구조적 특성 간의 상관관계에 대하여 분석하였으며, 결과를 통해 밀도와 재령 기간이 재료 강도에 미치는 영향을 확인하였다.

• 한국분말재료학회지
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• 제21권4호
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• pp.266-270
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• 2014

Metal foams have a cellular structure consisting of a solid metal containing a large volume fraction of pores. In particular, open, penetrating pores are necessary for industrial applications such as in high temperature filters and as a support for catalysts. In this study, Fe foam with above 90% porosity and 2 millimeter pore size was successfully fabricated by a slurry coating process and the pore properties were characterized. The Fe and $Fe_2O_3$ powder mixing ratios were controlled to produce Fe foams with different pore size and porosity. First, the slurry was prepared by uniform mixing with powders, distilled water and polyvinyl alcohol(PVA). After slurry coating on the polyurethane(PU) foam, the sample was dried at $80^{\circ}C$. The PVA and PU foams were then removed by heating at $700^{\circ}C$ for 3 hours. The debinded samples were subsequently sintered at $1250^{\circ}C$ with a holding time of 3 hours under hydrogen atmosphere. The three dimensional geometries of the obtained Fe foams with an open cell structure were investigated using X-ray micro CT(computed tomography) as well as the pore morphology, size and phase. The coated amount of slurry on the PU foam were increased with $Fe_2O_3$ mixing powder ratio but the shrinkage and porosity of Fe foams were decreased with $Fe_2O_3$ mixing powder ratio.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2002년도 학술논문발표회
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• pp.31-36
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• 2002

Recently, more interests in surface treatment of structure with water repellent agent are steadily increased, But, investigation of its properties such as protection, durability, morphology of micro structure is not sufficient. Therefore, This paper is aimed for the investigation of water repellent property and change of morphology of micro pores in mortar that is treated by water repellent agent(Inorganic polymer based material). Water repellent property, water absorption coefficient, air permeability, porosity and the observation of micro structure was investigated in different water repellent agent type. The test results indicated that water repellent treated mortar showed low absorption coefficient and air permeability(breathing effect). This is why inorganic polymer is coated at the wall of capillary and micro pores, also, the volume of micro pore is reduced without the change of morphology in micro structure.