• Title/Summary/Keyword: MgB2

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Classification of calcicoles and calcifuges on the basis of the ratio of soluble to insoluble ca2+ and mg2+ in the leaves (可溶性, 不溶性 Ca2+ 과 MG2+ 比에 의한 好石灰 및 嫌石灰植物의 分類)

  • Kim, Joon-Ho;Kwak, Young-Se;Mun, Hyung-Tae
    • The Korean Journal of Ecology
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    • v.15 no.3
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    • pp.311-328
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    • 1992
  • In other to classify calcicoles and calcifuges and calcifuges within plant communities occurring on limestone and granite soils in chungbuk province, korea, soil propertile, constancy for species by prsence or absence, and ratios of soluble to insoluble $Ca^{2+}$ and $Mg^{2+}$ were investigated. In the limestone soils ph values and $Ca^{2+}$ and $Mg^{2+}$ content, ranging 7.26 ~7.48, 5.32~7.37 mg $Ca^{2+}/g$ and 0.42~0.62 mg $Mg^{2+}/g$, respectively, were higher than those in the granite soil with ph 5.76, 1.03mg $Ca^{2+}/g$ and 0.24mg $Mg^{2+}/g$. species with high constancy in the 5 communities were classified into three groups; species group a(29~36% of total number of species) was composed of species occuring on the granite soil; group c(16~24%) is commonly distributed throughout both soils. Ratios of soluble to insoluble $Ca^{2+}$ and $Mg^{2+}$ ranged from 0.1 to 81.3 in the group a, 0.2 to 0.8 in the group b and 0.2 to 8.7 in the group c. species within each group can be divided into two groups based on the values of the ratio, below or above 1.0. consequently, each of the group a and c was classified again into two groups; the group a1 and c1 with the ratio of above 1.0 and the group a2 and c2 withbelow 1.0 but the ratio could not further subdivide the group b. from these results it was proposed that plants of the group a1 were termed as obligate calcicoles, the group b as obligate calcifuges, the group c1 as facultative calcicoles, the group c2 as facultative calcifuges and the group a2 as avoiding calcifuges.

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Nano $MgB_2$ Powder Synthesis by Spray Pyrolysis Method (분무열분해법에 의한 나노 $MgB_2$ 분말 제조 연구)

  • Ko Jae Woong;Yoo Jai Moo;Kim Young Kuk;Chung Kuk Chae;Yoo Sang lm;Han Bong Soo;Kim Young Jun
    • Progress in Superconductivity and Cryogenics
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    • v.7 no.1
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    • pp.1-4
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    • 2005
  • Nano- sized spherical $MgB_2$ Powders were synthesized by spray Pyrolysis method. The Influence of solution concentration and furnace reaction temperature on morphology and average particle size were investigated. For adequate preparation conditions, it has mostly spherical, solid and narrow particle size distribution. Average particle size$(X_{50})$ distribution was below 100 nm. The critical temperature for the synthesized $MgB_2$ was around 36K.

The Anisotropy of the London Penetration Depth and the Upper Critical Field in C-doped $MgB_2$ Single Crystals from Reversible Magnetization

  • Kang, Byeong-Won;Park, Min-Seok;Lee, Hyun-Sook;Lee, Sung-Ik
    • Progress in Superconductivity
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    • v.12 no.1
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    • pp.36-40
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    • 2010
  • We have studied the anisotropy of the London penetration depth of carbon doped $MgB_2$ single crystals, which was obtained from reversible magnetization measurements with the magnetic field both parallel and perpendicular to the c-axis. Similar to the pure $MgB_2$, the anisotropy of the upper critical field ${\gamma}_H$ decrease with temperature while the anisotropy of the London penetration depth ${\gamma}_{\lambda}$ slowly increases with temperature. However, the temperature dependence of ${\gamma}_H$ is drastically reduced and the value of ${\gamma}_{\lambda}$ becomes nearly ~1 as C is introduced. These results indicate that C substitution increases impurity scattering mainly in the $\sigma$ bands. The temperature dependence of the anisotropies agree well with the theoretical predictions with impurity scattering.

Wear Mechanisum of Carbon Bearing BOF Refreactories (전로용 MgO-C질 내화벽돌의 손상요인)

  • 김의훈;오영우;이철수;김종성;김종희
    • Journal of the Korean Ceramic Society
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    • v.23 no.1
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    • pp.51-59
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    • 1986
  • It was the first time the MgO-C brick was developed for the lining materials in the hot spots in electric are furnace in 1972. MgO-C brick is high registant to thermal and structural spalling. Futhermore for the reason that carbon is hard to react with slag and MgO is high fireproof MgO-C brick shows a high corrosion registance to slag attack compared with conventional basic refractories. Owing to their excellent properties the use of MgO-C refractories are being developed widely in the field of shaped refractories and even in that of monolithic refractories. In this paper the oxidation of carbon the infiltration of slag into the brick texture and effects of additions were investigated. The results obtained were as follows : 1) The use of fused MgO-clinker and high purity carbon as raw materials increased the corosion registance and hot modulus of rupture of MgO-C brick. 2) As the oxidation reaction of the carbon proceeded the slag infiltrated into the brick texture. And then the slag components reacted with the MgO grains and formed low melting point compounds particulary CaO.MgO.$SiO_2$ and 3CaO.MgO.$2SiO_2$ that resulted in the wear of the brick. 3) It is recongnized the Al, Si, $B_3C$ effects on the oxidation registant properties of MgO-C brick by contribu-ting to the decrease of permeability according to the formation of $Al_4C_3$, SiC, $B_2O_3$ and the decrease of open pores relating to the formation of MgO.Al2O3, $SiO_2$, 3MgO.$B_2O_3$ at the decarbonized layer.

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Temperature and magnetic field dependent optical properties of superconducting $MgB_2$ thin film (초전도 $MgB_2$ 박막의 온도와 장기장의 변화에 따른 광학적 성질)

  • Jung, J. H.;Lee, H. J.;Kim, K. W.;Kim, M. W.;Noh, T. W.;Wang, Y. J.;Kang, W. N.;Jung, C. U.;Lee, Sung-Ik
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.31-35
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    • 2001
  • We investigated the temperature and magnetic field dependent optical properties of a$ MgB_2$ thin film in the far-infrared region. In the superconducting state, i.e. 5 K, we obtained the values of superconducting gap $2\Delta$ ~ 5.2 meV and $2\Delta$ $_{k}$ $B/T_{c}$ ~1.8. Although the value of$ 2\Delta$$B/T_{c}$ was nearly half of the BCS value, the $2\Delta$ seemed to follow the temperature dependence of the BCS formula. Under the magnetic field (H), the superconducting state became suppressed. Interestingly, we found that the normal state area fraction abruptly increased at low field but slowly increased at high field. It did not follow the H-dependences predicted for a s-wave superconductor (i.e. a linear dependence) nor for a s-wave one (i.e. $H^{1}$2/ dependence). We discussed the complex gap nature of $MgB_2$ in comparison with two gap and anisotropic s-wave scenarios.ios.

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The growth of in-situ $MgB_2$ thin film by ESSD method (복합동시증착 방법을 이용한 In-situ $MgB_2$ 박막제조)

  • Song K.J.;Kim H.S.;Kim T.H.;Lee Y.S.;Ko R.K.;Ha H.S.;Ha D.W.;Oh S.S.;Moon S.H.;Park C.;Yoo S.I.
    • Progress in Superconductivity and Cryogenics
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    • v.8 no.3
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    • pp.18-22
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    • 2006
  • We obtained in-situ $MgB_2$ thin films in an one-step process using ESSD (Evaporation Sputtering Simultaneous Deposition) method. In our approach. the Ma evaporator is designed specially Mg and B are simultaneously evaporated and sputtered, respectively, in the specially designed ESSD chamber. The background pressure was less than $1{\times}10^{-6}$ Torr. The substrate temperature was kept at 623 K. The film properties were investigated by both electrical resistivity and PPMS. As a result, typical $T_c$ of films was 11 K.

Superconducting Properties of the Mg-Bi(Pb)SrCaCuO (110 K Phase) Composite System focusing on the Microstructure (Mg가 혼합된 Bi(Pb)SrCaCuO(110 K 상) 고온초전도체의 미세구조에 따른 초전도 특성 변화에 대한 연구)

  • 이정화;최봉수;이민수
    • Journal of the Korean Ceramic Society
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    • v.40 no.6
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    • pp.530-538
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    • 2003
  • Samples with the nominal composition, B $i_{1.84}$P $b_{0.34}$S $r_{1.91}$C $a_{2.03}$C $u_{3.06}$ $O_{10+}$$\delta$/ (110 K phase) high $T_{C}$ superconductors containing MgO as an additive were fabricated by a solid-state reaction method. Samples with 5~50 wt% MgO were sintered at 820~86$0^{\circ}C$ for 24 h. The structural characteristics, critical temperature and grain size of the samples with different MgO contents were analyzed by XRD and SEM. As the MgO content increased, the intensity of MgO peaks and ratio of Bi-2212 phase in superconductors were intensified and the proportion of the phase transition from Bi-2223 to Bi-2212 was increased.d.creased.d.