• 제목/요약/키워드: Mg-doped

검색결과 342건 처리시간 0.029초

Optimized Thermoelectric Properties in Zn-doped Zintl Phase Magnesium-Antimonide

  • Rahman, Md. Mahmudur;Ur, Soon-Chul
    • 한국재료학회지
    • /
    • 제32권6호
    • /
    • pp.287-292
    • /
    • 2022
  • Magnesium-antimonide is a well-known zintl phase thermoelectric material with low band gap energy, earth-abundance and characteristic electron-crystal phonon-glass properties. The nominal composition Mg3.8-xZnxSb2 (0.00 ≤ x ≤ 0.02) was synthesized by controlled melting and subsequent vacuum hot pressing method. To investigate phase development and surface morphology during the process, X-ray diffraction (XRD) and scanning electron microscopy (SEM) were carried out. It should be noted that an additional 16 at. % Mg must be added to the system to compensate for Mg loss during the melting process. This study evaluated the thermoelectric properties of the material in terms of Seebeck coefficient, electrical conductivity and thermal conductivity from the low to high temperature regime. The results demonstrated that substituting Zn at Mg sites increased electrical conductivity without significantly affecting the Seebeck coefficient. The maximal dimensionless figure of merit achieved was 0.30 for x = 0.01 at 855 K which is 30% greater than the intrinsic value. Electronic flow properties were also evaluated and discussed to explain the carrier transport mechanism involved in the thermoelectric properties of this alloy system.

$Zn_{0.5}Mg_{0.5}Te$$Zn_{0.5}Mg_{0.5}Te:Co$ 단결정 성장과 열역학 함수 추정 (Growth and Thermodynamic Function Properties of Undoped and Co-doped $Zn_{0.5}Mg_{0.5}Te$ Single Crystals)

  • 김용근
    • 한국진공학회지
    • /
    • 제3권2호
    • /
    • pp.198-202
    • /
    • 1994
  • Zn0.5Mg0.5Te 및 Zn0.5Mg0.5Te:Co 단결정을 온도진동법을 응용한 화학수송법으로 성장시켰고, 광 학적 energy gap의 온도의존성은 Varshni의형식에 잘 적용되었다. 광학적 energy gap의 온도의존성으 로부터 열역학 기본함수인 entropy, enthalpy, heat capacity를 구했다.

  • PDF

Nitrogen-doped carbon nanosheets from polyurethane foams and removal of Cr(VI)

  • Duan, Jiaqi;Zhang, Baohua;Fan, Huailin;Shen, Wenzhong;Qu, Shijie
    • Carbon letters
    • /
    • 제22권
    • /
    • pp.60-69
    • /
    • 2017
  • Nitrogen-doped carbon nanosheets with a developed porous structure were prepared from polyurethane foams by hydrothermal carbonization following $ZnCl_2$ chemical activation. Scanning electron microscopy, thermogravimetric analysis, Fourier transform infrared spectroscopy, solid state $^{13}C$ nuclear magnetic resonance (NMR) spectra and X-ray photoelectron spectroscopy were used to characterize the nitrogen-doped carbon nanosheet structure and composition. The removal of Cr(VI) by the N-doped carbon nanosheets was investigated. The results showed that the maximum removal capacity for chromium of 188 mg/g was found at pH=2.0 with PHC-Z-3. pH had an important effect on Cr(VI) removal and the optimal pH was 2.0. Moreover, amino groups and carboxyl groups in the nitrogen-doped carbon nanosheet played important roles in Cr(VI) removal, and promoted the reduction of Cr(VI) to Cr(III).

Enhanced Field Emission Behavior from Boron-Doped Double-walled Carbon Nanotubes Synthesized by Catalytic Chemical Vapor Deposition

  • Kang, J.H.;Jang, H.C.;Choi, J.M.;Lyu, S.C.;Sok, J.H.
    • Journal of Magnetics
    • /
    • 제17권1호
    • /
    • pp.9-12
    • /
    • 2012
  • Attempts to dope carbon nanotube (CNT) with impurities in order to control the electronic properties of the CNT is a natural course of action. Boron is known to improve both the structural and electronic properties. In this report, we study the field emission properties of Boron-doped double-walled CNT (DWCNT). Boron-doped DWCNT films were fabricated by catalytic decomposition of tetrahydrofuran and triisopropyl borate over a Fe-Mo/MgO catalyst at $900^{\circ}C$. We measured the field emission current by varying the doping amount of Boron from 0.8 to 1.8 wt%. As the amount of doped boron in the DWCNT increases, the turn-on-field of the DWCNT decreases drastically from 6 V/${\mu}m$ to 2 V/${\mu}m$. The current density of undoped CNT is 0.6 mA/$cm^2$ at 9 V, but a doped-DWCNT sample with 1.8 wt% achieved the same current density only at only 3.8 V. This shows that boron doped DWCNTs are potentially useful in low voltage operative field emitting device such as large area flat panel displays.

얇은막 산화철 광반도성 전극의 제조와 그 특성 (PREPARATION AND CHARACTERIZATION ON THIN FILMS OF DOPED IRON OXIDE PHOTOSEMICONDUCTIVE ELECTRODES.)

  • 김일광;김윤근;박태영;박춘배
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1993년도 춘계학술대회 논문집
    • /
    • pp.104-108
    • /
    • 1993
  • Thin films of MgO-doped and CaO-doped iron oxide were prepared y spray pyrolysis. The films were characterized b X-ray diffraction, scanning electron microscopy and voltammetric techniques. The photoelectrochemical behavior of thin film electrodes depended greatly on the doping level, sintering temperature, substrate temperature and added photosensitizing compounds in solution, showed p-type photoelectrochemical behavior, while the CaO-doped iron oxide thin films prepared at low temperature showed n-type photoelectrochemical behavior. This characteristic change was interpreted in terms of the surface structure change of the thin films and doping effect of metal oxide.

  • PDF

Improved stability of organic light-emitting diodes with lithium-quinolate doped electron transport layer

  • Choi, Sung-Hoon;Kim, Sang-Dae;Han, Kyu-Il;Lee, Se-Hee;Park, Eun-Jung;Kum, Tae-Il;Jung, Young-Kwan;Lee, Seok-Jong;Lee, Nam-Yang
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
    • /
    • pp.771-774
    • /
    • 2009
  • The Improved stability of organic light emitting diodes (OLEDs) containing lithium-quinolate (Liq) as the ETL doping material is investigated. The lifetime could be improved by threefold using the Liq-doped ETL structure. The improvement was attributed to the Liq-doped ETL, which improved hole-electron balance and has a good electrical stability. Additionally, when the Liq doped device was combined with an Mg/Al cathode, the OLED produced a longer lifetime than other device.

  • PDF

μ-PD법을 이용하여 성장시킨 Er2O3와 MgO를 첨가한 화학양론조성 LiNbO3 단결정의 Up-conversion 특성 (Up-conversion Property of Er2O3 and MgO Co-doped Stoichiometric LiNbO3 Single Crystal by Using the μ-PD Method)

  • 서중원;전원남;이성문;양우석;이한영;윤대호
    • 한국세라믹학회지
    • /
    • 제39권9호
    • /
    • pp.835-839
    • /
    • 2002
  • Micro-Pulling Down(${\mu}$-PD)법을 이용하여 직경 1 mm, 길이 30∼35 mm의 $Er_2O_3$와 MgO가 첨가된 화학양론조성 $LiNbO_3$단결정을 성장하였다. 성장된 결정의 $Er_2O_3$와 MgO 첨가에 따른 up-conversion 특성의 변화 및 MgO 첨가량이 광손상에 미치는 영향을 관찰하기 위해 투과율을 측정하였다. 또한 $LiNbO_3$ 단결정 내의 결함유무를 광학현미경을 이용하여 관찰하였고, Electron Probe Micro Analysis(EPMA)를 이용하여 결정 내에 $Er_2O_3$와 MgO가 균일하게 분포되어있음을 확인하였다.