• Title/Summary/Keyword: Mg electrode

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A STUDY ON THE FLUORIDE CONTENT OF THE COMMERCIALLY AVAILABLE BEVERAGES AND THE FLUORIDE INTAKE OF CHILDREN (시판되는 각종 음료수내 불소 함량과 소아의 불소섭취에 관한 연구)

  • Lee, Mi-Na;Lee, Sang-Hoon;Kim, Chong-Chul
    • Journal of the korean academy of Pediatric Dentistry
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    • v.24 no.1
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    • pp.125-138
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    • 1997
  • Along with recent economic prosperity, the consumption of commercially available beverages has increased dramatically. Beverages on the market are replacing tap water and constituting an increasing large proportion of the total daily fluoride intake. If such changes in the source of fluid intake are not taken into consideration, effective fluoride intake would become difficult in the fluoridated area while there would be confusion as to the basis for proper fluoride supplement prescription in the nonfluoridated area. So, dietary consultation is recommended for every pediatric patient. This study was conducted to provide the reference for dietary consultations on the subject of fluoride supplement using 72 beverages on the market. The fluoride content was measured and the fluoride intake from each age groups was calculated using fluoride ion specific electrode and HMDS-microdiffusion technique. 1. The average fluoride concentration of the 72 beverages was $0.23{\pm}0.10ppm$, from 0.0106ppm to 2.2050ppm. 2. Natural fruit juices, diluted fruit juices, carbonated beverages and mixed beverages showed average fluoride concentration of $0.15{\pm}0.66ppm$, $0.09{\pm}0.11ppm$, $0.15{\pm}0.23ppm$, $0.50{\pm}0.66ppm$, respectively. There were significant differrence between diluted friut juice drinks and mixed beverage, and between the carbonated beverages and mixed beverges(p<0.05). 3. Using available data on the daily total consumption of beverages and the relative consumption of beverages on the market according to age, daily fluoride intake for various age groups was calculated. According to the results, 2 to 3 year-old children need 0.13mgF/day, those between 4 and 6 year-old need 0.15mgF/day, and those between 7 and 10 year-old need 0.17mgF/day.

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Novel Silver(I) Ion Selective PVC Membrane Electrode Based on the Schiff Base (N2E,N2'E)-N2,N2'-Bis(Thiophen-2-ylmethylene)-1,1'-Binaphthyl-2,2'-Diamine

  • Jeong, Eunseon;Ahmed, Mohammad Shamsuddin;Jeong, Hae-Sang;Lee, Eun-Hee;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.800-804
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    • 2011
  • A potentiometric sensor based on the Schiff base $(N^2E,N^{2'}E)-N^2,N^{2'}$-bis(thiophen-2-ylmethylene)-1,1'-binaphthl-2,2'-diamine has been synthesized and explored as an ionophore PVC-based membrane sensor selective for the silver ($Ag^+$) ion. Potentiometric investigations indicate a high affinity of this receptor for the silver ion. Seven membranes have been fabricated with different compositions, with the best performance shown by the membrane with an ionophore composition (w/w) of: 1.0 mg, PVC: 33.0 mg, DOA: 66.0 mg in 1.0 mL THF. The sensor worked well within a wide concentration range of $1.0{\times}10^{-2}$ to $1.0{\times}10^{-7}$ M, at pH 5, at room temperature (slope 57.4 mV/dec.), and with a rapid response time of 9 s; the sensor also showed good selectivity towards the silver ion over a huge number of interfering cations, with the highest selectivity coefficient for $Hg^{2+}$ at -3.7. Thus far, the best lower detection limit was $4.0{\times}10^{-8}$ M.

Effect of Li2O-Bi2O3 Addition on the Piezoelectric Properties of Pb(Mg1/3Nb2/3)0.65Ti0.35O3 Ceramics (Li2O-Bi2O3 첨가가 Pb(Mg1/3Nb2/3)0.65Ti0.35O3 세라믹의 압전 특성에 미치는 영향)

  • Kim, Jae Hyuk;Kim, Shi Yeon;Choi, Jeoung Sik;Yeo, Dong-Hun;Shin, Hyo-Soon;Nahm, Sahn
    • Journal of Powder Materials
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    • v.26 no.5
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    • pp.405-409
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    • 2019
  • Piezoelectric ceramic specimens with the $Pb(Mg_{1/3}Nb_{2/3})_{0.65}Ti_{0.35}O_3$ (PMN-PT) composition are prepared by the solid state reaction method known as the "columbite precursor" method. Moreover, the effects of the $Li_2O-Bi_2O_3$ additive on the microstructure, crystal structure, and piezoelectric properties of sintered PMN-PT ceramic samples are investigated. The addition of $Li_2O-Bi_2O_3$ lowers the sintering temperature from $1,200^{\circ}C$ to $950^{\circ}C$. Moreover, with the addition of >5 wt.% additive, the crystal structure changes from tetragonal to rhombohedral. Notably, the sample with 3 wt.% additive exhibits excellent piezoelectric properties ($d_{33}=596pC/N$ and Kp = 57%) and a sintered density of $7.92g/cm^3$ after sintering at $950^{\circ}C$. In addition, the sample exhibits a curie temperature of $138.6^{\circ}C$ at 1 kHz. Finally, the compatibility of the sample with a Cu electrode is examined, because the energy-dispersive X-ray spectroscopy data indicate the absence of interdiffusion between Cu and the ceramic material.

A Particulate Matter Sensor with Groove Electrode for Real-Time Diesel Engine On-Board Diagnostics

  • Kim, S.;Kim, Y.;Lee, J.;Lim, S.;Min, K.;Chun, K.
    • Journal of Sensor Science and Technology
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    • v.22 no.3
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    • pp.191-196
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    • 2013
  • A particulate matter sensor fabricated by MEMS process is proposed. It is developed to accommodate Euro6 on-board diagnostics regulation for diesel automobile. In the regulation, emission of diesel particulate matter is restricted to 9 mg/km. Particulate matter sensor is designed to use induced charges by charged particulate matter. To increase sensitivity of the sensor, groove is formed on sensor surface because wider surface area generates more induced charges. Sensitivity of the sensor is measured 10.6 mV/(mg/km) and the sensor shows good linearity up to 15.7 mg/km. Also its minimum detectable range is about 0.25 mg/km. It is suitable to detect failure of a diesel particulate filter which should filter particulate matter more than 9 mg/km. For removing accumulated particulate matter on the sensor which can disturb normal operation, platinum heater is designed on the backside of the sensor. The developed sensor can sense very low amount of particulate matter from exhaust gas in real-time with good linearity.

Sintering Property of Ti-Te LTCC Materials with SnO Additions (SnO 첨가에 따른 Ti-Te LTCC 재료의 소결 특성)

  • Kim, Jae-Sik;Choi, Eui-Sun;Ryu, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2008.10a
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    • pp.169-170
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    • 2008
  • In this study, low temperature sintering property of the $0.6TiTe_3O_8-0.4MgTiO_3$ ceramics with sintering adds were investigated for LTCC application which enable to cofiring with Ag electrode. $TiTe_3O_8$ mixed with $MgTiO_3$ to improve the temperature property. In the X-ray diffraction patterns, the columbite structure of $TiTe_3O_8$ phase and ilmenite structure of $MgTiO_3$ phase were coexisted in all specimens. In the case of SnO addition, the bulk density and dielectric constant were increased but quality factor was decreased with amount of SnO additions. The TCRF of the $0.6TiTe_3O_8-0.4MgTiO_3$+xwt%SnO ceramics were shifted to negative direction. The dielectric constant, quality factor and TCRF of the $0.6TiTe_3O_8-0.4MgTiO_3$ ceramics with 2.5wt% addition of SnO sintered at $830^{\circ}C$ for 1hr were 29.86, 35,800 GHz, -0.58 ppm/$^{\circ}C$, respectively.

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Performance Analysis of The Direct Formic Acid Fuel Cell using A New Catalysis Coating Method (새로운 촉매 코팅법을 이용한 직접 개미산 연료전지의 성능 분석)

  • Kwon, Y.;Kwon, B.;Kim, J.;Kim, Y.Y.;Jung, W.;Han, J.
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.29-32
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    • 2008
  • The cell performance of direct formic acid fuel cell (DFAFC) having catalysts coated by electrospray was analyzed. Pd catalyst was used for the anode electrode and Pd catalyst loading amount and formic acid feed rate dependances of fuel cell performance were evaluated. When loading amount of Pd is in between 3mg/$cm^2$ and 7mg/$cm^2$ and formic acid feed rate is 5ml/min., 3mg/$cm^2$ sample showed better potential at 129 mA/$cm^2$ and power density due to difference in mass transfer limitation. However, when the feed rate is greater than 10ml/min., the opposite tendency was observed between 3mg/$cm^2$ and 7mg/$cm^2$ samples. The result was attributed to improvement in electrochemical reaction of the Pd. Based on the above results, In DFAFC including Pd catalyst that was coated by electrospray, 0.537V as the maximum potential at 129 mA/$cm^2$ was attained.

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Electrochemical Studies on the Methylviologen-Sodium Dodecyl Sulfate Solution in the Presence of $MgCl_2$ (염화마그네슘 존재하의 메틸비올로겐-도데실황산나트륨 용액의 전기화학적 연구)

  • Ko, Young Chun;Chung, Keun Ho
    • Analytical Science and Technology
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    • v.11 no.3
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    • pp.151-155
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    • 1998
  • Electrochemical behaviours on 1.0 mM methylviologen ($MV^{2+}$) in 100 mM NaCl+27 mM $MgCl_2$ solution, without and with sodium dodecyl sulfate (SDS), were studied. The intersection of two lines on ${\Delta}E_p$ (the difference between the anodic, $E_{pa}$, and the cathodic, $E_{pc}$, peak potentials) of the first and second redox waves vs. -log[SDS] plot was determined as a critical micelle concentration (CMC). When $Mg^{2+}$ was added, the effective access of $MV{\cdot}^+$ to the glassy carbon electrode surface became possible and the formation of micelles was retarded.

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Effect of Ti Adhesion Layer on the Electrical Properties of BMNO Capacitor Using Graphene Bottom Electrodes (그래핀 하부전극을 이용하여 BMNO 케페시터의 특성 향상을 위한 Ti Adhesion Layer의 효과)

  • Park, Byeong-Ju;Yoon, Soon-Gil
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.12
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    • pp.867-871
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    • 2013
  • The Ti adhesion layers were deposited onto the glass substrate for transparent capacitors using $Bi_2Mg_{2/3}Nb_{4/3}O_7$ (BMNO) dielectric thin films. Graphene was transferred onto the Ti/glass substrate after growing onto the Ni/$SiO_2$/Si using rapid-thermal pulse CVD (RTPCVD). The BMNO dielectric thin films were investigated for the microstructure, dielectric and leakage properties in the case of capacitors with and without Ti adhesion layers. Leakage current and dielectric properties were strongly dependent on the Ti adhesion layers grown for graphene bottom electrode.

Application of a. Strip Ion-Selective Electrode Sensor for Hydroponic Nutrient Solution Analysis - NO3 Analysis - (양액의 영양분 분석을 위한 Strip형 이온선택성전극 센서 의 응용 -NO3 이온 분석 -)

  • 김기영
    • Journal of Biosystems Engineering
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    • v.28 no.4
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    • pp.335-342
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    • 2003
  • A simple disposable thick-film potentiometric strip has been developed and evaluated for hydroponics application. The strip consisted of low ion-selective electrodes (ISE) fabricated by screen-printing technology. The electrochemical responses of ion sensors for nitrate, ammonium, potassium, and magnesium were measured with specially designed 16-channel low voltage signal transducers. The analytical characteristics of the sensors were comparable with those of conventional ISE sensors. The thick-film sensors exhibit linear relationships over five concentration decades. The concentration of N $O_3$ - ion in standard solution can be determined by direct potentiometric measurements without any conditioning before measurements. However, measurement of $K^{+}$, N $H_4$$^{+}$, and $Mg^{2+}$ ionic concentrations in nutrient solutions seems not feasible.

Effects of Electrolyte Concentration and Relative Cathode Electrode Area Sizes in Titania Film Formation by Micro-Arc Oxidation

  • Lee, Yong-K.;Lee, Kang-Soo
    • Corrosion Science and Technology
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    • v.9 no.4
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    • pp.171-174
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    • 2010
  • MAO (micro-arc oxidation) is an eco-friendly convenient and effective technology to deposit high-quality oxide coatings on the surfaces of Ti, Al, Mg and their alloys. The roles of the electrolyte concentration and relative cathode electrode area sizes in the grown oxide film during titanium MAO were investigated. The higher the concentration of the electrolyte, the lower the $R_{total}A$ value. The oxide film produced by the lower concentration of the electrolyte is thinner and less uniform than the film by the higher concentration, which is thick and porous. The cathode area size must be bigger than the anode area size in order to minimize the voltage drop across the cathode. The ratio of the cathode area size to the anode area size must be bigger than 8. Otherwise, the cathode will be another source for voltage drop, which is detrimental to and slows down the oxide growth.