• Title/Summary/Keyword: Methane precursor

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In vivo Methane Production from Formic and Acetic Acids in the Gastrointestinal Tract of White Roman Geese

  • Chen, Yieng-How;Wang, Shu-Yin;Hsu, Jenn-Chung
    • Asian-Australasian Journal of Animal Sciences
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    • v.22 no.7
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    • pp.1043-1047
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    • 2009
  • Three experiments were conducted to determine the conversion rate of formic and acetic acids into methane in the gastrointestinal tracts of geese. In experiment I, two sets of two 4-month-old male White Roman geese were allocated to one of two treatment groups. Each set of geese was inoculated either with formic acid or with phosphate buffer solution (PBS). After the acid or the PBS was inoculated into the esophagi of the geese, two birds from each treatment were placed in a respiratory chamber as a measurement unit for 4 h in order to determine methane production rate. In experiment II and III, 6- and 7-wk-old male White Roman goslings were used, respectively. Birds were allocated to receive either formic acid or PBS solution injected into the ceca in experiment II. Acetic acid or PBS solution injected into the cecum were used for experiment III. After either the acids or the PBS solution were injected into the cecum, two birds from each treatment were placed in a respiratory chamber as a measurement unit for 3 h; each treatment was repeated 3 times. The results indicated that formic acid inoculated into the oesophagi of geese was quickly converted into methane. Compared with the PBS-injected group, methane production increased by 5.02 times in the formic acid injected group (4.32 vs. 0.86 mg/kg BW/d; p<0.05). Acetic acid injected into the ceca did not increase methane production; conversely, it tended to decrease methane production. The present study suggests that formic acid may be converted to methane in the ceca, and that acetic acid may not be a precursor of methane in the ceca of geese.

Formation of SiC layer on Single Crystal Si Using Hot-Filament Reactor

  • Kim, Hong-Suk;Park, In-Hoon;Eun, Kwang-Yong;Baik, Young-Joon
    • The Korean Journal of Ceramics
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    • v.4 no.1
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    • pp.25-27
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    • 1998
  • The effect of gas activation on the formation of SiC layer on Si substrate using methane as a carbon source was investigated. Tungsten filaments, heated above 200$0^{\circ}C$, were used to activate the methane-hydrogen mixed gas. The dissociation of methane gas by the heated filament was enough to form a SiC layer successfully, which was very difficult without any activation. The SiC layer formed on the Si substrate was crystalline and nearly epitaxial as measured by X-ray diffraction. The SiC layer formed on the Si substrate was crystalline and nearly epitaxial as measured by X-ray diffraction. The stoichiometry was also close to 1:1. However, the characteristic of the SiC layer was dependent on the heat-treatment condition. The general behavior of the layer growth with the variables was discussed.

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Various Shape of Carbon Layer on Ga2O3 Thin Film by Controlling Methane Fraction in Radio Frequency Plasma Chemical Vapor Deposition (Ga2O3박막 상에서의 RF 플라즈마 화학기상증착법의 메테인 분율 조절에 의한 탄소층의 다양한 형상 제어 연구)

  • Seo, Ji-Yeon;Shin, Yun-Ji;Jeong, Seong-Min;Kim, Tae-Gyu;Bae, Si-Young
    • Journal of the Korean Society for Heat Treatment
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    • v.35 no.2
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    • pp.51-56
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    • 2022
  • In this study, we controlled the shape of a carbon layer on gallium oxide templates. Gallium oxide layers were deposited on sapphire substrates using mist chemical vapor deposition. Subsequently, carbon layers were formed using radio frequency plasma chemical vapor deposition. Various shapes of carbon structures appeared according to the fraction of methane gas, used as a precursor. As methane gas concentration was adjusted from 1 to 100%, The shapes of carbon structures varied to diamonds, nanowalls, and spheres. The growth of carbon isotope structures on Ga2O3 templates will give rise to improving the electrical and thermal properties in the next-generation electronic applications.

Synthesis of thin-multiwalled carbon nanotubes by Fe-Mo/MgO catalyst using sol-gel method

  • Dubey, Prashant;Choi, Sang-Kyu;Kim, Bawl;Lee, Cheol-Jin
    • Carbon letters
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    • v.13 no.2
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    • pp.99-108
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    • 2012
  • The sol-gel technique has been studied to fabricate a homogeneous Fe-Mo/MgO catalyst. Ambient effects (air, Ar, and $H_2$) on thermal decomposition of the citrate precursor have been systematically investigated to fabricate an Fe-Mo/MgO catalyst. Severe agglomeration of metal catalyst was observed under thermal decomposition of citrate precursor in air atmosphere. Ar/$H_2$ atmosphere effectively restricted agglomeration of bimetallic catalyst and formation of highly-dispersed Fe-Mo/MgO catalyst with high specific surface-area due to the formation of Fe-Mo nanoclusters within MgO support. High-quality thin-multiwalled carbon nanotubes (t-MWCNTs) with uniform diameters were achieved on a large scale by catalytic decomposition of methane over Fe-Mo/MgO catalyst prepared under Ar-atmosphere. The produced t-MWCNTs had outer diameters in the range of 4-8 nm (average diameter ~6.6 nm) and wall numbers in the range of 4-7 graphenes. The as-synthesized t-MWCNTs showed product yields over 450% relative to the utilized Fe-Mo/MgO catalyst, and indicated a purity of about 85%.

Graphene Growth with Solid Precursor-Polyethylene (고체 전구체-폴리에틸렌을 이용한 그래핀 성장)

  • Ryu, Jongseong;An, Sung Jin
    • Korean Journal of Materials Research
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    • v.29 no.5
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    • pp.304-310
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    • 2019
  • Chemical vapor deposition method using $CH_4$ gaseous hydrocarbons is generally used to synthesize large-area graphene. Studies using non-gaseous materials such as ethanol, hexane and camphor have occasionally been conducted. In this study, large-area graphene is synthesized via chemical vapor deposition using polyethylene as a carbon precursor. In particular, we used a poly glove, which is made of low-density polyethylene. The characteristics of the synthesized graphene as functions of the growth time of graphene and the temperature for vaporizing polyethylene are evaluated by optical microscopy and Raman spectroscopy. When the polyethylene vaporizing temperature is over $150^{\circ}C$, large-area graphene with excellent quality is synthesized. Raman spectroscopy shows that the D peak intensity increased and the 2D peak intensity decreased with increasing growth time. The reason for this is that sp3 bonds in the graphene can form when the correct amount of carbon source is supplied. The quality of the graphene synthesized using polyethylene is similar to that of graphene synthesized using methane gas.

Morphology of Carbon Nanotubes Prepared by Methane Plasma CVD (메탄 플라즈마 CVD법으로 합성한 탄소나노튜브의 구조적 특성)

  • Kim, Myung-Chan;Moon, Seung-Hwan;Lim, Jae-Seok;Hahm, Hyun-Sik;Park, Hong-Soo;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.4
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    • pp.289-299
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    • 2004
  • Multi-walled carbon nanotubes (CNTs) were prepared by microwave plasma chemical vapor deposition (MPCVD) using various combination of binary catalysts and methane precursor. The maximum yield (10.3 %) of CNTs was obtained using a methane-hydrogen-nitrogen mixture with volume ratio of 1:1:2 at 1000 W of microwave power. As the microwave power increased up to 1000 W, the deposition yield of CNTs raised from 4.1 % to 10. 3 %. However, the prepared CNTs at 800 W showed the more crystalline structure than those prepared at 1000 W. The prepared CNTs over different binary catalysts had various structural conformations such as aligned cylinder, bamboo, and nanofibers. The Id/Ig value of CNTs over$Fe-Fe/Al_2O_3, $Co-Co/Al_2O_3, and $Co-Cu/Al_2O_3 were in the range of 0.89${\sim}$0.93. Among the various binary catalysts used, $Fe-Co./Al_2O_3 showed the highest yield.

Electrostatic Charging and Substrate Seeding in Gas Phase Synthesis of Nanocrystalline Diamond Powder

  • Cho, Jung-Min;Lee, Hak-Joo;Choi, Heon-Jin;Lee, Wook-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.418-418
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    • 2012
  • Synthesis of nanocrystalline diamond powder was investigated via a gas-to-particle scheme using the hot filament chemical vapor deposition. Effect of substrate surface seeding by nano diamond powder, and that of the electrical conductance of the substrate were studied. The substrate temperature, methane content in the precursor gas, filament-substrate distance and filament temperature were $670^{\circ}C$, 5% methane in hydrogen, 10 mm and $2400^{\circ}C$, respectively. The powder formation by gas-to-particle mechanism were greatly enhanced by the substrate seeding by the nano diamond powder. It was attributed to the removal of the electrostatic force between the substrate and the seeded nano diamond particle by the thermal electron shower from the hot filament, via the depolarization of the substrate surface or the attached diamond powder and subsequent levitation into the gas phase to serve as the gas-phase nucleation site. The powder formation was greatly favoured by the conducting substrate relative to the insulating substrate, which proved the actual effect of the electric static force in the powder formation.

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Tomographic Interpretations of Visible Emissions from the Axisymmetric Partially Premixed Flames (단층진단법을 이용한 축대칭 부분예혼합 화염의 자발광 스펙트럼 해석에 관한 연구)

  • Ha, Kwang-Soon;Choi, Sang-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.6
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    • pp.769-776
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    • 2000
  • Visible spectral characteristics of cross-sectional emissions from a partially premixed methane/air and propane/air flames have been investigated. An optical train with a two-axis scanning mirror system was used to record line-of-sight emission spectra from 354nm to 618nm, and inversion technique was adapted to obtain cross-sectional emission spectra. By analyzing the reconstructed emission spectra, cross-sectional intensities of CH and $C_2$ radicals were separated from the background emissions. The blue flame edge and yellow flame edge were also obtained by image processing technique for edge detection with color photograph of flame. These edges were compared with radial distributions of CH, $C_2$ radicals and background emissions. The CH radicals were observed at blue flame edge. The background emissions were generated by soot precursor at upstream of flame and by soot at downstream of flame. The $C_2$ radicals in propane/air flame were observed more than those in methane/air flame.

Carbon molecular sieves from soybean straw-based activated carbon for CO2/CH4 separation

  • Xu, Yuxian;Chen, Xiaochuan;Wu, Dan;Luo, Yongjin;Liu, Xinping;Qian, Qingrong;Xiao, Liren;Chen, Qinghua
    • Carbon letters
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    • v.25
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    • pp.68-77
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    • 2018
  • Soybean straw (SS)-based activated carbon was employed as a precursor to prepare carbon molecular sieves (CMSs) via chemical vapor deposition (CVD) technique using methane as carbon source. Prior to the CVD process, SS was activated by 0.5 wt% $ZnCl_2$, followed by a carbonization at $500^{\circ}C$ for 1 h in $N_2$ atmosphere. $N_2$ (77 K) adsorption-desorption and $CO_2$ (273 K) adsorption tests were carried out to analyze the pore structure of the prepared CMSs. The results show that increasing the deposition temperature, time or methane flow rate leads the decrease in $N_2$ adsorption capacity, micropore volume and average pore diameter of CMSs. The adsorption selectivity coefficient of $CO_2/CH_4$ achieves as high as 20.8 over CMSs obtained under the methane flow rate of $30mL\;min^{-1}$ at $800^{\circ}C$ for 70 min. The study demonstrates the prepared CMSs are a candidate adsorbent for $CO_2/CH_4$ separation.

Synthesis of Vertically Aligned SiNW/Carbon Core-shell Nanostructures

  • Kim, Jun-Hui;Kim, Min-Su;Kim, Dong-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.488.2-488.2
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    • 2014
  • Carbon-based materials such as carbon nanotubes and graphene have emerged as promising building blocks in applications for nanoelectronics and energy devices due to electrical property, ease of processability, and relatively inert electrochemistry. In recent years, there has been considerable interest in core-shell nanomaterials, in which inorganic nanowires are surrounded by inorganic or organic layers. Especially, carbon encapsulated semiconductor nanowires have been actively investigated by researchers in lithium ion batteries. We report a method to synthesize silicon nanowire (SiNW) core/carbon shell structures by chemical vapor deposition (CVD), using methane (CH4) as a precursor at growth temperature of $1000{\sim}1100^{\circ}C$. Unlike carbon-based materials synthesized via conventional routes, this method is of advantage of metal-catalyst free growth. We characterized these materials with FE-SEM, FE-TEM, and Raman spectroscopy. This would allow us to use these materials for applications ranging from optoelectronics to energy devices such as solar cells and lithium ion batteries.

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