• Membrane Journal
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• v.21 no.2
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• pp.148-154
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• 2011

Metal-ceramic composite membrane have been developed to separate hydrogen from mixed gases, particularly product streams generated during coal gasification and methane reforming. Cermet membrane was fabricated with palladium as hydrogen-permeable metal and $Y_2O_3$-stabilized $ZrO_2$ (YSZ) as ceramic supporter. As-prepared membrane showed dense structure with continuous channel of palladium. The hydrogen flux of Pd/YSZ membrane have been measured in the range of 0.5~2 atm with 100% hydrogen gas. The results indicate that the hydrogen flux was 0.333 mL/$min{\cdot}cm^2$ at $450^{\circ}C$ and 2 atm. The crack was formed in the surface and cross-section of membrane.

• Korean Journal of Agricultural and Forest Meteorology
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• v.23 no.4
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• pp.235-250
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• 2021

The overarching question of this study is how a typical rice cultivation system in Gimje, Korea was keeping up with the triple-win challenge of climate-smart agriculture (CSA). To answer this question, we have employed (1) quantitative data from direct measurement of energy, water, carbon and information flows in and out of a rice cultivation system and (2) appropriate metrics to assess production, efficiency, GHG fluxes, and resilience. The study site was one of the Korean Network of Flux measurement (KoFlux) sites (i.e., GRK) located at Gimje, Korea, managed by National Academy of Agricultural Science, Rural Development Administration. Fluxes of energy, water, carbon dioxide (CO₂) and methane (CH₄) were directly measured using eddy-covariance technique during the growing seasons of 2011, 2012 and 2014. The production indicators include gross primary productivity (GPP), grain yield, light use efficiency (LUE), water use efficiency (WUE), and carbon uptake efficiency (CUE). The GHG mitigation was assessed with indicators such as fluxes of carbon dioxide (F_CO2), methane (F_CH4), and nitrous oxide (F_N2O). Resilience was assessed in terms of self-organization (S), using information-theoretic approach. Overall, the results demonstrated that the rice cultivation system at GRK was climate-smart in 2011 in a relative sense but failed to maintain in the following years. Resilience was high and changed little for three year. However, the apparent competing goals or trade-offs between productivity and GHG mitigation were found within individual years as well as between the years, causing difficulties in achieving the triple-win scenario. The pursuit of CSA requires for stakeholders to prioritize their goals (i.e., governance) and to practice opportune interventions (i.e., management) based on the feedback from real-time assessment of the CSA indicators (i.e., monitoring) - i.e., a purpose-driven visioneering.

• Journal of ILASS-Korea
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• v.25 no.3
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• pp.95-102
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• 2020

Six shear coaxial injectors for a 3 tonf-class liquid rocket engine using oxygen and methane as propellants were designed and manufactured by considering geometric design parameters such as a recess length and a taper angle. Cold-flow tests on the injectors were performed using water and air as simulants. By changing the water mass flow rate and air mass flow rate, the injection pressure drop under single-injection and bi-injection was measured. The discharge coefficients through the injector oxidizer-side and fuel-side were calculated and the discharge coefficient ratio between bi-injection and single-injection was obtained. Under single-injection, the recess served to reduce the injection pressure drop on the injector fuel-side. For the injectors without recess, the discharge coefficients under bi-injection were almost the same as those under single-injection. However, for the injectors with recess, the taper angle and bi-injection had a significant effect on the discharge coefficient.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.255-258
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• 2002

Liquid rocket engines using liquefied natural gas (LNG) or methane as a fuel is known to have several good characteristics, such as high specific impulse compared to other hydrocarbon fuels, environment-friendly exhaust gas, low production cost, and re-usability with low soot generation in the cooling channel. In this study, experimental combustion chambers capable of using LNC and $CH_{4}$ are being researched through experimental firing tests, and within easy range of eyes' inspection, there are the periodical existence of soot or discoloration in the chamber wall surface. This result means that mixture ratio of oxidizer and fuel fluctuates periodically between outer-row injectors in the mixing head in the circumferential direction. Therefore, based on this phenomenon, the variation of mixture ratio near the chamber wall caused by the spill pattern of a shear coaxial injector was analyzed quantitatively and the thermal heat flux Into the cooling channel is modified. Then, the calculated and modified results are compared with the measured ones.

• Analytical Science and Technology
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• v.16 no.5
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• pp.407-417
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• 2003

In this study, we measured the concentration of VOCs in ambient air and landfill gas (LFG) in a midsize municipal landfill site. The LFG flux values of VOCs were computed using a total of fifteen VOCs determined by GC-PID system. To understand relative contribution of these 15 VOCs to the total carbon budget, their concentration and flux estimates were compared to those of non-methane hydrocarbons (NMHC) measured concurrently. It was also found that there were systematic differences in absolute VOC concentration levels between LFG and air samples above landfill surface. The VOC concentrations in LFG samples were high enough to reach above a few tens of ppm that are 10 to 100 times higher than those in air above landfill surface. If the LFG flux values were computed using the LFG concentration data of 15 VOCs and NMHC with exit ventilation speed, the magnitude of emissions in the study area is estimated to be 8.6 and 103 ton C/yr, respectively. In the meantime, large fraction of those speciated VOC emissions is accounted for by BTEX.

• Membrane Journal
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• v.21 no.2
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• pp.177-192
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• 2011

Hollow fiber membrane using CTA polymers were prepared by the phase separation method for the separation and purification of biogas and the hollow fiber gas separation membrane modules with the effective surface area of 0.17 $m^2$ were prepared. The pure gas permeation properties of membrane modules for methane, oxygen and carbon dioxide were measured. The permeance of $CO_2$ and $CH_4$were 0.46 GPU and 18.52 GPU, respectively, therefore, the high $CO_2$/$CH_4$ selectivity of 40.4 was obtained. The separation and purification test for 4 different simulated mixed gases were carried out after the pure gas test and the gas concentration and flux of the permeate at the various stage-cut were measured from the 1 stage, 2 stage, and 3 stage cascade of membrane modules. In the 1 stage test, the concentration of $CH_4$ increased as the increase of the stage-cut, while the $CH_4$ recovery efficiency ratio decreased. In the 2 stage test, the $CH_4$ recovery efficiency ratio increased compared to the 1 stage. The 3 stage test was employed to reduce the loss of $CH_4$ in biogas and the result showed less than 5% of $CH_4$ recovery loss.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.3
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• pp.523-533
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• 2000

A two-phase anaerobic reactor with submerged membrane system was developed for increasing acidogen concentration and methane recovery. The membrane used was mixed esters of cellulose of $0.5{\mu}m$ pore size and $0.8m^2$ of effective surface area. The methanogenic reactor comprised of UASB (Upflow Anaerobic Sludge Blanket) and AF (Anaerobic Filter). COD removal efficiency was 70~80% and the methane content in the biogas increased up to 90% for the submerged membrane system in the anaerobic reactor. As the cake resistance of membrane caused a serious problem, stainless steal prefilters (40, 53, $63{\mu}m$) and air backwashing methods were applied to minimize the cake resistance effectively. Among the tested prefilters. the $63{\mu}m$ prefilter showed the best performance for reduction of cake resistance and a successful long-tern operation. By cleaning with alkali first and acidic solution later. the permeate flux decreased by long term operation was recovered to 89% of that with a new membrane.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.23 no.1
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• pp.32-48
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• 2018

The mechanisms of $CH_4$ uptake into and release from the ocean are not well understood due mainly to complexity of the biogeochemical cycle and to lack of regional-scale and/or process-scale observations in the marine boundary layers. Without complete understanding of oceanic mechanisms to control the carbon balance and cycles on a various spatial and temporal scales, however, it is difficult to predict future perturbation of oceanic carbon levels and its influence on the global and regional climates. High frequency, high precision continuous measurements for carbon isotopic compositions from dissolved $CH_4$ in the surface ocean and marine atmosphere can provide additional information about the flux pathways and production/consumption processes occurring in the boundary of two large reservoirs. This paper introduces recent advances on optical instruments for real time $CH_4$ isotope analysis to diagnose potential applications for in situ, continuous measurements of carbon isotopic composition of dissolved $CH_4$. Commercially available, three laser absorption spectrometers - quantum cascade laser spectroscopy (QCLAS), off-axis integrated cavity output spectrometer (OA-ICOS), and cavity ring-down spectrometer (CRDS) are discussed in comparison with the conventional isotope ratio mass spectrometry (IRMS). Details of functioning and performance of a CRDS isotope instrument for atmospheric ${\delta}^{13}C-CH_4$ are also given, showing its capability to detect localized methane emission sources.

• Korean Journal of Agricultural and Forest Meteorology
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• v.18 no.4
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• pp.337-347
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• 2016

Carbon dioxide ($CO_2$) and methane ($CH_4$) were measured in a rice-barley double cropping and rice mono cropping paddy fields, which are located in the southwestern coast of Korea, over a one-year period. Net ecosystems $CO_2$ exchange (NEE) and ecosystem respiration (Re) were estimated by the eddy covariance (EC) method, and an automatic open/close chamber (AOCC) method was used to measure $CH_4$ fluxes. Environmental factors (solar radiation, air temperature, precipitation etc.) were also measured along with fluxes. After the quality control and gap-filling, the observed fluxes were analyzed. As a result, NEE was -603.0 and $-471.5g\;C\;m^{-2}\;yr^{-1}$ in rice-barley double cropping and rice mono cropping paddy field, respectively. $CH_4$ emissions increased during the course of flooded days and were similar in two cropping paddy field. Accoding to rough results considering only fluxes of $CO_2$ and $CH_4$, it was estimated that the carbon absorbation in rice-barley double cropping paddy field was higher than that in rice mono cropping paddy field by $128.9g\;C\;m^{-2}\;yr^{-1}$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.4
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• pp.425-430
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• 2012

In this study, a preconverter of an MCFC for an emergency electric power supplier is numerically simulated to increase the hydrogen production from natural gas (methane). A commercial code is used to simulate a porous catalyst with a user subroutine to model three dominant chemical reactions-steam reforming, water-gas shift, and direct steam reforming. To achieve a fuel conversion rate of 10% in the preconverter, the required external heat flux is supplied from the outer wall of the preconverter. The calculated results show that the temperature distribution and chemical reaction are extremely nonuniform near the wall of the preconverter. These phenomena can be explained by the low heat conductivity of the porous catalyst and the endothermic reforming reaction. The calculated results indicate that the use of a compact-size preconverter makes the chemical reaction more uniform and provides many advantages for catalyst maintenance.