• 한국식품과학회지
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• 제15권2호
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• pp.133-134
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• 1983

Some metallic ions such as copper, manganese, iron, zinc and cadmium in ginseng extract, originated from white ginseng, were determined by atomic absorption spectrophotometry. The extracts were prepared with water, 35% ethanol, 50% ethanol or 75% ethanol solution followed by filtration or centrifugation. Greater amounts of metallic ions were found in the solution filtrated by filter paper (Toyo No. 5A) or by filter cloth than in that of centrifugation. The residual amount of metallic ions in the extract decreased with increasing concentration of ethanol. The percentages of each metallic ion in ginseng extracts on the basis of original amount of metallic ions were as follows: Cu, 10.4-31.9%, Fe,5.1-19.0%, Mn,3.0-12.2% Zn,7.4-12.0%, Cd,5.9-11.8%.

• 멤브레인
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• 제20권2호
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• pp.151-158
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• 2010

본 연구는 양성전해질막의 금속이온 특성을 조사하기 위하여 Taurine (TAU)막을 제조하였다. 제조방법으로는 방사선조사법에 의한 Glycidyl methacrylate (GMA)의 중공사막 표면위에 고정시키고, 이후 Taurine의 염기성 부분인 $-NH_2$기(amine fuction)와 GMA의 glycididyl의 개환 반응을 통하여 안정된 막을 형성하도록 하였다. 한편 TAU막과 비교를 위해 GMA가 고정된 중공사 막에 Sodium sulfite로 화학적 결합을 형성 SS막을 제조하였다. 이렇게 제조된 TAU막의 타우린 밀도가 높아져도 투과유속은 0.9 m/h로 변화 없으나, SS막은 술폰산기의 밀도가 높아짐에 따라 투과유속이 급격히 감소하는 것을 나타내었다. 타우린 밀도가 0.8 mmol/g인 막을 사용한 결과 금속이온의 량은 Cu > Cd > Mg > Sb > Pb의 순으로 나타내었다. 전반적으로 타우린막은 전화율과 밀도의 증가에 따라 많은 양의 금속이온 흡착과 높은 투과유속을 나타내었다.

• 한국음향학회지
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• 제29권2호
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• pp.111-117
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• 2010

본 연구에서는 액체 내에서 초음파에 의해 빛이 발생하는 현상인 Sono-Luminescence (이하 SL)에 대해 연구하였다. 알칼리 금속과 알칼리 토금속 화합물을 녹인 용액에서의 SL을 관찰 하였으며, 금속 이온 농도, 금속이온의 종류를 바꾸어 가며 SL에 미치는 영향을 조사하였다. 이 때 각각의 SL에서 나오는 빛을 사진으로 찍어 RGB 성분 분석을 통해 금속 이온을 녹인 용액의 SL이 증류수에서 SL과 금속 불꽃 반응 색 또는 선스펙트럼에서 강한 세기로 방출되는 색의 합성으로 표현될 수 있는지 연구하였다. 알칼리 금속의 경우 두 색의 합성으로 잘 표현되었으나 알칼리 토금속의 경우는 그렇지 않았다. 그 이유로 SL 방출시 온도가 그리 높지 않아서 알칼리 토금속의 선스펙트럼에서 에너지가 큰 단파장의 빛이 SL에서 잘 방출되지 않기 때문인 것으로 추론하였다.

• 대한기계학회논문집A
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• 제32권9호
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• pp.754-760
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• 2008

A two-photon induced photoreduction process suggests a possibility for fabricating complicated metallic microstructures which can be applied to 3-D micro-circuits and optical devices, etc. The process employs the photoreduction of silver ions in a metallic solution which is composed of metallic salt ($AgNO_3$) and watersoluble polymer ((poly(4-styrenesulfonique acid) 18wt. % in $H_2O$, $(C_8H_8O_3S)_n$)). In this process, the improvement of the resolution and the uniformity of fabricated metallic structures are important issues. To address these problems, continuous forming window (CFW) is obtained from a parametric study on the conditions of laser power and scanning velocity and the direct seed generation (DSG) method is proposed. Silver nano particles are uniformly generated in a metallic solution through the DSG method, which enables the decrease of a laser power to trigger the photoreduction of silver ions as well as the increase of metal contents in a metallic solution. So the two-photon induced photoreduction property of a metallic solution is improved. Through this work, precise silver patterns are fabricated with a minimum line width of 400 nm.

• 대한화학회지
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• 제67권4호
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• pp.222-225
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• 2023

Metallic salts of C10-18 aliphatic carboxylic acids were prepared and their scanning electron microscopic images were analyzed for the morphology dependency with the metal and the carboxylic acid. Regardless of metal ion, metal salts of dicarboxylic acids showed a high crystallinity with a fiber image (SuA-Na). The aromatic dicarboxylates also represented a morphology of a rectangular-rod or board shapes (IA-Li, IA-Ba). With Na ion, most aliphatic carboxylate (MA, PA, SA) showed a fiber-like crystallinity. However, other monovalent Li, K and multivalent Mg, especially Al ion resulted a glassy-amorphous in the metallic salts of acids (MA, PA, SA). With divalent Ba and Ca ions, the metal salt of aliphatic acids expressed a branched round cluster shape as in SA-Ca, SA-Ba. Both Li and Mg ions with a similar size showed a strong morphological similarity in the metallic salts of aliphatic acids MA, PA, SA. In the case of Na and Ca ions with a similar size (98, 106 pm), both ionic salts of stearic acid gave a branching effect for a fiber or round granular image. In the case of hydroxyl-aliphatic acids (HLA, HPA, HSA), the fiber images in HLA-Na and HSA-Na was appeared about 100 nm thicker than those of nonhydroxycarboxylates (LA-Na, SA-Na). The metallic salts of unsaturated C-18 carboxylic acids (OlA, LeA and LnA) showed an amorphous glassy image due to a kinked carbon chain.

• 대한화학회지
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• 제21권1호
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• pp.60-66
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• 1977

m-Phenylenediamine(以下 MPD로 略함)과 resorcinol(以下 RES로 略함)을 몰比를 달리하면서 포름알데히드와 酸化觸媒 존재하에서 反應시켜 生成되는 附加共縮合型 樹脂를 流動파라핀을 사용하여 서스펜젼重合시켜 60∼80 mesh의 粒狀重合體를 合成하고 이를 精製한후 5, 10, 15, 20, $25{\%}$의 水酸化 나트륨 水溶液으로 처리한후, 原樹脂와 이들 알칼리 處理樹脂의 金屬이온들에 대한 吸着性을 檢討하였다. $Cd^{2+}$이온에 대한 흡착성은 原樹脂보다 水酸化나트륨水溶液을 처리한 경우 현저히 吸着性은 向上되지만 MPD : RES의 몰比 가 增加함에 따라 原樹脂의 경우와는 달리 減少하는 경향을 나타내며 $Pb^{2+}와\;Al^{3+}$이온들은 알칼리처리로 吸着能增加와 더불어 MPD : RES의 몰比가 2 : 1에서 最大値를 나타내며 $Ca^{2+}$이온의 경우는 MPD : RES의 몰比가 1 : 1에서 최대치를 나타내고 있다. $Mg^{2+}과\;Co^{2+}$이온들은 거의 類似한 傾向을 나타내어 MPD : RES의 몰比增加와 더불어 吸着能은 減少하는 傾向을 나타낸다. $Hg^{2+}$이온의 경우는 特異하며 MPD : RES의 몰比가 減少함에 따라 吸着能은 현저히 增加하는 경향을 나타내어 窒素含宥킬레이트와의 結合性이 强한 一般性과 잘 一致하고 있다. 이 系의 樹脂들은 輕金屬 이온(例 $Ca^{2+},\;Mg^{2+}$) 들보다 重金屬이온(例 $Cd^{2+},\;Hg^{2+}$)들에 對한 吸着力이 현저히 優秀하다.

• 환경위생공학
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• 제22권3호
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• pp.77-87
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• 2007

The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 - divinylbenzene(DVB) with 1%, 3%, and 5%-crosslinking and macro cyclic ligand of OenNen-$H_4$ by copolymerization method and the adsorption characteristics of uranium(VI), iron(II) and samarium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium ${UO_2}^{2+}>Fe^{2+}>Sm^{3+}$ ion. The adsorption was in order of 1%, 3%, and 5% crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvent.

• 환경위생공학
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• 제20권3호
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• pp.27-35
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• 2005

The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 -divinyl-benzene(DVB) with $1\%,\;4\%,\;and\;10\%$-crosslinking and macrocyclic ligand of cryptand type by copolymerization method and the adsorption characteristics of uranium(VI), calcium(II) and lutetium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium $(UO_2^{2+})>calcium(Ca^{2+})>lutetium(Lu^{3+})$ ion. The adsorption was order of $1\%,\;4\%,\;and\;10\%$ crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.1983-1987
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• 2008

This study demonstrates the electrochemical conversion of the synthetic procedure of monolayer-protected clusters using a thin toluene layer over an edge plane pyrolytic graphite electrode. A thin toluene layer with a thickness of 0.31 mm was coated over the electrode and an immiscible liquid/liquid water/toluene interface was introduced. The transfer of the tetrachloroaurate ($AuCl_4^-$) ions into the toluene layer interposed between the aqueous solution and the electrode surface was electrochemically monitored. The $AuCl_4^-$ ions initially could not move through into the toluene layer, showing no reduction wave, but, in the presence of the phase transfer reagent, tetraoctylammonium bromide (TOABr), a cathodic wave at 0.23 V vs. Ag/AgCl was observed, indicating the reduction of the transferred $AuCl_4^-$ ions in the toluene layer. In the presence of dodecanethiol together with TOABr, a self-assembled monolayer was formed over the electro-deposited metallic gold surface. The E-SEM image of the surface indicates the formation of a highly porous metallic gold surface, rather than individual nanoparticles, over the EPG electrode.

• 환경위생공학
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• 제21권3호
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• pp.52-60
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• 2006

The ion exchange resins have been synthesized from chlormethyl styrene-1,4-divinylbenzene(DVB) with 1%, 2%, and 20%-crosslinking and macrocyclic ligand of cryptand 21 by copolymerization method and the adsorption characteristics of uranium(VI), copper(II) and dysprosium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, equilibrium time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The metal ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium$(UO^{2+}_2)\;>\;copper(Cu^{2+})\;>\;dysprosium(Dy^{3+})$ ion. The adsorption was in order of 1%, 2%, and 20% crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.