• Title/Summary/Keyword: Membrane resistance

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Separation of Hydrogen-Nitrogen Gas Mixture by PTMSP/PDMS-PEI Composite Membrane

  • Lee, Hyun-Kyung;Kang, Tae-Beom
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.148-151
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    • 2004
  • The development of the gas separation processes using polymeric membranes has attracted a great deal of interest during the last two decades. Membrane in this application has to offer an excellent thermal stability, chemical/solvent resistance, and mechanical strength under operating conditions.(omitted)

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Experimental Study and Modelling on Membrane Fouling in Taylor Vortex Flow Microfiltration (테일러 와류 정밀여과에서 막오염의 실험적 연구 및 모델링)

  • 박진용;김현우;최창균
    • Membrane Journal
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    • v.13 no.2
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    • pp.88-100
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    • 2003
  • A change of filtrate flux in Taylor vortex flow filtration was investigated experimentally by rotating speed of inner cellulose ester membrane cylinder (average pore size: 1.2 ${\mu}m$), slurry concentration, and particle size. The filtrate flux was a direct proportion relation with TMP, but an inverse relation with resistances. A change of cake resistance with time was examined by rotating speed, slurry concentration, and particle size. Initial resistance increased dramatically as raising slurry concentration, and the pseudo-steady state was maintained at high resistance value. However, times to reach the pseudo-steady state did not depend on slurry concentration. The resistance was larger as smaller particle size, because possibility of pore blocking inside membrane could be higher and shear effect should be lower as smaller particle size. A model equation suggested in this study was composed of particle deposition and removal terms, and could confirm well experimental data using average values of experimental coefficients.

The effect of MEA fabrication procedure on PEMFC performance (고분자전해질 연료전지의 MEA 제조방법에 따른 성능비교)

  • Cho Yong-Hun;Cho Yoon-Hwan;Park In-Su;Choi Baeckbom;Jung Dae-Sik;Sung Yung-Eun
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.291-295
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    • 2005
  • The PEMFC behavior is quite complex and is influenced by several factors, including composition and structure of electrodes and membrane type. Fabrication of MFA is important factor for proton exchange membrane fuel cell. MFA of PEMFC with hot pressing and direct coating method were prepared, and performances were evaluated and compared each other. The effect of MEA preparation methods, hot pressing methods and direct coating methods, on the cell performance was analyzed by impedance spectroscopy and SEM. The performance of PEMFC wi th direct coat ing method was better than wi th hot pressing method because membrane internal resistance and membrane-:-interfacial resistance were reduced by elimination of hot pressing process in MEA fabrication. In addition the micro structure of MEA with direct coating method reveals uniform interface between membrane and catalyst layer.

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Fouling and cleaning of a tubular ultrafiltration ceramic membrane

  • Siddiqui, Farrukh Arsalan;Field, Robert W.
    • Membrane and Water Treatment
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    • v.7 no.5
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    • pp.433-449
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    • 2016
  • The successful application of cleaning protocols is vital for optimized filtration processes. A series of experiments with an ultrafiltration ceramic tubular membrane were carried out for the foulants dextran and carboxymethyl cellulose. Firstly, the impact on fouling of concentration changes was investigated with the increase in resistance being used as the key parameter. In the second phase, removal of reversible fouling was also investigated by employing intermittent rinsing consisting of a cold water rinse followed by a hot one. A comparative analysis for both foulants is reported. Across a range of concentrations and for both foulants, the reduction in resistance due to rinsing was found to depend upon concentration (C); it changed as $C^n$ where n was found to be 0.3. A plausible semi-theoretical explanation is given. Thirdly, for both foulants, the application of a combination of strong alkaline solutions with oxidizing agent (mainly sodium hypochlorite) followed by acid was found to be appropriate for cleaning of the ceramic membrane. The effect of increased temperature for cleaning agents followed by a warm water rinse contributed positively to the cleaning capability.

Test on the Mechanical Characteristics of Glass Fiber Membrane (유리섬유 막재의 역학적 특성에 관한 시험)

  • Park, Kang-Geun;Yoon, Sung-Kee
    • Journal of Korean Association for Spatial Structures
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    • v.8 no.2
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    • pp.55-62
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    • 2008
  • Membrane structures are now used in various ways throughout the world with the merits of free shape, lightness, durability, sunlight transmittance and homogeneous material. The development of new membrane material opened up new possibility for the design of new building structures. Recently it was mainly used PVC, PVF, PVDF, PTFE, ETFE membrane for using the roofing material of membrane structures. Some problems of membrane materials have fire proofing, lack of strength, self cleaning capacity, tear resistance, durability, heat insulation, sound insulation and elasticity. For the solution of this problems, it will be tested the mechanical properties of membrane material about tensile strength, tearing resistance, etc.

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Uncoupling Protein, UCP-4 May Be Involved in Neuronal Defects During Aging and Resistance to Pathogens in Caenorhabditis elegans

  • Cho, Injeong;Hwang, Gyu Jin;Cho, Jeong Hoon
    • Molecules and Cells
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    • v.39 no.9
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    • pp.680-686
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    • 2016
  • Uncoupling proteins (UCPs) are mitochondrial inner membrane proteins that function to dissipate proton motive force and mitochondrial membrane potential. One UCP has been identified in Caenorhabditis elegans (C. elegans), namely UCP-4. In this study, we examined its expression and localization using a GFP marker in C. elegans. ucp-4 was expressed throughout the body from early embryo to aged adult and UCP-4 was localized in the mitochondria. It is known that increased mitochondrial membrane protential leads to a reactive oxygen species (ROS) increase, which is associated with age-related diseases, including neurodegenerative diseases in humans. A ucp-4 mutant showed increased mitochondrial membrane protential in association with increased neuronal defects during aging, and the neurons of ucp-4 overexpressing animals showed decreased neuronal defects during aging. These results suggest that UCP-4 may be involved in neuroprotection during aging via relieving mitochondrial membrane protential. We also investigated the relationship between UCP-4 and innate immunity because increased ROS can affect innate immunity. ucp-4 mutant displayed increased resistance to the pathogen Staphylococcus aureus compared to wild type. The enhanced immunity in the ucp-4 mutant could be related to increased mitochondrial membrane protential, presumably followed by increased ROS. In summary, UCP-4 might have an important role in neuronal aging and innate immune responses through mediating mitochondrial membrane protential.

Use of Inner Ionomer Solution in Preparing Membrane-Electrode Assembly (MEA) for Fuel Cells and Its Characterization

  • Seo, Seok-Jun;Woo, Jung-Je;Yun, Sung-Hyun;Park, Jin-Soo;Moon, Seung-Hyeon
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.46-52
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    • 2008
  • Optimization of ionomer solution was conducted in order to improve the performance of MEAs in PEMPC. The interface between membrane and electrodes in MEAs is crucial region determining fuel cell performance as well as ORR reaction at cathode. Through the modification of Nafion ionomer content at the interface between membrane and electrodes, an optimal content was obtained with Nafion 115 membranes. Two times higher current density was obtained with the outer Nafion sprayed MEA compared with the non-sprayed one. In addition, the symmetrical impedance spectroscopy mode (SM) exhibited that the resistances of membrane area, proton hydration, and charge transfer decreased as the outer Nafion is sprayed. From the polarization curves and SM, the highest current density and the lowest resistance was obtained at the outer ionomer content of $0.15\;mg\;cm^{-2}$.

High Temperature Characteristics of Commercially Available Anion Exchange Membrane for Alkaline Water Electrolysis (알칼리 수전해를 위한 상용 음이온교환막의 고온 특성)

  • JANG, SU-YOEN;RYU, CHEOL-HWI;HWANG, GAB-JIN
    • Journal of Hydrogen and New Energy
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    • v.33 no.4
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    • pp.330-336
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    • 2022
  • In order to evaluate the possibility as a separator in alkaline water electrolysis, the high temperature characteristics were evaluated by measuring the membrane resistance and durability of 5 types of commercial anion exchange membranes in 7 M KOH solution and at 80℃. The membrane resistance of AEM membrane measured in 7 M KOH solution and at 80℃ had a lower value of about 8-24 times compared to the other membranes. The durability of AEM membrane tested with the soaking time in 7 M KOH solution and at 80℃ showed a very good stability and that of FAAM40 and FAAM75-PK showed secondly a good stability. The thermal stability with the soaking time in 7 M KOH solution and at 80℃ of FAAM40 and FAAM75-PK membrane analyzed by thermo-gravimetric analysis showed a good stability compared to the other membranes.

Enhanced performance of thin-film nanocomposite RO/NWF membrane by adding ZnO nanospheres in aqueous phase during interfacial polymerization process

  • Li, Hongbin;Shi, Wenying;Su, Yuheng;Hou, Hongxiang;Du, Qiyun;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
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    • v.8 no.3
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    • pp.225-244
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    • 2017
  • A novel thin-film nanocomposite (TFN) reverse osmosis (RO)/non-woven fabric (NWF) membrane was prepared by adding zinc oxide (ZnO) nanospheres ($30{\pm}10nm$) during the interfacial polymerization process of m-phenylenediamine (MPD) and trimesoyl chloride (TMC) on self-made polysulfone (PSF) membrane/polyester (PET) non-woven fabric support. The improved performance of TFN RO membrane was verified in terms of water contact angle (WCA), water flux, salt rejection, antifouling properties and chlorine resistance. The results showed that the WCA value of TFN RO surface had a continuous decrease with the increasing of ZnO content in MPD aqueous solution. The water flux of composite TFN RO membranes acquired a remarkable increase with a stable high solute rejection (94.5 %) in $1g{\cdot}L^{-1}$ NaCl aqueous solution under the optimized addition amount of ZnO (1 wt%). The continuous testing of membrane separation performance after the immersion in sodium hypochlorite solution indicated that the introduction of ZnO nanospheres also dramatically enhanced the antifouling properties and the chlorine resistance of composite RO membranes.

Flame Resistance Performance of Architectural Membrane According to Woven Fabrics and Coating Materials (직포 및 코팅재 타입에 따른 건축용 막재의 난연성능)

  • Kim, Ji Hyeon;Song, Hun
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.6
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    • pp.545-551
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    • 2016
  • Membrane structures which can be used large spatial structure are being expanded because of various advantages. However, despite the diverse membrane structure buildings and materials, the standard for membrane material performance that considering fire safety is still inadequate. Therefore, this study applied basalt or glass woven fabric with flame resistance on architectural membrane, and report the fire safety for architectural membrane using the strength properties, flammability and incombustibility. From the test result, the architectural membrane using basalt or glass woven fabric showed a low heat release rate and total heat release. Therefore, it was confirmed that the fire safety is relatively high.