• Title/Summary/Keyword: Matrix diffusion

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Travel Times of Radionuclides Released from Hypothetical Multiple Source Positions in the KURT Site (KURT 환경 자료를 이용한 가상의 다중 발생원에서의 누출 핵종의 이동 시간 평가)

  • Ko, Nak-Youl;Jeong, Jongtae;Kim, Kyung Su;Hwang, Youngtaek
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.4
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    • pp.281-291
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    • 2013
  • A hypothetical repository was assumed to be located at the KURT (KAERI Underground Research Tunnel) site, and the travel times of radionuclides released from three source positions were calculated. The groundwater flow around the KURT site was simulated and the groundwater pathways from the hypothetical source positions to the shallow groundwater were identified. Of the pathways, three pathways were selected because they had highly water-conductive features. The transport travel times of the radionuclides were calculated by a TDRW (Time-Domain Random Walk) method. Diffusion and sorption mechanisms in a host rock matrix as well as advection-dispersion mechanisms under the KURT field condition were considered. To reflect the radioactive decay, four decay chains with the radionuclides included in the high-level radioactive wastes were selected. From the simulation results, the half-life and distribution coefficient in the rock matrix, as well as multiple pathways, had an influence on the mass flux of the radionuclides. For enhancing the reliability of safety assessment, this reveals that identifying the history of the radionuclides contained in the high-level wastes and investigating the sorption processes between the radionuclides and the rock matrix in the field condition are preferentially necessary.

The Aging Effect of $Avimid^(R)$ K3B/1M7 Laminates in $80^{\circ}C$ Water ($Avimid^(R)$ K3B/IM7 복합재료의 $80^{\circ}C$ 물에서의 노화현상)

  • Kim Hyung-Won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.9 no.4
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    • pp.23-30
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    • 2005
  • The Hygrothermal aging of the laminates of $Avimid^(R)$ K3B/IM7 in $80^{\circ}C$ water was studied as a function of immersion time prior to forming microcracks. The factors causing the $80^{\circ}C$ water to degradation of the laminates could be the degradation of the matrix toughness, the change in residual stresses or the interfacial damage between the fiber and the matrix. The times to saturation in $80^{\circ}C$ water for the laminates and for the neat resin were 100 hours and 500 hours. After 500 hours aging of the neat resin, the glass transition temperature was changed less than 1% by DSC test, and the weight gain was 1.55% increase with the diffusion coefficient $7\times10^{-6}m/s^2$ and the fracture toughness was decreased about 41%. After 100 hours fully saturated aging of the ${[+45/0/-45/90]}_s$ K3B/IM7 laminates in $80^{\circ}C$ water, the weight gain was 0.41% increase with the diffusion coefficient $1\times10^{-6}m/s^2$. In 100 hours, the loss of the fracture toughness of the laminates was 43.8% of the original toughness by the microcracking fracture toughness criterion. Therefore, the main factor to degrade the microcracking toughness of the laminates could be the degradation of the matrix fracture toughness.

Effect of Process Parameters on Plasma Nitriding Properties of $FeAl/SiC_p$ Composites ($FeAl/SiC_p$ 복합재료의 공정변수에 따른 플라즈마 질화 특성)

  • 박지환;김수방;박윤우
    • Journal of Powder Materials
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    • v.6 no.4
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    • pp.286-293
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    • 1999
  • This study was to analyse the relationship between process parameters of the sintered composite and plasma nitriding properties with pulsed DC plasma. Fe-40at%$SiC_p$ composites of full density were fabricated by hot pressing at 1100~$1150^{\circ}C$. Sintered Fe-40at%Al and Fe-40at%$Al/SiC_p$ alloys were nitrided under pulsed DC plasma. Excellent surface hardness in the FeAl alloys could be obtained by plasma nitriding. ($H_v$ :100gf, diffusion layer : 1100~$1450kg/mm^2$, matrix : 330~$360kg/mm^2$) The wear resistance of $FeAl/SiC_p$ composites were improved about by 4~6times than FeAl and nitrided $FeAl/SiC_p$ were improved about 2 times than $FeAl/SiC_p$ matrix.

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Penetration Enhancement of β2-Selective Agonist, Tulobuterol, Across Hairless Mouse Skin

  • Kim, Byung-Do;Choi, Hoo-Kyun
    • Journal of Pharmaceutical Investigation
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    • v.33 no.2
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    • pp.79-84
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    • 2003
  • The effects of various pressure sensitive adhesives (PSA) and enhancers on the percutaneous absorption of tulobuterol were investigated. The permeation rate of tulobuterol through hairless mouse skin from various adhesives was evaluated using a flow-through diffusion cell system at $37^{\circ}C$. The permeability of tulobuterol was variable depending on the physicochemical property of the PSA. The permeation rate of tulobuterol from polyethylene oxide grafted acrylic adhesive matrix was higher than that from other PSA matrices. The flux of tulobuterol was $4.37{\pm}0.34\;{\mu}g/hr/cm^2$ from polyethylene oxide grafted acrylic adhesive matrix. When the effects of various enhancers on the percutaneous absorption of tulobuterol from grafted acrylic adhesive were evaluated, Plurol $oleique^{\circledR}$ showed higher flux than all other enhancers tested.

Formation of Metal Complex in a Poly(hydroxamic acid) Resin Bead

  • Lee, Taek-Seung;Jeon, Dong-Won;Kim, Jai-Kyeong;Hong, Sung-Il
    • Fibers and Polymers
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    • v.2 no.1
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    • pp.135-139
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    • 2001
  • Poly(hydroxamic acid) resin beads were prepared and complexed with various metal ions. We used IR spectroscopy to investigate the structure of metal complex. It proved that the products formed by introduction of metal ions gave stable and colored complex. It was found that the resin bead as synthesized would be a good column packing material for continuous extraction. Energy dispersive spectroscopy was use to study the distribution of metal ions in the resin matrix. It could be tentatively concluded that adsorption and diffusion of metal ions in the chelating resins mainly depended on the loading of the resin matrix which indicated interacting sites with metal ions.

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A Study of Threshold stress during High Temperature Creep of $\textrm{BN}_f$/Al-5, wt% Mg Metal Matrix Composite (BN 입자 강화 Al-5wt% Mg 기지 복합재료의 고온 크립 변형에서의 임계응력 해석)

  • Song, M.H.;Kwon, H.;Kim, Y.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2000.04a
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    • pp.187-191
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    • 2000
  • High temperature creep behaviour of Al-5 wt% Mg alloy reinforced with 7.5% BN flakes was studied. The composite specimens showed two main creep characteristics : (1) the value of the apparent stress exponent of the composite was high and varied with applied stress (2) the apparent activation energy for creep was much larger than that for self-diffusion in aluminum The true stress exponent of the composite was set equal to 5. Temperature dependence of the threshold stress of the composite was very strong. Which could not be rationalized by allowing for the temperature dependence of the elastic modulus change. AIN particles which were incorporated into the Al matrix during fabrication of the composite by the PRIMEXTM method were found to be effective barriers to dislocation motion and to give rise the threshold stress during creep of the composite

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Simulations of premixed combustion in porous media (다공판 내의 예혼합연소 특성 해석)

  • Shin, Youngjun;Lee, Jeongwon;Kim, Yongmo
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.253-255
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    • 2012
  • This study has numerically investigated the combustion processes in the bilayer porous media. To account for the velocity transition and diffusion influenced by solid matrix, porosity effects are included in the governing equations. Heat transfer coefficient is calculated by Nusselt number to reflect the effect of gas velocity, pore diameter, and material properties. Numerical results indicate that the present approach is capable of the essential features of the premixed combustion in the porous burner, in terms of the precised flame structure, pollutant formation, and flame stabilization. It is also found that heat transferred from the downstream flame zone is conducted to the upstream flame region through the solid matrix and the preheated mixture. By increasing the inlet velocity, the solid temperature of upstream is cooling down.

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Modeling for Multilayered Polymer Matrix Drug Delivery Device (다층구조로 된 고분자 제형의 약물 방출에 대한 모델링)

  • Byun, Young-Rho;Jeong, Seo-Young;Kim, Young-Ha
    • Journal of Pharmaceutical Investigation
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    • v.19 no.2
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    • pp.87-92
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    • 1989
  • The multilayered monolithic type transdermal delivery device has been designed and analyzed by a numerical analysis. The device consists of three layered polymer matrices which posess the different diffusion parameters, respectively. The purpose of this study was to design an ideal transdermal drug delivery device which is capable of initial burst and zero order release later on. Numerical modelings were simulated for a dispersed and a dissolved multilayered monolithic system. The results showed that the dispersed multilayered monolithic system could meet the requirements for an ideal transdermal delivery device.

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The Technology Valuation Model for Technology of Management (기술경영을 위한 기술가치 평가모형)

  • Hong, Du-Wha;Park, Hae-Keun
    • Journal of the Korea Safety Management & Science
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    • v.8 no.4
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    • pp.63-89
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    • 2006
  • Recently, the technology is getting to be the most important factor for companies, as the industry is changing fast. The uncertainty and complexity of technology valuation arc higher so that the technology concentrated companies need more developed and high performance technology. This paper reviews the methods of technology valuation for five categories that have been developed by valuation researchers, (1) research of technology diffusion and acceptance model, (2) research of technology valuation, (3) research of technology import and export factor, (4) research of technology valuation model, (5) research of technology transfer and market. And we propose a new technology valuation model using need(market), seed(technology) and deeds(management) factor by cross impact matrix. This model gives us the reference negotiation range for deciding the amount of royalty. I hope this paper induces more research on this field of technology valuation.

Response of angle-ply laminated cylindrical shells with surface-bonded piezoelectric layers

  • Wang, Haojie;Yan, Wei;Li, Chunyang
    • Structural Engineering and Mechanics
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    • v.76 no.5
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    • pp.599-611
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    • 2020
  • A state-space method is developed to investigate the time-dependent behaviors of an angle-ply cylindrical shell in cylindrical bending with surface-bonded piezoelectric layers. Both the interfacial diffusion and sliding are considered to describe the properties of the imperfect interfaces. Particularly, a matrix reduction technique is adopted to establish the transfer relations between the elastic and piezoelectric layers of the laminated shell. Very different from our previous paper, in which an approximate numerical technique, i.e. power series expansion method, is used to deal with the time-dependent problems, the exact solutions are derived in the present analysis based on the piezoelasticity equations without any assumptions. Numerical results are finally obtained and the effects of imperfect interfaces on the electro-mechanical responses of the laminated shell are discussed.