• Title/Summary/Keyword: Material Measurements

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OMVPE and Plasma-Assisted Doping of ZnSe with Dimethlzinc:triethylamine Adduct Source

  • Huh, Jeung-Soo;Lim, Jeong-Ok
    • Journal of Sensor Science and Technology
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    • v.5 no.2
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    • pp.55-60
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    • 1996
  • The growth and microwave plasma assisted nitrogen doping of ZnSe by low pressure organometallic vapor phase epitaxy(OMVPE) has been investigated in a vertical downflow reactor equipped with a laser interferometer for in-situ growth rate measurements. Particular emphasis is placed on understanding growth characteristics of $H_{2}Se$ and the new adduct source dimethylzinc:triethyllamine($DMZn:NEt_{3}$) as compared with those obtained with $H_{2}Se$ and DMZn. At lower temperatures ($<300^{\circ}C$) and pressures(<30Torr), growth rates are higher with the adduct source and the surface morphology is improved relative to films synthesized with DMZn. Hall measurements and photoluminescence spectra of the grown films demonstrate that DMZn and $DMZn:NEt_{3}$ produce material with comparable electronic and optical properties. Microwave plasma decomposition of ammonia is investigated as a possible approach to increasing nitrogen incorporation in ZnSe and photoluminescence spectra are compared to those realized with conventional ammonia doping.

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Viscoelastic Properties of Fresh Cement Paste to Study the Flow Behavior

  • Choi, Myoungsung;Park, Kyoungsoo;Oh, Taekeun
    • International Journal of Concrete Structures and Materials
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    • v.10 no.sup3
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    • pp.65-74
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    • 2016
  • During concrete pumping, the migration and redistribution of particles occur in a pipe and the lubrication layer that forms between the bulk concrete and the pipe wall is the governing factor determining the flow behavior. In order to identify flow behavior of pumping, in this study, the viscoelastic properties related to the microstructural behavior of a flocculated suspension were examined by using dynamic oscillatory measurements. Cement paste is assumed to be a constituent material of the lubrication layer and ten cases of mixing design are employed by changing the proportions of mineral admixtures. The relationship between the yield stress obtained from the steady shear test and the dynamic modulus resulted from the oscillatory shear measurement was derived and the implications of the correlation are discussed. Moreover, based on the investigation of the viscoelastic properties with oscillatory measurements, the initial behavior of pumped concrete was analyzed systematically.

Capacitance-Voltage (C-V) Characteristics of Cu/n-type InP Schottky Diodes

  • Kim, Hogyoung
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.5
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    • pp.293-296
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    • 2016
  • Using capacitance-voltage (C-V) and conductance-voltage (G/ω-V) measurements, the electrical properties of Cu/n-InP Schottky diodes were investigated. The values of C and G/ω were found to decrease with increasing frequency. The presence of interface states might cause excess capacitance, leading to frequency dispersion. The negative capacitance was observed under a forward bias voltage, which may be due to contact injection, interface states or minority-carrier injection. The barrier heights from C-V measurements were found to depend on the frequency. In particular, the barrier height at 200 kHz was found to be 0.65 eV, which was similar to the flat band barrier height of 0.66 eV.

Study of Electron Injection of Pentacene Field Effect Transistor with Au Electrodes by C-V and SHG Measurements

  • Lim, Eun-Ju;Manaka, Takaaki;Tamura, Ryosuke;Ohshima, Yuki;Iwamoto, Mitsumasa
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.4
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    • pp.151-155
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    • 2008
  • Using pentacene field effect transistors (FETs) with Au source and drain electrodes, electron injection from the Au electrodes into the pentacene was investigated. The capacitance-voltage (C-V) and optical second harmonic generation (SHG) measurements were employed. Electron injection from the Au electrodes was suggested by the hysteresis behavior with the C-V characteristics and slowly decaying SHG signal under DC biasing, A mechanism of hole-injection assisted by trapped electrons is proposed. To confirm electron injection process, light-emitting behavior under the application of AC applied voltage was observed.

Electrical Stress in High Permittivity TiO2 Gate Dielectric MOSFETs

  • Kim, Hyeon-Seag;S. A. Campbell;D. C. Gilmer
    • Electrical & Electronic Materials
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    • v.11 no.10
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    • pp.94-99
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    • 1998
  • Suitable replacement materials for ultrathin SiO2 in deeply scaled MOSFETs such as lattice polarizable films, which have much higherpermittivities than SiO2, have bandgaps of only 3.0 to 4.0 eV. Due to these small bandgaps, the reliability of these films as a gate insulator is a serious concern. Ramped voltage, time dependent dielectric breakdown, and hot carrier effect measurements were done on 190 layers of TiO2 which were deposited through the metal-organic chemical vapor deposition of titanium tetrakis-isopropoxide (TTIP). Measurements of the high and low frequency capacitance indicate that virtually no interface state are created during constant current injection stress. The increase in leakage upon electrical stress suggests that uncharged, near-interface states may be created in the TiO2 film near the SiO2 interfacial layer that allow a tunneling current component at low bias.

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Alginic acid-silica hydrogel coatings for the protection of ssmotic distillation membranes against wet-out by surface-active agents

  • Xu, J.B.;Spittler, D.A.;Bartley, J.P.;Johnson, R.A.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.354-354
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    • 2006
  • Alginic acid-silica hydrogel films was prepared for testing as protective coating materials for PTFE OD membranes. Unprotected hydrophobic membranes are subject to wet-out when contacted by surface-active agents. Films were characterised using SEM, XRD, DSC, mechanical strength measurements, and water-swelling measurements. In OD trials using coated membranes, no wet-out occurred over the 15 h duration of three consecutive 5 h OD trials using orange oil-water mixtures. In the case of detergent solutions, the coating afforded protection to the membrane for 4-5 h. In a separate trial, no wet-out occurred when the coated side of the membrane was placed in contact with 1.2 wt % orange oil for 72 hours.

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Characterization of Silk Fibroin/S-carboxymethyl Kerateine Surfaces: Evaluation of Biocompatibility by Contact Angle Measurements

  • Lee, Kuen-Yong
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.71-74
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    • 2001
  • Surface characterization of materials has been considered critical in the development of biomaterials, as many unfavorable responses from the body occur at the interface between a material and the body component. The contact angle measurement is one means to characterize the surface properties and to correlate them to the biocompatibility of materials. In this paper, surface characteristics of silk fibroin/S-carboxymethyl kerateine, representative fibrous proteins, were investigated by contact angle measurements of ESCA. The biocompatibility of the blends was evaluated based on minimal interfacial free energy concept, and compared with other potential biomaterials. It was also hypothesized that the enhanced surface polarity of the blends was generated from the conformational transition of proteins. This approach to evaluate the biocompatibility of materials based on surface characteristics may find wide utility in many biomedical applications.

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Demonstrative Experiments on the Magnetocaloric Effect of Gadolinium (가돌리늄의 자기열량효과에 대한 실증실험)

  • 이종석
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.4
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    • pp.383-389
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    • 2004
  • Magnetic refrigeration is based on the magnetocaloric effect (MCE) - the ability of some materials to heat up when magnetized and cool down when removed from the magnetic field. The available techniques for studying the MCE we: (1) direct measurements by monitoring the change in the material's temperature during the application or removal of the magnetic field; and (2) indirect calculations from the experimental data of magnetization and/or specific heat as a function of the temperature and magnetic field. The MCE of gadolinium (Gd) has been demonstrated by direct measurements of temperature change, and isothermal magnetic entropy changes and adiabatic temperature changes have been calculated.

Analysis of Chemical and Morphological Changes of Phenol Formaldehyde-based Photoresist Surface caused by O2 Plasma

  • Shutov, D.A.;Kang, Seung-Youl;Baek, Kyu-Ha;Suh, Kyung-Soo;Min, Nam-Ki;Kwon, Kwang-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.5
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    • pp.211-214
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    • 2007
  • Chemical and morphological changes of phenol formaldehyde-based photoresist after $O_2$ radiofrequency(RF) plasma treatment depending on exposure time and source power were investigated. It was found that etch rate of photoresist sharply increased after discharge turn on and reached a limit with increase in plasma exposure time. Contact angle measurements and X-ray photoelectron spectroscopy(XPS) analysis showed that the surface chemical structure become nearly constant after 15 sec of the treatment. Atomic force microprobe(AFM) measurements were shown that surface roughness was increased with plasma exposure time.

Sensitivity Analysis in the Estimation of Complex Elastic Modulus of Viscoelastic Materials by Transmissibility Measurements (전달율 측정에 의한 점탄성재료의 복소탄성계수 추출시의 민감도 분석)

  • 안태길;허진욱;김광준
    • Journal of KSNVE
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    • v.2 no.2
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    • pp.99-106
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    • 1992
  • The complex Young's modulus of a viscoelastic material can be obtained as a function of frequency from the measurements of relative motion between the two ends of a bar-type specimen. Non-resonance method is usually used to obtain the complex Young's modulus over wide range of frequency including resonance points, while in resonance method information at resonance frequencies only is used. However, the complex Young's modulus obtained by the non-resonance method is often unreliable in the anti-resonance frequency regions because of the measurement noise problems. In this study, the effects of the random measurement errors on estimating the complex Young's modulus are studied in the aspect of sensitivity, and how to obtain the reliable frequency region for a given measurement error level is shown. The usable frequency regions in determining the complex Young's modulus are represented by a non-dimensional parameter formed with the wave length and specimen length.

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