• Title/Summary/Keyword: Material Decomposition

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A Study on the Thermal Stability of Carpet in Air Condition (에어컨디션에서 카펫의 열안정성에 관한 연구)

  • Park, Keun-Ho;Lee, Soo;Song, Ju-Yeong;Lee, Ki-Chul
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.4
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    • pp.362-367
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    • 2006
  • This paper describes the experiments for investigating the effects of thermal stability of several commercial carpet mate materials. The melting point and thermal decomposition temperature was measured by means of a differential scanning calorimeter(DSC) in air condition. The DSC data and burning test results of nylon bulked continuous filament(N-BCF) yarn 100%, nylon(NY), polypropylene(PP), and a new material named polytrimethyleneterephthalate(PTT) were analysed to obtain the effect on their thermal stability. Conclusively, we observed that PTT and PP were approximately $380^{\circ}C$ and $240^{\circ}C$ to start the thermal decomposition, respectively. In other words, PTT is thermally the most stable material for carpet manufacturing.

Data reconciliation for multicomposition processes (다성분 공정을 위한 데이터 보정)

  • 이무호;한종훈;장근수
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10b
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    • pp.36-39
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    • 1996
  • In chemical processes, measurement errors reduce the credibility of information and cause inconsistency in material and energy balances. Because multicomposition flows and temperature measurements make material and energy balances nonlinear equations, data reconciliation becomes a nonlinear constrained optimization problem. In multicomposition processes, if we follow general optimization procedure, the number of measurement variables is so large that data reconciliation requires much computation time. We propose the decomposition procedure to reduce the computation time without the decrease of accuracy of data reconciliation. Decomposition procedure finds global variables, that can reduce the nonlinearity of constraints, and divides two sub-optimization problems. Once we optimize the global variables at upper level, we can easily optimize the remain variables at tower level, We can obtain the short computational time and the same accuracy as SQP optimization method.

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Evaluation of Ozone for Metal Oxide Thin Film Fabrication

  • Lim, Jung-Kwan;Park, Yong-Pil;Jang, Kyung-Uk;Lee, Hee-Kab
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.675-678
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    • 2004
  • Ozone is usually generated from oxygen gas using a silent discharge apparatus and its concentration is less then 10 mol%. An ozone condensation system is constructed for metal oxide thin film fabrication. Ozone is condensed by the adsorption method, which is widely used for the growth of oxidation thin films such as superconductor. Highly condensed ozone is analyzed by three methods; ultraviolet absorption, thermal decomposition and Q-mass analyzing methods. Thermal decomposition method is most effective in the highly condensed ozone region and its method is superior to Q-mass analyzer for determining ozone concentration because of the simplicity of the method.

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Analysis of $O_3$ Concentration for Metal Oxide Thin Films Growth (금속 산화물 박막제작을 위한 오존 농도 분석)

  • Lim, Jung-Kwan;Park, Yong-Pil;Jang, Kyung-Uk;Lee, Hee-Kab
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.331-332
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    • 2005
  • Ozone is ambient gas which is useful for the fabrication of metal oxide thin films under conditions of molecular beam epitaxy. Ozone is condensed by the adsorption method and its concentration is analyzed using the thermal decomposition method. The concentration of ozone exceeds 90 mol% and ozone is supplied for a sufficiently long time to grow oxide thin films. The ozone concentration is also evaluated using a quadrupole mass analyzer and the accuracy of this method is compared with the results of the thermal decomposition method.

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Characteristics of Oxidation System for Superconductor Thin Film( II ) (초전도 박막 제작을 위한 산화 시스템의 특성( II ))

  • An, I.S.;Park, Y.P.;Lim, J.K.;Jang, K.U.;Lee, H.K.;Kim, G.Y.;Lee, J.U.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.264-267
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    • 2002
  • An ozone condensation system is evaluated from the viewpoint of an ozone supplier for oxide thin film growth. Ozone is condensed by the adsorption method and its concentration is analyzed by three methods; ultraviolet absorption, thermal decomposition and Q-mass analyzing methods. Thermal decomposition method is found to be available to the concentration evaluation from dilution to highly condensed ozone. The highest ozone concentration condensed by the adsorption method is evaluated to be 97 mol%

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Characteristics of Oxidation System for Superconductor Thin Film( I ) (초전도 박막 제작을 위한 산화 시스템의 특성( I ))

  • Lim, J.K.;Park, Y.P.;Yang, D.B.;Kim, J.H.;Lee, H.K.;Park, N.B.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.272-275
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    • 2002
  • An ozone condensation system is evaluated in the viewpoint of an ozone supplier for oxide thin film growth. Ozone is condensed by the adsorption and distillation method. Then their concentrations are analyzed by three methods; ultraviolet absorption, thermal decomposition and Q-mass analyzing methods. Thermal decomposition method is found to be available to the concentration evaluation from dilution to highly condensed ozone. The highest ozone concentration condensed by the adsorption method is evaluated to be 96 mol%. The ozone is supplied for a sufficiently long time to grow oxide thin films.

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A study of decomposition of harmful gases using Composite catalyst by Photocatalytic plasma reactions (복합촉매를 이용한 플라즈마 반응에 의한 유해가스의 제거에 관한 연구)

  • Park, Hwa-Young;Kim, Kwan-Jung;Woo, In-Sung
    • Journal of the Korea Safety Management & Science
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    • v.15 no.1
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    • pp.121-132
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    • 2013
  • The objective of this study is to maintain the same frequency as the electrode material, concentration, duration of decomposition efficiency, power consumption and voltage measurements using a composite catalyst according to the change of process parameters to obtain the optimum state of the process and the maximum decomposition efficiency. In this paper, known as a major cause of air pollution, such as NO, NO2, SO2, frequency, flow rate, concentration, the material of the electrodes, and using TiO2 catalyst reactor with surface discharge caused by discharging the reactor plasma NOx, SOx decompose the harmful gas want to remove.

Microstructure and Microwave Dielectric Properties of ZrTiO4 Thin Films Prepared by Metal-organic Decomposition (금속유기분해 법으로 제조한 ZrTiO4 박막의 미세구조 및 고주파 유전특성)

  • Park, Chang-Sun;Sun, Ho-Jung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.1
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    • pp.53-60
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    • 2009
  • $ZrTiO_4$ dielectric thin films were coated by metal-organic decomposition, and annealed by rapid thermal processing up to $900^{\circ}C$ for their crytallization. Crystallized single-phase $ZrTiO_4$ thin films were fabricated above the annealing temperature of $800^{\circ}C$, but their grains were randomly oriented without specific textured orientation. Best dielectric properties were presented by the sample annealed at $800^{\circ}C$ which had crystalline structure and flat surface. Dielectric constant of the film was maintained at 32 throughout full frequency range up to 6 GHz, and dielectric loss was varied between 0.01 and 0.04.

Evaluation of Ozone Concentration for the Oxide Thin Film Growth

  • Park, No-Bong;Iim, Jung-Kwan;Park, Yong-Pil;Lee, Hee-Kab
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.579-582
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    • 2003
  • Ozone is usually generated from oxygen gas using a silent discharge apparatus and its concentration is less then 10 mol%. Ozone is condensed by the adsorption method, which is widely used for the growth of oxidation thin films such as superconductor. Highly condensed ozone is analyzed by three methods; ultraviolet absorption, thermal decomposition and Q-mass analyzing methods. Thermal decomposition method is most effective in the highly condensed ozone region and its method is superior to Q-mass analyzer for determining ozone concentration because of the simplicity of the method.

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Decomposition of CFC-12($CCl_2F_2$) by Discharge Plasma (방전 플라스마에 의한 CFC-12($CCl_2F_2$)의 분해)

  • 강현춘;우인성;황명환;안형환;이한섭;조정국;강안수
    • Journal of the Korean Society of Safety
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    • v.14 no.3
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    • pp.93-100
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    • 1999
  • Decomposition efficiency, power consumption, and applied voltage of CFC(Chlorofluorocatbon) were investigated by SPCP(surface induced discharge plasma chemical processing) reactor to obtain optimum process variables and maximum decomposition efficiencies. Decomposition efficiency of CFC-12 with various electric frequencies(5~50kHz). flow rates (100~1,000mL/min), initial concentrations(100~1,000ppm), electrode materials(W, Cu, Al). electrode thickness(1, 2, 3mm) and reference gases($N_2$, $O_2$, air) were measured and the products were analyzed with FT-IR. Experimental results showed that at the frequency of 10kHz, the highest decomposition efficiency of 92.7% for CFC-12 were observed at the power consumptions of 29.6W. respectively, and that decomposition efficiency decreased with increasing frequency above 20kHz and decomposition efficiency per unit power were 3.13%/W for CFC-12. Decomposition efficiency was increased with increasing residence times and with decreasing initial concentration of pollutants. Decomposition efficiency was increased with increasing thickness of discharge electrode and the highest decomposition efficiency was obtained for the electrode diameter of 3m. As the electrode material, decomposition efficiency was in order that tungsten(W), copper(Cu), aluminum (Al). Decomposition of CFC-12 in the reference gas of $N_2$ showed the highest efficiency among three reference gases, and then the effect of reference gas on the decomposition efficiency decreased in order of air and $O_2$. The optimum power for the maximum decomposition efficiency was 25.3W for CFC.

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