• Atmosphere
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• v.21 no.3
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• pp.301-309
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• 2011

In this study, we compared light-absorption properties of aerosols observed in East and South Asia from black carbon (BC) mass concentration, aerosol scattering (${\sigma}_s$) and absorption (${\sigma}_a$) coefficients measurements at four sites: Korea Climate Observatory-Gosan (KCO-G), Korea Climate Observatory-Anmyeon (KCO-A), Maldives Climate Observatory-Hanimaadhoo (MCO-H) and Nepal Climate Observatory-Pyramid (NCO-P). No significant seasonal variations of BC mass concentration, ${\sigma}_s$ and ${\sigma}_a$, despite of wet removal of aerosols by precipitation in summer, were observed in East Asia, whereas dramatic changes of light-absorbing aerosol properties were observed in South Asia between dry and wet monsoon periods. Although BC mass concentration in East Asia is generally higher than that observed in South Asia, BC mass concentration at MCO-H during winter dry monsoon is similar to that of East Asia. The observed solar absorption efficiency (${\alpha}$) at 550 nm, where ${\alpha}={\sigma}_a/({\sigma}_s+{\sigma}_a)$, at KCO-G and KCO-A is higher than that in MCO-H due to large portions of BC emission from fossil fuel combustion. Interestingly, ${\alpha}$ at NCO-P is 0.14, which is two times great than that in MCO-H and is about 40% higher than that in East Asia, though BC mass concentration at NCO-P is the lowest among four sites. Consistently, the highest elemental carbon to sulphate ratio is found at NCO-P.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.3
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• pp.418-429
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• 2018

Measurements of 24-hr size-segregated ambient particles were made at an urban site of Gwangju under high pressure conditions occurred in the Korean Peninsula late in March 2018. The aim of this study was to understand the effect of air stagnation on mass size distributions and formation pathways of water-soluble organic and inorganic components. During the study period, the $NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$, water-soluble organic carbon (WSOC), and humic-like substances(HULIS) exhibited mostly bi-modal size distributions peaking at 1.0 and $6.2{\mu}m$, with predominant droplet modes. In particular, outstanding droplet mode size distributions were observed on March 25 when a severe haze occurred due to stable air conditions and long range transport of aerosol particles from northeastern regions of China. Air stagnation conditions and high relative humidity during the study period resulted in accumulation of primary aerosol particles from local emission sources and enhanced formation of secondary ionic and organic aerosols through aqueous-phase oxidations of $SO_2$, $NO_2$, $NH_3$, and volatile organic compounds, leading to their dominant droplet mode size distributions at particle size of $1.0{\mu}m$. From the size distribution of $K^+$ in accumulation mode, it can be inferred that in addition to the secondary organic aerosol formations, accumulation mode WSOC and HULIS could be partly attributed to biomass burning emissions.

• Journal of Environmental Science International
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• v.22 no.3
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• pp.347-358
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• 2013

The aerosol number concentration have measured with an aerodynamic particle sizer spectrometer(APS) at Gosan in Jeju Island, which is known as background area in Korea, from March 2010 to February 2011. The obtained results of asian dust events and non-asian dust period have been compared. The results show that the entire averaged aerosol number concentration from APS measurement during asian dust events and non-asian dust period are about 341 particles/$cm^3$ and 240 particles/$cm^3$, respectively. During asian dust events, the number concentration in small size ranges(${\leq}0.4{\mu}m$) are similar to non-asian dust period, however, those in large size ranges(${\geq}0.7{\mu}m$) are very higher than non-asian dust period. The contributions of the size resolved number concentration(23 channel in $0.25{\sim}10.0{\mu}m$) to total number concentration in that range are dramatically decreased with increased particle size. The contributions of smaller size ranges(${\leq}0.4{\mu}m$) during asian dust events are very low compared with non-asian dust period, on the other hand, those of larger size ranges(${\geq}0.4{\mu}m$) are higher than non-asian dust period. The number concentration in each size range are strongly correlated with the concentration in adjacent size range. And the total aerosol number concentration are depended on the number concentration in range of smaller than $0.58{\mu}m$ during non-asian dust period and asian dust events. On the other hand, $PM_{10}$ mass concentration has mainly affected with the number concentration in range of smaller than $1.0{\mu}m$ during non-asian dust period, however, during asian dust events, the mass concentration has mainly affected with the number concentration in range of $0.65{\sim}3.0{\mu}m$.

• Particle and aerosol research
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• v.8 no.1
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• pp.29-35
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• 2012

The Faraday cup electrode of different size has been developed and evaluated to investigate the diffusion effect of particles by Brownian motion in a particle beam mass spectrometer(PBMS). Particles which focused and accelerated by aerodynamic lens are charged to saturation in an electron beam, and then deflected electrostatically into a Faraday cup detector for measurement of the particle current. The concentration of particles is converted from currents detected by Faraday cup. Measurements of particle current as a function of deflection voltage are combined with measured relationships between particle velocity and diameter, charge and diameter, and mass and diameter, to determine the particle size distribution. The particle currents were measured using 5, 10, 20, 40 mm sized Faraday cup that can be move to one direction by motion shaft. The current difference for each sizes as a function of position was compared to figure out diffusion effect during transport. Polystyrene latex(PSL) 100, 200 nm sized standard particles were used for evaluation. The measurement using 5 mm sized Faraday cup has the highest resolution in a diffusion distance and the smaller particles had widely diffused.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.3
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• pp.457-468
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• 2018

To improve understanding of the physico-chemical characteristics of aerosols in the national park and comparing the air pollution between national park and the urban area nearby national park, the aerosol characterization study was conducted in Bukhansan National Park, Seoul, from July through September 2017. Semi-continuous measurements of $PM_{2.5}$ using PILS (Particle Into Liquid System) coupled with IC (Ion Chromatography) and TOC (Total Organic Carbon) analyzer allowed quantification of concentrations of major ionic species($Cl^-$, $SO_4{^{2-}}$, $NO_3{^-}$, $Na^+$, $NH_4{^+}$, $K^+$, $Mg{^{2+}}$ and $Ca{^{2+}}$) and water soluble organic carbon (WSOC) with 30-minute time resolution. The total mass concentration of $PM_{2.5}$ was measured by T640 (Teledyne) with 5-minute time resolution. The black carbon (BC) and ozone were measured with a minute time resolution. The timeline of aerosol chemical compositions reveals a strong influence from urban area (Seoul) at the site in Bukhansan National Park. Inorganic aerosol composition was observed to be dominated by ammoniated sulfate at most times with ranging from $0.1{\sim}32.6{\mu}g/m^3$ (6.5~76.1% of total mass of $PM_{2.5}$). The concentration of ammonium nitrate, a potential indicator of the presence of local source, ranged from below detection limits to $20{\mu}g/m^3$ and was observed to be highest during times of maximum local urban (Seoul) impact. The total mass of $PM_{2.5}$ in Bukhansan National Park was observed to be 10~23% lower than the total mass of $PM_{2.5}$ in urban area (Gireum-dong and Bulgwang-dong, Seoul). In general, ozone concentration in Bukhansan National Park was observed to be similar or higher than urban sites in Seoul, suggesting additional biogenic VOCs with $NO_x$ from vehicle emission were to be precursors for ozone formation in Bukhansan National Park.

• Atmosphere
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• v.27 no.2
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• pp.225-233
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• 2017

Korea has recently suffered from severe hazes, largely being long-range transported from China but frequently mixed with domestic pollution. It is important to identify the origin of the frequently-occurring hazes, which is however hard to clearly determine in a quantitative term. In this regard, we suggest a possible classification procedure of various hazes into long-range transported haze (LH), Yellow Sand (YS), and urban haze (UH), based on mass loading of fine particles, time lag of PM mass concentrations between two sites aligned with dominant wind direction, backward trajectory of air mass, and the mass ratio of PM2.5 to PM10. The analysis sites are Seoul (SL) and Baengnyeongdo (BN), which are distant about 200 km from each other in the west to east direction. Aerosol concentrations at BN are overall lower than those of SL, indicative of BN being a background site for SL. We found distinct time lag of PM2.5 and PM10 concentrations between BN and SL in case of both LH and YS, but the intensity of YS being stronger than LH. Time scale (e-folding time scale) of LH appears to be longer and more variable than YS, which implies that LH covers much larger spatial scale. In addition, we found linear and significant correlations between ${\tau}_a$ obtained from sunphotometer and ${\tau}_{cal}$ calculated from surface aerosol scattering coefficient for LH episodes, relative to few correlation between those for YS, which might be associated with transported height of YS being much higher than LH. Therefore surface PM concentrations for the YS period are thought to be not representative for vertical integrated amount of aerosol loadings, probably by virtue of decoupled structure of aerosol vertical distribution. Improvement of various hazes classification based on the current result would provide the public as well as researchers with more accurate information of LH, UH, and YS, in terms of temporal scale, size, vertical distribution of aerosols, etc.

• Particle and aerosol research
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• v.9 no.2
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• pp.39-50
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• 2013

Real-time aerosol measuring instruments have been widely used for the measurement of atmospheric aerosol, diesel particulate matter, or material synthesis. A scanning mobility particle sizer (SMPS) measures the number size distribution of particles using electrical mobility detection technique. An aerodynamic particle sizer (APS) is used to determine the number concentration and the mean aerodynamic diameter of test particles. An electrical low-pressure impactor (ELPI) is a multi-stage impaction device to separate airborne particles into aerodynamic size classes using particle charging and electrical detection techniques. In this study, the performance of these instruments were evaluated to assess their ability to obtain mass concentrations from particle number concentration measurements made as a function of particle size. The effect of determination of particle density on the measurement of mass concentration was investigated for the three instruments.

• Korean Journal of Remote Sensing
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• v.29 no.2
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• pp.243-251
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• 2013

The optical properties of long-range transported Asian dust were studied by the satellite observations and Sun/sky radiometer measurements from the Aerosol Robotic Network(AERONET) in Northeast Asia. The movement of Asian dust from source regions to downwind areas was tracked by the Ozone Monitoring Instrument(OMI) derived aerosol product imagery. The optical properties of Asian dust were classified for geographical locations, which are source regions such as deserts area in Dunhuang and Inner Mongolia, downwind areas such as Yulin and Beijing, and long-range transported regions such as Korea(Anmyon and Gosan) and Japan(Noto). In general, relatively higher aerosol mass loadings with larger aerosol particles at desert regions were found. Aerosol Optical Depth(AOD) decreased significantly in downwind areas and long-range transported areas, which was accompanied by increased Angstrom exponents. This indicates the effects of aerosol mixing with various pollutants during transport of Asian dust plume on aerosol optical properties. Moreover, relatively high Single-Scattering Albedo(SSA) at 440 nm values ranging from 0.90 - 0.96 and increasing tendency of SSA with wavelength were observed at source region. The spectral dependence of SSA decreased during long-range transport.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.4
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• pp.411-422
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• 2012

Ground-based in-situ measurements of aerosol optical properties at Gosan climate observatory have been analyzed to investigate the optical contribution of Asian dust and polluted particles on light absorption in springtime 2011. During the Asian dust episode, the contribution of Asian dust particle to aerosol absorption coefficient estimated about 45% at 370 nm and about 23% at 520 nm. Especially, black carbon in dust plume contributes about 48% to aerosol light absorption at 520 nm since the airmass are transported from the Gobi and inner Mongolia deserts, and this airmass comes across the northeastern coast of China, near the Shandong Peninsula. In pollution case, the contributions of dust particle and black carbon to aerosol absorption coefficient estimated about 41% and 11% at 370 nm, respectively. However, pollution case shows the highest light absorption of 48% for brown carbon at 370 nm, which indicates the significantly high mass concentration of organic carbon ($6.3{\pm}2.2{\mu}g\;m^{-3}$) in pollution plume can contribute to the increase of light absorption at near-UV spectral region.

• Journal of Environmental Science International
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• v.12 no.10
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• pp.1043-1054
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• 2003

During the period from April to September 2002, the size distributions of ambient aerosol were measured at the coastal site at Hamduk in Jeju Island. Na$\^$+/, K$\^$+/, Mg$\^$2+/, Ca$\^$2+/and Cl$\^$-/ exhibited mostly a bimodal coarse mode size distribution, while ammonium and sulfate were mainly in the fine size range, with maximum at around 0.54$\mu\textrm{m}$. The average molar concentration ratio of ammonium to sulfate for fine particles was equal to 2.0${\pm}$0.9. Nitrate was evenly found in both the coarse and fine modes. Elements like Al, Fe, Cu, Mg, Na, Ti, Sr and Mn were dominant in coarse particles, with the maximum at around 5.25$\mu\textrm{m}$. S and Pb were mainly in the submicrometer size range. Other elements with a fine and coarse modes were V, Ni, Cu, Ba and Mo. The patterns of the size distributions of trace elements measured at the downtown in Jeju City were very similar to those at the coastal site in Hamduk. However, the amplitude of size fractional concentrations at Jeju City was narrower than that at Hamduk. While the mass median diameters for the chemical species originated from the natural origin such as marine and crust were relatively large, those for ammonium, sulfate, S and Pb were very small.