• 제목/요약/키워드: Low-spin

검색결과 462건 처리시간 0.024초

m-Phenylene-Linked Bis-(Biradicals). Generation, Characterization and Computational Studies

  • Nicolaides, Athanassios;Tomioka, Hideo
    • Journal of Photoscience
    • /
    • 제10권1호
    • /
    • pp.165-173
    • /
    • 2003
  • m-Phenylene-linked biscarbenes, bisnitrenes and carbenonitrenes can be formed photochemically from appropriate nitrogenous precursors. Generation of such reactive intermediates under matrix-isolation conditions allows for their characterization by spectroscopic techniques such as ESR, UV /vis and IR. The latter method is also useful in characterizing secondary products derived from these reactive intermediates. Computational chemistry methods complement experimental IR data, aiding, thus, in identification of such compounds. In addition electronic structure calculations help in developing qualitative and semi-quantitative models, which can be useful in predicting ground-state multiplicities. The parent systems of m-phenylene-linked carbenes and nitrenes have high-spin ground states, but a switching to lower multiplicity can be achieved by chemical substitution. The ground state and various low-lying excited states of m-phenylenecarbenonitrenes can be reasonably approximated by simple valence-bond depictions. Finally, m-phenylenecarbenonitrenes are photoreactive in the inert matrix isomerizing to cyclopropene derivatives.

  • PDF

STRUCTURAL MORPHOLOGY AND DIELECTRIC PROPERTIES OF POLYANILINE-EMERALDINE BASE AND POLY METHYL METHACRYLATE THIN FILMS PREPARED BY SPIN COATING METHOD

  • Shekar, B. Chandar;Yeon, Ji;Rhee, Shi-Woo
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
    • /
    • pp.1081-1084
    • /
    • 2003
  • Structural morphology, annealing behavior and dielectric properties of polyaniline-emeraldine base (Pani-EB) and poly methyl methacrylate (PMMA) thin films prepared by spin coating technique have been studied. MIM and MISM structures were used to investigate annealing and dielectric behavior. The XRD and AFM spectrum of as grown and annealed thin films indicates the amorphous nature. The observed amorphous phase, low loss, dielectric behavior and thermal stability even at high temperatures implies the feasibility of utilizing PMMA and Pani-EB thin films as gate dielectric insulator layer in organic thin film transistors which can find application in flat panel display.

  • PDF

Electron Spin Transition Line-width of Mn-doped Wurtzite GaN Film for the Quantum Limit

  • Park, Jung-Il;Lee, Hyeong-Rag;Lee, Su-Ho;Hyun, Dong-Geul
    • Journal of Magnetics
    • /
    • 제17권1호
    • /
    • pp.13-18
    • /
    • 2012
  • Starting with Kubo's formula and using the projection operator technique introduced by Kawabata, EPR lineprofile function for a $Mn^{2+}$-doped wurtzite structure GaN semiconductor was derived as a function of temperature at a frequency of 9.49 GHz (X-band) in the presence of external electromagnetic field. The line-width is barely affected in the low-temperature region because there is no correlation between the resonance fields and the distribution function. At higher temperature the line-width increases with increasing temperature due to the interaction of electrons with acoustic phonons. Thus, the present technique is considered to be more convenient to explain the resonant system as in the case of other optical transition systems.

Microfabrication of MEMS Cantilevers for Mechanically Detected High-Frequency ESR Measurement

  • Ohmichi, E.;Yasufuku, Y.;Konishi, K.;Ohta, H.
    • Journal of Magnetics
    • /
    • 제18권2호
    • /
    • pp.163-167
    • /
    • 2013
  • We fabricated prototype cantilevers for mechanically detected high-frequency ESR measurement. Cantilevers are fabricated from silicon-on-insulator (SOI) wafers using standard MEMS techniques such as lithography, wet etching, and plasma etching. Using commercial SOI wafers, fabrication cost and the number of processes can be substantially reduced. In this study, three types of cantilevers, designed for capacitive and optical detection, are shown. Capacitive type with lateral dimensions of $3.5{\times}1.6mm^2$ is aimed for low spin concentration sample. On the other hand, optical detection type with lateral dimensions of $50{\times}200{\mu}m^2$ is developed for high-sensitive detection of tiny samples such as newly synthesized microcrystals.

Fe-Cr-Ni 합금의 저온에서의 자기적 성질에 관한 연구 (A Study on the low temperature magnetic properties of Fe-Cr-Ni alloys)

  • 안병덕;김진옥;장경호;송기영
    • 한국자기학회지
    • /
    • 제3권4호
    • /
    • pp.277-283
    • /
    • 1993
  • 세개의 오스테 나이트계의 Fe-Cr-Ni 스테인레스 합금강들의 DC 자화율의 온도의존성을 4.2-300 K 온도영역에서 측정하였다. 측정결과 두개의 합금강들은 two-magnetic-phase 모델(spin glass와 초상자성)을 만족하였으며 나머지 하나는 자기적 2중 천이현상을 나타내었다. 또한 Ni/Cr의 비가 증가할수록 자화율의 최 대값이 증가하고 이 값을 나타내는 온도는 감소하였다.

  • PDF

Matlab Simulink를 이용한 회전안정탄의 6 자유도 탄도 모델링 (6 - DOF Trajectory M&S of Spin - stabilized Munitions using Matlab Simulink)

  • 김기표;윤상용;김진석;홍종태
    • 시스템엔지니어링학술지
    • /
    • 제2권2호
    • /
    • pp.39-44
    • /
    • 2006
  • With the advent of low cost, miniature and high-g hardened inertial sensors and actuators, many kind of smart munitions are becoming practical such as 1D or 2D TCM, SFM, Range Extended GPS guided munitions and so on. They have more complicated trajectory control algorithm than conventional munitions'. Therefore it is necessary to study the complicated operation algorithm of smart munitions with M&S in advance of developing them. The purpose of this paper is to introduce a practical M&S method to study an operation concept of smart munitions using PRODAS and Matlab.

  • PDF

The Structure, and the Magnetic and Magnetoresistive Characteristics of the Spin Valve Multilayers

  • Stobiecki, T.;Czapkiewicz, M.;Wrona, J.;Powroynik, W.;Stobiecki, F.
    • Journal of Magnetics
    • /
    • 제3권3호
    • /
    • pp.92-95
    • /
    • 1998
  • In this paper we report the low and high angle diffraction results, and the magnetic and magnetroesistive characteristics of the spin valve multilayer structure prepared by the sputter machine Emerald II in the Balzers Laboratory. The investigated system consists of a ferromagnetic free layer (7 nm NiFe) and a ferromagnetic pinned layer (7 nm NiFe), separated from each other by a nonmagnetic (2.1 nm Cu) spacer. The NiFe pinned layer is fixed by the exchange coupling with an antiferromagnetic layer (10 nm FeMn). For such system the magnetoresistance ratio ΔR/R=3.58%, the interlayer exchange coupling $H_c=6.4$ Oe and the field sensitivity 1.15%/Oe were otained.

  • PDF

자전 안정화형 탐색기 주사루프의 비연성 제어기 설계 (A decoupling controller design for the seeker scan loop with a spin-stabilized platform)

  • 유인억;이상정
    • 전자공학회논문지S
    • /
    • 제35S권5호
    • /
    • pp.35-41
    • /
    • 1998
  • This paper presents a decoupling controller of the missile seeker scan loop with a spin-stabilized platform. A precise seeker motion with respect to the scan command is essential for the higher acquisition probability of the target. As the seeker scan loop is a deeply cross-coupled two input two output system, an accurate pointing or scanning for each axis to the target is very difficult, even though provided with the help of a high performance controller. When a decoupling control is applied to the seeker scan loop, the cross-coupling between two axes can be reduced to a remarkable amount. As a low order of controller is required for the real time operation, a PI controller with decoupling filter is suggested and compared with other controllers. A linearized dynamic model of seeker scan loop is used and validated through the comparison of experimental results of step responses.

  • PDF

Magneto-optical Measurements of Semiconductor Quantum Structures in Pulsed-magnetic Fields

  • Kim, Yongmin
    • Applied Science and Convergence Technology
    • /
    • 제23권1호
    • /
    • pp.1-13
    • /
    • 2014
  • Semiconductor quantum structures are often characterized by their energy gaps which are modified by the quantum size effect. Energy levels in semiconductors can be realized by optical transitions within confined structures. Photoluminescence spectroscopy in magnetic fields at low temperatures has proved to be a powerful technique for investigating the electronic states of quantum semiconductor heterostructures and offers a complimentary tool to electrical transport studies. In this review, we examine comprehensive investigations of magneto-excitonic and Landau transitions in a large variety of undoped and doped quantum-well structures. Strong magnetic fields change the diamagnetic energy shift of free excitons from quadratic to linear in B in undoped single quantum well samples. Two-dimensional electron gas induced by modulation doping shows pronounce quantum oscillations in integer quantum Hall regime and discontinuous transition at ${\nu}=1$. Such discontinuous transition can be explained as the formation of spin waves or Skyrmions.

Spectroscopic Properties and Ligand Field Analysis of Tris[($\pm$)-trans-1,2-cyclohexanediamine]chromium(Ⅲ) Chloride$^1$

  • Jong-Ha Choi
    • Bulletin of the Korean Chemical Society
    • /
    • 제15권2호
    • /
    • pp.145-150
    • /
    • 1994
  • The low temperature luminescence and excitation, room-temperature UV-visible and infrared spectra of [Cr(${\pm})chxn_3]Cl_3$ (chxn=trans-1,2-cyclohexanediamine) have been measured. It is found that the zero-phonon line in the excitation spectrum splits into two components by $47\;cm^{-1}$. The eight electronic transitions due to spin-allowed and spin-forbidden are assigned. As expected, nitrogen atoms of chxn ligand have strong ${\sigma}-donor $properties toward chromium(Ⅲ). The positions and splittings of sharp-line transitions are analyzed as a function of the Cartesian bite (${\alpha}$) and twist (${\beta}$) angles to predict the metal-ligand geometry.